化工学报 ›› 2019, Vol. 70 ›› Issue (9): 3346-3352.doi: 10.11949/0438-1157.20190401

• 流体力学与传递现象 • 上一篇    下一篇

局部低温诱发过冷三水醋酸钠释能特性实验研究

王慧丽(),周国兵()   

  1. 华北电力大学能源动力与机械工程学院，北京 102206
  • 收稿日期:2019-04-17 修回日期:2019-05-21 出版日期:2019-09-05 发布日期:2019-09-05
  • 通讯作者: 周国兵 E-mail:w17073224271@163.com;zhougb@ncepu.edu.cn
  • 作者简介:王慧丽（1996—），女，硕士研究生，w17073224271@163.com
  • 基金资助:
    北京市自然科学基金项目(3192034)

Experimental investigation on discharging characteristics of supercooled sodium acetate trihydrate induced by local cooling

Huili WANG(),Guobing ZHOU()   

  1. School of Energy, Power and Mechanic Engineering, North China Electric Power University, Beijing 102206, China
  • Received:2019-04-17 Revised:2019-05-21 Published:2019-09-05 Online:2019-09-05
  • Contact: Guobing ZHOU E-mail:w17073224271@163.com;zhougb@ncepu.edu.cn

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摘要：

利用半导体制冷局部低温诱发稳定过冷的三水醋酸钠溶液凝固，实验研究不同含水量、样品质量、输入功率等条件下过冷溶液结晶诱导期及释热特性。结果表明：随样品含水量增加，整体呈现结晶诱导期增加，释热温度下降的趋势，含水量44%作为较理想的体系配比，结晶诱导期为2 min，稳定放热温度达52.8℃；诱发过程中制冷装置输入功率越大，容器壁面降温越快，较容易触发，功率为280 W的结晶诱导期是功率为70 W的 1/3；样品质量越大，结晶诱导期越短，稳定放热温度相对较高，放热时间趋长。实验结果为稳定过冷水合盐局部低温诱发凝固释能系统设计提供依据。

关键词: 局部低温, 三水醋酸钠, 稳定过冷, 结晶, 相变, 含水量, 太阳能

Abstract:

Experiments are performed on the effect of local cooling by thermoelectric cooler on triggering solidification of supercooled sodium acetate trihydrate (SAT). Factors such as the water content, the SAT sample mass as well as the input power of the thermoelectric cooler are examined about their effects on the crystallization activation and discharging characteristics. The results showed that with the increase of water content, the overall crystallization induction period increased, the heat release temperature decreased, and the water content of 44% was used as the ideal system ratio. The crystallization induction period was 2 min and the stable exothermic temperature was 52.8℃. The higher the input power(P) is, the faster the unit is cooled and the induction time period for P=280 W is one third of that for P=70 W. The probability of nucleation of samples is increased for higher sample mass and then the induction time is shorter with higher discharging temperature and longer heat release time.

Key words: local cooling, sodium acetate trihydrate, stable supercooling, crystallization, phase change, water content, solar energy

中图分类号: 

  • TK 02

图1

实验装置简图"

图2

局部低温诱发过冷水合盐溶液凝固机理"

图3

两种冷却方式下壁面温度随时间变化曲线"

图4

循环过程中容器壁面温度随时间变化曲线"

图5

含水量44%触发过程容器壁面温度随时间变化曲线"

图6

不同含水量下样品壁面温度及平均诱导时间变化"

图7

不同样品质量下壁面温度及平均诱导时间变化"

图8

不同输入功率下壁面温度及平均诱导时间变化"

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