化工学报 ›› 2005, Vol. 56 ›› Issue (9): 1690-1693.

• 催化、动力学与反应器 • 上一篇    下一篇

甲基丙烯醛氧化酯化制备甲基丙烯酸甲酯

赵威;李增喜;张锁江;庞海舰;董海峰;张香平   

  1. 中国科学院过程工程研究所绿色化学与技术课题组,北京 100080;中国科学院研究生院,北京 100039;哈尔滨工程大学化工学院,黑龙江 哈尔滨 150001
  • 出版日期:2005-09-25 发布日期:2005-09-25

Oxidative esterification of methacrolein to methyl methacrylate

ZHAO Wei;LI Zengxi;ZHANG Suojiang;PANG Haijian;DONG Haifeng;ZHANG Xiangping   

  • Online:2005-09-25 Published:2005-09-25

关键词: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化, 酯化, 催化反应

Abstract: Supported multi-metal catalyst was prepared by impregnation.A variety of factors such as reaction temperature, feedstock ratio, alkali concentration, catalyst concentration and antipolymerizer concentration were systematically investigated in terms of their effects on the oxidative esterification reaction for methyl methacrylate production from methacrolein.The experimental results showed that under the condition of temperature 333 K,methanol/methacrolein ratio 97∶1(molar ratio),NaOH concentration 0.001 g•ml-1 and catalyst concentration 0.02 g•ml-1, methacrolein conversion and methyl methacrylate selectivity were about 100% and 71.4% respectively, after 30 min reaction.

Key words: 甲基丙烯醛, 甲基丙烯酸甲酯, 氧化, 酯化, 催化反应