CIESC Journal ›› 2023, Vol. 74 ›› Issue (1): 205-223.DOI: 10.11949/0438-1157.20221311

• Reviews and monographs • Previous Articles     Next Articles

Advances in chemical-looping oxidative dehydrogenation of light alkanes

Jiachen SUN1,2(), Chunlei PEI1,2, Sai CHEN1,2, Zhijian ZHAO1,2, Shengbao HE3, Jinlong GONG1,2()   

  1. 1.Key Laboratory for Green Technology, Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
    2.Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, China
    3.Petrochemical Research Institute, PetroChina Company Limited, Beijing 100083, China
  • Received:2022-09-30 Revised:2023-02-14 Online:2023-03-20 Published:2023-01-05
  • Contact: Jinlong GONG

化学链低碳烷烃氧化脱氢技术进展

孙嘉辰1,2(), 裴春雷1,2, 陈赛1,2, 赵志坚1,2, 何盛宝3, 巩金龙1,2()   

  1. 1.天津大学化工学院,绿色合成与转化教育部重点实验室,天津 300072
    2.天津化学化工协同创新中心,天津 300072
    3.中国石油天然气股份有限公司石油化工研究院,北京 100083
  • 通讯作者: 巩金龙
  • 作者简介:孙嘉辰(1994—),男,博士研究生,Jiachens@tju.edu.cn
  • 基金资助:
    国家重点研发计划项目(2021YFA1501302);国家自然科学基金创新研究群体项目(22121004);国家自然科学基金优秀青年科学基金项目(22122808);中石油科技部项目(2020A-4816)

Abstract:

The production capacity of light olefins can reflect the technology level of the chemical industry. With the growing market demand for light olefins, novel and efficient light olefin production processes have attracted extensive attention. With chemical-looping light alkane oxidative dehydrogenation technology, through the reaction of lattice oxygen in the oxygen carrier and reactant molecules, the selective conversion of alkane molecules to olefin molecules can be realized, which can increase the yield of olefins and effectively reduce the process energy consumption and CO2 emission. This review analyzes the current research progress on the screening and theoretical design of oxygen carrier materials, the regulation mechanism of surface active sites and lattice oxygen transport in the bulk phase, and the optimization of reactors and processes for chemical-looping light alkane oxidative dehydrogenation technology. The future development trends of chemical-looping light alkane oxidative dehydrogenation technologies are systematically summarized to provide instructive perspectives for the advance of relevant technologies.

Key words: chemical-looping, oxygen carrier, oxidative dehydrogenation, selective hydrogen combustion, light alkanes

摘要:

低碳烯烃生产能力是化工行业技术水平的重要标志。随着低碳烯烃市场需求的增加,新型高效的低碳烯烃生产工艺得到了广泛关注。化学链低碳烷烃氧化脱氢技术,通过载氧体中的晶格氧与反应物分子发生反应,实现烷烃分子向烯烃分子的选择性转化,可以提高烯烃产率,有效降低过程能耗和CO2排放。本文针对化学链低碳烷烃氧化脱氢技术,深入分析了载氧体材料的筛选和理论设计、表面活性位和体相氧传输的调控机制、循环稳定性、载氧体的制备、化学链烷烃脱氢反应器和工艺设计优化等方向的研究现状和进展,并系统总结了未来化学链低碳烷烃脱氢技术及相关领域的发展趋势,为化学链烷烃脱氢领域的技术进步提供参考和借鉴。

关键词: 化学链, 载氧体, 氧化脱氢, 选择性氢燃烧, 低碳烷烃

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