分子蒸馏、薄膜蒸发与精馏耦合技术分离肉桂油组分

doi:10.11949/j.issn.0438-1157.20150895

化工学报 ›› 2015, Vol. 66 ›› Issue (9): 3542-3548.DOI: 10.11949/j.issn.0438-1157.20150895

分子蒸馏、薄膜蒸发与精馏耦合技术分离肉桂油组分

吴海波¹, 张玉姣², 方岩雄², 杨祖金^1,3, 芮泽宝³, 叶超¹, 禤耀明⁴, 纪红兵^1,3

1 中山大学惠州研究院, 广东惠州 516081;
2 广东工业大学轻工化工学院, 广东广州 510006;
3 中山大学化学与化学工程学院, 广东广州 510275;
4 佛山汉维科技有限公司, 广东佛山 528244

收稿日期:2015-06-10 修回日期:2015-06-20 出版日期:2015-09-05 发布日期:2015-09-05
通讯作者: 纪红兵
基金资助:
国家自然科学基金项目(21376279,21425627);广东省重大科技专项项目(2012A080103005);高校基本业务项目(14lgpy28);广州市科技计划项目(2014J4100125);大亚湾科技计划项目(2013A01013)。

Separation of components from cinnamon oil by molecular distillation, thin-film evaporation coupling distillation technology

WU Haibo¹, ZHANG Yujiao², FANG Yanxiong², YANG Zujin^1,3, RUI Zebao³, YE Chao¹, XUAN Yaoming⁴, JI Hongbing^1,3

1 Huizhou Research Institute of Sun Yat-sen University, Huizhou 516081, Guangdong, China;
2 Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China;
3 School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong, China;
4 Foshan Hanwei Technology Co., Ltd., Foshan 528244, Guangdong, China

Received:2015-06-10 Revised:2015-06-20 Online:2015-09-05 Published:2015-09-05
Supported by:
supported by the National Natural Science Foundation of China (21376279, 21425627), the Science and Technology Major Program of Guangdong Province (2012A080103005), the Fundamental Research Funds for the Central Universities (14lgpy28), Guangzhou Science and Technology Plan Projects (2014J4100125) and Dayawan Science and Technology Plan Projects (2013A01013).

摘要/Abstract

摘要：

本文采用分子蒸馏、薄膜蒸发与精馏耦合技术对肉桂油主要成分的分离进行研究。系统的温度、压力和回流比对5种组分的得率和纯度的影响分别进行了研究,实验结果表明这种技术成功地用于分离肉桂油。为了进一步理解分离因素相互之间对分离效果的影响,本文选择肉桂醛为模型化合物,采用中心响应面法对肉桂醛分离的影响因素进行研究。实验结果表明:温度95℃,压力50 Pa时,肉桂醛的得率和纯度最高。实验验证的数值与响应面法模拟的数值一致,表明响应面法可以用于指导肉桂油的生产。

关键词: 肉桂油, 蒸馏, 预测, 优化, 分离

Abstract:

In this study, a triple-integration technology including molecular distillation, thin-film evaporation, and distillation was adopted to separate cinnamon oil. The effects of distillation temperature, pressure and reflux ratio on the yield and purity of five components were investigated. Statistical calculations showed that the technology is successful in the separation of cinnamon oil. In order to understand the effects of separation factors, cinnamaldehyde is selected as a model compound. Based on a central composite design, the statistic model shows that distillation temperature and pressure have significant effects on the separation of cinnamaldehyde. The optimal values for highest yield and purity are as follows: temperature 95℃ and pressure 50 Pa. The experimental results are in agreement with the predicted values, indicating a successful application of response surface methodology in the optimization of separation parameters for cinnamon oil.

Key words: cinnamon oil, distillation, prediction, optimization, separation

中图分类号:

TQ654

吴海波, 张玉姣, 方岩雄, 杨祖金, 芮泽宝, 叶超, 禤耀明, 纪红兵. 分子蒸馏、薄膜蒸发与精馏耦合技术分离肉桂油组分[J]. 化工学报, 2015, 66(9): 3542-3548.

WU Haibo, ZHANG Yujiao, FANG Yanxiong, YANG Zujin, RUI Zebao, YE Chao, XUAN Yaoming, JI Hongbing. Separation of components from cinnamon oil by molecular distillation, thin-film evaporation coupling distillation technology[J]. CIESC Journal, 2015, 66(9): 3542-3548.

参考文献 21

[1]	Wang Shiyi(王世仪), Zhang Li(张丽), Wang Bing(王冰), Li Wenyan(李文颜). Bacteriological study of Chinese herbs cinnamicaldehyde on disinfection of infection root canal [J]. Chinese Journal of Microecology(中国微生态学杂志), 2000, 12(6): 369-373.
[2]	Yang Xia(杨霞), Huang Ping(黄萍), Xiao Xiaorong(肖晓蓉), Li Conghua(李从华). Antibacterial activities of Chinese medicine cinnamicaldehyde against main periodontal pathogen [J]. Chongqing Medicine(重庆医学), 2009, 38(1): 75-76.
[3]	Ruan Haiyan(阮海燕). Application of cinnamaldehyde in essence and flavor daily chemical and food additive industries [J]. Fine and Specialty Chemicals(精细与专用化学品), 2005, 13(3): 9-10.
[4]	Bi Wen(毕文). Research of antimicrobial substance in cinnamon oil [J]. Gansu Science and Technology(甘肃科技), 2012, 28(9): 145-146.
[5]	Tang Yufang(唐裕芳), Zhang Miaoling(张妙玲), Huang Baifei(黄白飞). The extraction and Anti-microbial activity of cinnamon oil [J]. Nat. Prod. Res. Dev.(天然产物研究与开发), 2006, 18(3): 432-433.
[6]	Yu H S, Lee S Y, Jang C G. Involvement of 5- HTlA and GABAA receptors in the anxiolytic-like effects of Cinnamomum cassia inmice [J]. Pharmacol. Biochem. Behav., 2007, 87(1): 164-170.
[7]	Yen T B, Chang S T. Synergistic effects of cinnamaldehyde in combination with eugenol against wood decay fungi [J]. Bioresour. Technol., 2008, 99(1): 232-236.
[8]	Wang R, Wang R J, Yang B. Extraction of essential oils from five cinnamon leaves and identification of their volatile compound compositions [J]. Innov. Food. Sci. Emerg., 2009, 10(2): 289-292.
[9]	Yang C H, Li R X, Chuang L Y. Antioxidant activity of various parts of Cinnamomum cassia extracted with different extraction methods [J]. Molecules, 2012, 17(6): 7294-7304.
[10]	Yu Jianliang(喻健良), Qu Zhiyong(翟志勇). Development of molecular distillation technique [J]. Chemical Engineering(化学工程), 2001, 29(5): 70-74.
[11]	Zhu Shunqin(祝顺琴), Tan Feng(谈锋). Application of molecular distillation technique in separation of natural products [J]. Fine Chemicals (精细化工), 2004, 21(1): 46-50.
[12]	Burch C R. Some experiments on vacuum distillation [J]. Proceedings of the Royal Society of London: Series A, 1929, 123(791): 271-284.
[13]	Wang Junwu(王军武), Xu Songlin(许松林), Xu Shimin(徐世民), Gan Aihua(干爱华). Application status of molecular distillation technology [J]. Chemical Industry and Engineering Progress(化工进展), 2002, 21(7): 499-501.
[14]	Wang Mingyan(王明艳), Zhang Xiaojie(张小杰), Wang Tao(王涛), Ma Weixing(马卫兴), Xu Xingyou(许兴友). Response surface methodology for optimizing extraction of polysaccharides from Toona sinensis (A. Juss.) Roem leaves[J]. Food Sci.(食品科学), 2010, 31(4): 106-110.
[15]	Khayet M, Cojocaru C, Garcia-Payo C. Application of response surface methodology and experimental design in direct contact membrane distillation [J]. Ind. Eng. Chem. Res., 2007, 46(17): 5673-5685.
[16]	Li Yanliang, Fang Zhixiang, You Jing. Application of Box-Behnken experimental design to optimize the extraction of insecticidal Cry1Ac from soil [J]. J. Agric. Food. Chem., 2013, 61(2): 1464-1470.
[17]	Akitha Devi M K, Giridhar P. Isoflavone augmentation in soybean cell cultures is optimized using response surface methodology [J]. J. Agric. Food Chem., 2014, 62(14): 3143-3149.
[18]	Zhang D, Li S, Xiong Q, et al. Extraction, characterization and biological activities of polysaccharides from Amomum villosum[J]. Carbohydr. Polym., 2013, 95(1): 114-122.
[19]	Hollebeeck S, Borlon F, Schneider Y, et al. Development of a standardized human in vitro digestion protocol based on macronutrient digestion using reponse surface methodology [J]. Food Chem., 2013, 138(2): 1936-1944.
[20]	Lu C H, Engelmann N, Lila M A, Erdman J W. Optimization of lycopene extraction from tomato cell suspension culture by response surface methodology [J]. J. Agric. Food Chem., 2008, 56: 7710-7714.
[21]	Sujoy B, Chandan D. Role of binder and preparation pressure in tubular ceramic membrane processing: design and optimization study using response surface methodology [J]. Ind. Eng. Chem. Res., 2014, 53(31): 12319-12329.

分子蒸馏、薄膜蒸发与精馏耦合技术分离肉桂油组分

Separation of components from cinnamon oil by molecular distillation, thin-film evaporation coupling distillation technology

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 21

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杨欣, 王文, 徐凯, 马凡华. 高压氢气加注过程中温度特征仿真分析[J]. 化工学报, 2023, 74(S1): 280-286.
[2]	赵亚欣, 张雪芹, 王荣柱, 孙国, 姚善泾, 林东强. 流穿模式离子交换层析去除单抗聚集体[J]. 化工学报, 2023, 74(9): 3879-3887.
[3]	陈哲文, 魏俊杰, 张玉明. 超临界水煤气化耦合SOFC发电系统集成及其能量转化机制[J]. 化工学报, 2023, 74(9): 3888-3902.
[4]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[5]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.
[6]	邢雷, 苗春雨, 蒋明虎, 赵立新, 李新亚. 井下微型气液旋流分离器优化设计与性能分析[J]. 化工学报, 2023, 74(8): 3394-3406.
[7]	刘爽, 张霖宙, 许志明, 赵锁奇. 渣油及其组分黏度的分子层次组成关联研究[J]. 化工学报, 2023, 74(8): 3226-3241.
[8]	张佳怡, 何佳莉, 谢江鹏, 王健, 赵鹬, 张栋强. 渗透汽化技术用于锂电池生产中N-甲基吡咯烷酮回收的研究进展[J]. 化工学报, 2023, 74(8): 3203-3215.
[9]	尹刚, 李伊惠, 何飞, 曹文琦, 王民, 颜非亚, 向禹, 卢剑, 罗斌, 卢润廷. 基于KPCA和SVM的铝电解槽漏槽事故预警方法[J]. 化工学报, 2023, 74(8): 3419-3428.
[10]	陈国泽, 卫东, 郭倩, 向志平. 负载跟踪状态下的铝空气电池堆最优功率点优化方法[J]. 化工学报, 2023, 74(8): 3533-3542.
[11]	刘文竹, 云和明, 王宝雪, 胡明哲, 仲崇龙. 基于场协同和耗散的微通道拓扑优化研究[J]. 化工学报, 2023, 74(8): 3329-3341.
[12]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[13]	张曼铮, 肖猛, 闫沛伟, 苗政, 徐进良, 纪献兵. 危废焚烧处理耦合有机朗肯循环系统工质筛选与热力学优化[J]. 化工学报, 2023, 74(8): 3502-3512.
[14]	诸程瑛, 王振雷. 基于改进深度强化学习的乙烯裂解炉操作优化[J]. 化工学报, 2023, 74(8): 3429-3437.
[15]	闫琳琦, 王振雷. 基于STA-BiLSTM-LightGBM组合模型的多步预测软测量建模[J]. 化工学报, 2023, 74(8): 3407-3418.