CIESC Journal ›› 2020, Vol. 71 ›› Issue (12): 5854-5862.DOI: 10.11949/0438-1157.20200618

• Material science and engineering, nanotechnology • Previous Articles    

Preparation and lithium storage properties of Mo2N quantum dots@nitrogen-doped graphene composite

WANG Lixia1,2,3(),ZHANG Zhenhua1,LI Lei1,ZHANG Linsen1,2,3(),FANG Hua1,2,3,SONG Yanhua1,3,LI Xiaofeng1,3   

  1. 1.School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, Henan, China
    2.Ceramic Materials Research Center, Zhengzhou University of Light Industry, Zhengzhou 450001, Henan, China
    3.Zhengzhou Key Laboratory of Green Power, Zhengzhou 450001, Henan, China
  • Received:2020-05-20 Revised:2020-07-09 Online:2020-12-05 Published:2020-12-05
  • Contact: ZHANG Linsen

Mo2N量子点@N-掺杂石墨烯复合材料的制备及储锂性能

王利霞1,2,3(),张振华1,李雷1,张林森1,2,3(),方华1,2,3,宋延华1,3,李晓峰1,3   

  1. 1.郑州轻工业大学材料与化学工程学院,河南 郑州 450001
    2.郑州轻工业大学陶瓷材料研究中心,河南 郑州 450001
    3.郑州市绿色化学电源重点实验室,河南 郑州 450001
  • 通讯作者: 张林森
  • 作者简介:王利霞(1984—),女,博士,讲师,2014050@zzuli.edu.cn
  • 基金资助:
    国家自然科学基金项目(21506198);河南省科技攻关项目(182102210163);郑州轻工业大学众创空间孵化项目(2019ZCKJ214);大学生创新创业训练计划项目(S202010462035)

Abstract:

To improve the electrochemical lithium storage performance of molybdenum nitrides, Mo2N quantum dots@nitrogen-doped graphene oxide sponge (Mo2N-QDs@Ngs) was prepared by hydrothermal reaction, freeze-drying and calcination in H2/N2 mixture with ammonium molybdate ((NH4)Mo7O24·4H2O), hexamethylenetetramine (C6H12N4) and graphene oxide (GO) as raw materials. The effect of GO content on the electrochemical lithium storage performance was investigated. The transmission electron microscope (TEM) results show that the size of the prepared Mo2N quantum dots is about 2—5 nm, and the Mo2N quantum dots are uniformly distributed on the surface of nitrogen-doped graphene. The electrochemical test results show that when the GO content is 30%, the prepared Mo2N-QDs@Ngs-30 has the best electrochemical lithium storage performance, which has 699 mA·h·g-1 specific capacity at the current density of 0.1 A·g-1, and has 286 mA·h·g-1 specific capacity even at the current density of 2 A·g-1.

Key words: Mo2N quantum dots, nitroden-doped graphene oxide, nanomaterials, nanostructure, electrochemistry, lithium-ion battery

摘要:

为改善钼氮化物的电化学储锂性能,以钼酸铵、六次甲基四胺及氧化石墨烯(GO)为原料,通过水热、冷冻干燥及在H2/N2混合气中热处理,制备了Mo2N量子点@氮掺杂石墨烯复合材料(Mo2N-QDs@Ngs),并探究了GO复合量对电化学储锂性能的影响。透射电子显微镜(TEM)测试结果表明:制备的Mo2N量子点尺寸约为2~5 nm,Mo2N量子点均匀地分布在氮掺杂石墨烯的表面。电化学测试结果表明:当GO复合量为30%时(Mo2N-QDs@Ngs-30),制备的复合材料具有最佳的电化学储锂性能,其在0.1 A·g-1的电流密度下具有699 mA·h·g-1的比容量,在2 A·g-1下仍具有286 mA·h·g-1的比容量。

关键词: Mo2N量子点, 氮掺杂石墨烯, 纳米材料, 纳米结构, 电化学, 锂离子电池

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