化工学报 ›› 2021, Vol. 72 ›› Issue (1): 483-494.DOI: 10.11949/0438-1157.20201126
杨晓勇1(),代健1,王炳捷1,严圣林1,杨航1,白志山1(
),彭冲2
收稿日期:
2020-08-06
修回日期:
2020-10-19
出版日期:
2021-01-05
发布日期:
2021-01-05
通讯作者:
白志山
作者简介:
杨晓勇(1989—),男,博士,博士后,基金资助:
YANG Xiaoyong1(),DAI Jian1,WANG Bingjie1,YAN Shenglin1,YANG Hang1,BAI Zhishan1(
),PENG Chong2
Received:
2020-08-06
Revised:
2020-10-19
Online:
2021-01-05
Published:
2021-01-05
Contact:
BAI Zhishan
摘要:
环隙式离心萃取器是集成液-液混合与液-液分离于一体的高性能萃取设备,其广泛应用于核工业、化工环保、有色冶金、生物医药等领域。离心萃取器具有优异的水力学特性和传质特性,这主要得益于其环隙中的泰勒涡流以及转鼓内的离心分离流等特殊流动。本文主要依据离心萃取器结构和两相流动特点,综述了环隙内气-液界面变化规律、气泡流动特性、液-液两相流型、液滴流动特性,以及转鼓内的气-液界面等方面的研究进展,还总结了环隙螺旋隔板、转鼓径向叶片等结构的优化对于两相流动、混合或分离效果的影响。在后续研究中,可以从离心萃取过程中的液滴分散和聚并机理、三相流动测试及模拟、结构的模型化设计方法等方面开展更加深入的研究。
中图分类号:
杨晓勇, 代健, 王炳捷, 严圣林, 杨航, 白志山, 彭冲. 环隙式离心萃取器内部两相流动研究进展[J]. 化工学报, 2021, 72(1): 483-494.
YANG Xiaoyong, DAI Jian, WANG Bingjie, YAN Shenglin, YANG Hang, BAI Zhishan, PENG Chong. Advancement in two-phase flow of annular centrifugal extractor[J]. CIESC Journal, 2021, 72(1): 483-494.
1 | 叶春林. 圆筒式离心萃取器[M]. 北京: 原子能出版社, 2007: 36-38. |
Ye C L. Cylinderical Centrifugal Extractor[M]. Beijing: Atomic Energy Press, 2007: 36-38. | |
2 | Andereck C D, Liu S S, Swinney H L. Flow regimes in a circular Couette system with independently rotating cylinders[J]. Journal of Fluid Mechanics, 1986, 164: 155-183. |
3 | Deshmukh S S, Sreepriya V A, Joshi J B, et al. Computational flow modeling and visualization in the annular region of annular centrifugal extractor[J]. Industrial & Engineering Chemistry Research, 2007, 46(25): 8343-8354. |
4 | 叶立, 李立楠, 陈丹, 等. 泰勒流反应器的流动及反应特性[J]. 化工学报, 2013, 64(6): 2058-2064. |
Ye L, Li L N, Chen D, et al. Flow and reaction performance of Taylor-vortex flow reactor[J]. CIESC Journal, 2013, 64(6): 2058-2064. | |
5 | Ramezani M, Legg M J, Haghighat A, et al. Experimental investigation of the effect of ethyl alcohol surfactant on oxygen mass transfer and bubble size distribution in an air-water multiphase Taylor-Couette vortex bioreactor[J]. Chemical Engineering Journal, 2017, 319: 288-296. |
6 | Pawar S B, Thorat B N. CFD simulation of Taylor-Couette flow in scraped surface heat exchanger[J]. Chemical Engineering Research & Design, 2012, 90(3A): 313-322. |
7 | Webster D S, Williamson C L, Ward J F. Hydraulic performance of a 5-inch centrifugal contactor: DP-370 [R]. USA: Savannah River Laboratory, 1962. |
8 | Bernstein G, Grosvenor D, Lenc J, et al. A high-capacity annular centrifugal contactor[J]. Nuclear Technology, 1973, 20(3): 200-202. |
9 | 段五华, 张春秀, 周秀珠, 等. ϕ50 mm核用离心萃取器的研制及其水力学性能[J]. 核科学与工程, 2006, 26(2): 97-102. |
Duan W H, Zhang C X, Zhou X Z, et al. Development and hydraulic performance of ϕ50 mm centrifugal extractor used in nuclear industry[J]. Chinese Journal of Nuclear Science and Engineering, 2006, 26(2): 97-102. | |
10 | 张志庚, 张成群, 周嘉贞, 等. ϕ 230环隙式离心萃取器的流体力学性能研究[J]. 化学工程, 1993, 21(4): 21-28. |
Zhang Z G, Zhang C Q, Zhou J Z, et al. Study on hydromechanical properties of ϕ230 annular centrifugal extractor[J]. Chemical Engineering(China), 1993, 21(4): 21-28. | |
11 | 周嘉贞, 周秀珠, 于文东, 等. 一种放化分离用的微型离心萃取器[J]. 清华大学学报 (自然科学版), 1997, (5): 46-49. |
Zhou J Z, Zhou X Z, Yu W D, et al. A miniature centrifugal extractor for radiochemical separation[J]. Journal of Tsinghua University ( Sci & Tech), 1997, (5): 46-49. | |
12 | 李传博, 张宇, 晏太红, 等. ϕ20 mm离心萃取器的水力学性能[J]. 核化学与放射化学, 2011, 33(6): 349-352. |
Li C B, Zhang Y, Yan T H, et al. Hydraulic performance of ϕ20 mm centrifugal extractor[J]. Journal of Nuclear and Radiochemistry, 2011, 33(6): 349-352. | |
13 | 李传博, 郑卫芳, 晏太红, 等. ϕ10 mm离心萃取器水力学性能研究[J]. 原子能科学技术, 2012, 46(5): 530-532. |
Li C B, Zheng W F, Yan T H, et al. Study on hydraulic performance of ϕ10 mm centrifugal extractor[J]. Atomic Energy Science and Technology, 2012, 46(5): 530-532. | |
14 | 陈崔龙, 张德友, 卓培忠, 等. 实验室用小流量环隙式离心萃取器的设计[J]. 流体机械, 2009, 37(7): 30-33. |
Chen C L, Zhang D Y, Zhuo P Z, et al. Design of small flow annular centrifugal extractor for laboratory[J]. Fluid Machinery, 2009, 37(7): 30-33. | |
15 | 陈崔龙, 张德友, 陈道林, 等. 大长径比直联环隙式离心萃取分离机的研制[J]. 湿法冶金, 2011, 30(4): 340-343. |
Chen C L, Zhang D Y, Chen D L, et al. Development of a big length-to-diameter ratio direct-connect centrifugal extracting separator [J]. Hydrometallurgy of China, 2011, 30(4): 340-343. | |
16 | Duan W H, Sun T X, Wang J C. An industrial-scale annular centrifugal extractor for the TRPO process[J]. Nuclear Science and Techniques, 2018, 29(4): 9. |
17 | He X M. Development of compact miniature annular centrifugal contactor for hot cell placement[J]. Chemical Engineering Communications, 2008, 195(10): 1227-1239. |
18 | Brown M A, Wardle K E, Lumetta G, et al. Accomplishing equilibrium in ALSEP: demonstrations of modified process chemistry on 3-D printed enhanced annular centrifugal contactors[J]. Procedia Chemistry, 2016, 21: 167-173. |
19 | Chen H L, Zheng Q, Duan W H. Hydraulic characteristics of n-octanol/aqueous solution systems in a 25-mm annular centrifugal extractor[J]. Separation Science and Technology, 2019, 55(8): 1515-1523. |
20 | Deshmukh S S, Sathe M J, Joshi J B, et al. Residence time distribution and flow patterns in the single-phase annular region of annular centrifugal extractor[J]. Industrial & Engineering Chemistry Research, 2009, 48(1): 37-46. |
21 | Xu J Q, Duan W H, Zhou X Z, et al. Extraction of phenol in wastewater with annular centrifugal contactors[J]. Journal of Hazardous Materials, 2006, 131(1/2/3): 98-102. |
22 | Yang X, Jie F, Wang B, et al. High-efficient synergistic extraction of Co(II) and Mn(II) from wastewater via novel microemulsion and annular centrifugal extractor[J]. Separation and Purification Technology, 2019, 209: 997-1006. |
23 | 包福毅, 杨明德, 方军, 等. 采用离心萃取器萃取净化氯化浸出镍溶液[J]. 矿冶工程, 1995, 15(1): 42-47. |
Bao F Y, Yang M D, Fang J, et al. A process for purification of the nickel leacheate from chlorination leaching in centrifugal extractors[J]. Mining and Metallurgical Engineering, 1995, 15(1): 42-47. | |
24 | Jing X H, Wang J Y, Cao H B, et al. Rapid selective extraction of V(V) from leaching solution using annular centrifugal contactors and stripping for NH4VO3[J]. Separation and Purification Technology, 2017, 187: 407-414. |
25 | Wen J W, Ning P G, Cao H B, et al. Recovery of high-purity vanadium from aqueous solutions by reusable primary amines N1923 associated with semiquantitative understanding of vanadium species[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(6): 7619-7626. |
26 | Zhou J Z, Duan W H, Zhou X Z, et al. Extraction of hydrocortisone from the fermentation liquor with annular centrifugal contactors[J]. Separation Science and Technology, 2006, 41(3): 573-581. |
27 | Schuur B, Winkelman J G M, Vries J G D, et al. Experimental and modeling studies on the enantio-separation of 3,5-dinitrobenzoyl-(R),(S)-leucine by continuous liquid-liquid extraction in a cascade of centrifugal contactor separators[J]. Chemical Engineering Science, 2010, 65(16): 4682-4690. |
28 | 潘九海, 甘仁武, 张艳红, 等. 环隙式离心萃取器流场研究进展[J]. 现代化工, 2012, 32(6): 26-29. |
Pan J H, Gan R W, Zhang Y H, et al. Research advances of flow field of annular centrifugal extractor[J]. Modern Chemical Industry, 2012, 32(6): 26-29. | |
29 | Hwang J Y, Yang K S. Numerical study of Taylor-Couette flow with an axial flow[J]. Computers & Fluids, 2004, 33(1): 97-118. |
30 | Wereley S T, Lueptow R M. Velocity field for Taylor-Couette flow with an axial flow[J]. Physics of Fluids, 1999, 11(12): 3637-3649. |
31 | Bai Z S, Zhang J, Gan R W, et al. Effect of cylinder rotation on flow characteristics of the annular region in annular centrifugal extractor[J]. Separation Science, 2015, 50(6): 813-819. |
32 | Eggert A, Kogl T, Arlt W, et al. Computer tomographic detection of the liquid-liquid mixing and separation within the annular centrifugal contactor extractor[J]. Chemical Engineering Research & Design, 2019, 142: 143-153. |
33 | Li S, Duan W, Chen J, et al. CFD simulation of gas-liquid-liquid three-phase flow in an annular centrifugal contactor[J]. Industrial & Engineering Chemistry Research, 2012, 51(34): 11245-11253. |
34 | 杨晓勇. 基于三元溶剂与离心萃取协同技术的煤焦油加工硫酸钠废水资源化研究[D]. 上海: 华东理工大学, 2019. |
Yang X Y. Study on synergetic treatment of sodium sulfate wastewater from coal tar processing by ternary solvent and centrifugal extractor[D]. Shanghai: East China University of Science and Technology, 2019. | |
35 | Wang C Q, Li S W, Duan W H, et al. CFD simulations of the air/water two-phase flow in an annular centrifugal contactor[J]. Energy Procedia, 2013, 39: 467-473. |
36 | Misumi R, Kunii K, Todoroki K, et al. Rotor speed and supply flow rate effects on flow behavior in an annular centrifugal extractor[J]. Kag. Kog. Ronbunshu, 2018, 44(3): 135-141. |
37 | Wardle K E, Allen T R, Anderson M H, et al. Free surface flow in the mixing zone of an annular centrifugal contactor[J]. AIChE Journal, 2008, 54(1): 74-85. |
38 | Wardle K E, Lee T. Finite element lattice Boltzmann simulations of free surface flow in a concentric cylinder[J]. Computers & Mathematics with Applications, 2013, 65(2): 230-238. |
39 | 李志康, 商鲁伟, 聂苗苗, 等. G/O/W微分散体系实现甲酸/三辛胺-正辛醇体系萃取分离[J]. 化工学报, 2020, 71(9): 4219-4227. |
Li Z K, Shang L W, Nei M M, et al. Extraction of formic acid with G/O/W microdispersion system[J]. CIESC Journal, 2020, 71(9): 4219-4227 | |
40 | Eduardo M F, Canedo L, Zehev T, et al. An experimental study of bubble deformation in viscous liquids in simple shear flow[J]. AIChE Journal, 1993, 39(4): 553-559. |
41 | Prakash J, Lavrenteva O M, Byk L, et al. Interaction of equal-size bubbles in shear flow[J]. Physical Review E, 2013, 87(4): 043002. |
42 | Prakash J, Lavrenteva O M, Nir A. Interaction of bubbles in an inviscid and low-viscosity shear flow[J]. Physical Review E, 2013, 88(2): 023021. |
43 | Deng R S, Wang C H, Smith K A. Bubble behavior in a Taylor vortex[J]. Physical Review E, 2006, 73(3): 036306. |
44 | Ramezani M, Kong B, Gao X, et al. Experimental measurement of oxygen mass transfer and bubble size distribution in an air-water multiphase Taylor-Couette vortex bioreactor[J]. Chemical Engineering Journal, 2015, 279: 286-296. |
45 | Gao X, Kong B, Vigil R D. CFD investigation of bubble effects on Taylor-Couette flow patterns in the weakly turbulent vortex regime[J]. Chemical Engineering Journal, 2015, 270: 508-518. |
46 | Joseph D D, Nguyen K, Beavers G S. Non-uniqueness and stability of the configuration of flow of immiscible fluids with different viscosities[J]. Journal of Fluid Mechanics, 1984, 141: 319-345. |
47 | Campero R J, Vigil R D. Flow patterns in liquid-liquid Taylor-Couette-Poiseuille flow[J]. Industrial & Engineering Chemistry Research, 1999, 38(3): 1094-1098. |
48 | Nakase M, Makabe R, Takeshita K. Relation between oil-water flow and extraction performance in liquid-liquid countercurrent centrifugal extractors with Taylor vortices[J]. Journal of Nuclear Science and Technology, 2013, 50(3): 287-295. |
49 | Campbell C, Olsen M G, Vigil R D. Flow regimes in two-phase hexane/water semibatch vertical Taylor vortex flow[J]. Journal of Fluids Engineering-Transactions of the ASME, 2019, 141(11): 111203. |
50 | Zhu X, Vigil R D. Banded liquid-liquid Taylor‐Couette‐Poiseuille flow[J]. AIChE Journal, 2004, 47(9): 1932-1940. |
51 | Zhu X, Campero R J, Vigil R D. Axial mass transport in liquid-liquid Taylor-Couette-Poiseuille flow[J]. Chemical Engineering Science, 2000, 55(21): 5079-5087. |
52 | Sathe M J, Deshmukh S S, Joshi J B, et al. Computational fluid dynamics simulation and experimental investigation: study of two-phase liquid-liquid flow in a vertical Taylor-Couette contactor[J]. Industrial & Engineering Chemistry Research, 2010, 49(1): 14-28. |
53 | Hass P A. Turbulent dispersion of aqueous drops in organic liquids[J]. AIChE Journal, 1987, 33(6): 987-995. |
54 | Kadam B D, Joshi J B, Koganti S B, et al. Dispersed phase hold-up, effective interfacial area and Sauter mean drop diameter in annular centrifugal extractors[J]. Chemical Engineering Research & Design, 2009, 87(10): 1379-1389. |
55 | Tamhane T V, Joshi J B, Mudali K, et al. Measurement of drop size characteristics in annular centrifugal extractors using phase Doppler particle analyzer (PDPA)[J]. Chemical Engineering Research and Design, 2012, 90(8): 985-997. |
56 | Wyatt N B, O'Hern T J, Shelden B. Drop size distributions and spatial distributions in an annular centrifugal contactor[J]. AIChE Journal, 2013, 59(6): 2219-2226. |
57 | Joseph D D, Singh P, Chen K. Couette flows, rollers, emulsions, tall Taylor cells, phase separation and inversion, and a chaotic bubble in Taylor-Couette flow of two immiscible liquids[J]. Nonlinear Evolution of Spatio-Temporal Structures in Dissipative Continuous Systems, 1990, 225: 169-189. |
58 | Fridjonsson E O, Chandrasekera T C, Sederman A J, et al. Imaging the effects of peptide bio-surfactants on droplet deformation in a Taylor-Couette shear cell[J]. Soft Matter, 2011, 7(6): 2961-2967. |
59 | Qiao J, Deng R, Wang C H. Droplet behavior in a Taylor vortex[J]. International Journal of Multiphase Flow, 2014, 67: 132-139. |
60 | Eskin D, Taylor S D, Yang D. Modeling of droplet dispersion in a turbulent Taylor-Couette flow[J]. Chemical Engineering Science, 2017, 161: 36-47. |
61 | Padial-Collins N T, Zhang D Z, Zou Q, et al. Centrifugal contactors: separation of an aqueous and an organic stream in the rotor zone (LA-UR-05-7800)[J]. Separation Science and Technology, 2006, 41(6): 1001-1023. |
62 | 徐艳. 环隙式离心萃取器转筒区域流场PIV测试研究[D]. 上海: 华东理工大学, 2014. |
Xu Y. Studies on the flow field in the rotor zone of annular centrifugal contactor[D]. Shanghai: East China University of Science and Technology, 2014. | |
63 | Xu Y, Wang J G, Zhao S L, et al. PIV experimental study on the flow field in the rotor zone of an annular centrifugal contactor[J]. Chemical Engineering Research & Design, 2015, 94: 691-701. |
64 | Wardle K E, Allen T R, Swaney R. CFD simulation of the separation zone of an annular centrifugal contactor[J]. Separation Science and Technology, 2009, 44(3): 517-542. |
65 | Gandhir A, Wardle K E. CFD analysis of fluid flow above the upper weir of an annular centrifugal contactor[J]. Separation Science and Technology, 2012, 47(1): 1-10. |
66 | 段五华, 景山, 陈靖, 等. 核用离心萃取器的研制和应用进展[J]. 科技导报, 2006, (6): 55-58. |
Duan W H, Jing S, Chen J, et al. Advances in development and application of centrifugal extractors in nuclear industry[J]. Science and Technology Review, 2006, (6): 55-58. | |
67 | Wardle K E, Allen T R, Anderson M H, et al. Analysis of the effect of mixing vane geometry on the flow in an annular centrifugal contactor[J]. AIChE Journal, 2009, 55(9): 2244-2259. |
68 | Wardle K E. Liquid-liquid mixing studies in annular centrifugal contactors comparing stationary mixing vane options[J]. Solvent Extraction and Ion Exchange, 2015, 33(7): 671-690. |
69 | Tamhane T V, Joshi J B, Patil R N. Performance of annular centrifugal extractors: CFD simulation of flow pattern, axial mixing and extraction with chemical reaction[J]. Chemical Engineering Science, 2014, 110: 134-143. |
70 | Grafschafter A, Siebenhofer M. Effect of rotor disc diameter on holdup, axial dispersion and droplet size in a Taylor-Couette disc contactor[J]. Chemie Ingenieur Technik, 2019, 91(11): 1589-1596. |
71 | 范智, 白志山, 徐艳, 等. 离心萃取器转筒入口半径对筒内流场的影响[J]. 化工进展, 2015, 34(5): 1232-1235. |
Fan Z, Bai Z S, Xu Y, et al. Effects of centrifugal extractor cylinder inlet radius on the cylinder flow field[J]. Chemical Industry and Engineering Progress, 2015, 34(5): 1232-1235. | |
72 | Ghaya H, Guizani R, Mhiri H, et al. CFD study of the effect of geometrical shape of separation blades on the rotor performance of an annular centrifugal extractor (ACE)[J]. Journal of Applied Fluid Mechanics, 2019, 12(4): 1189-1202. |
[1] | 陈哲文, 魏俊杰, 张玉明. 超临界水煤气化耦合SOFC发电系统集成及其能量转化机制[J]. 化工学报, 2023, 74(9): 3888-3902. |
[2] | 齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930. |
[3] | 文兆伦, 李沛睿, 张忠林, 杜晓, 侯起旺, 刘叶刚, 郝晓刚, 官国清. 基于自热再生的隔壁塔深冷空分工艺设计及优化[J]. 化工学报, 2023, 74(7): 2988-2998. |
[4] | 高金明, 郭玉娇, 鄂承林, 卢春喜. 一种封闭罩内顺流多旋臂气液分离器的分离特性研究[J]. 化工学报, 2023, 74(7): 2957-2966. |
[5] | 江锦波, 彭新, 许文烜, 门日秀, 刘畅, 彭旭东. 泵出型螺旋槽油气密封泄漏特性及参数影响研究[J]. 化工学报, 2023, 74(6): 2538-2554. |
[6] | 孙永尧, 高秋英, 曾文广, 王佳铭, 陈艺飞, 周永哲, 贺高红, 阮雪华. 面向含氮油田伴生气提质利用的膜耦合分离工艺设计优化[J]. 化工学报, 2023, 74(5): 2034-2045. |
[7] | 刘尚豪, 贾胜坤, 罗祎青, 袁希钢. 基于梯度提升决策树的三组元精馏流程结构最优化[J]. 化工学报, 2023, 74(5): 2075-2087. |
[8] | 周必茂, 许世森, 王肖肖, 刘刚, 李小宇, 任永强, 谭厚章. 烧嘴偏转角度对气化炉渣层分布特性的影响[J]. 化工学报, 2023, 74(5): 1939-1949. |
[9] | 王泽栋, 石至平, 刘丽艳. 考虑气泡非均匀耗散的矩形反应器声流场数值模拟及结构优化[J]. 化工学报, 2023, 74(5): 1965-1973. |
[10] | 李纪元, 李金旺, 周刘伟. 不同扰流结构冷板传热性能研究[J]. 化工学报, 2023, 74(4): 1474-1488. |
[11] | 许文烜, 江锦波, 彭新, 门日秀, 刘畅, 彭旭东. 宽速域三种典型型槽油气密封泄漏与成膜特性对比研究[J]. 化工学报, 2023, 74(4): 1660-1679. |
[12] | 陈俊先, 姬忠礼, 赵瑜, 张倩, 周岩, 刘猛, 刘震. 基于微波技术的天然气管道内颗粒物在线检测方法研究[J]. 化工学报, 2023, 74(3): 1042-1053. |
[13] | 魏进家, 刘蕾, 杨小平. 面向高热流电子器件散热的环路热管研究进展[J]. 化工学报, 2023, 74(1): 60-73. |
[14] | 赵涛岩, 曹江涛, 李平, 冯琳, 商瑀. 区间二型模糊免疫PID在环己烷无催化氧化温度控制系统中的应用[J]. 化工学报, 2022, 73(7): 3166-3173. |
[15] | 魏朋, 陈珺, 王志国, 刘飞. 基于双部分丢弃的模拟移动床产率提高策略[J]. 化工学报, 2022, 73(7): 3099-3108. |
阅读次数 | ||||||||||||||||||||||||||||||||||||||||||||||||||
全文 349
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||
摘要 809
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||