法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用

doi:10.11949/j.issn.0438-1157.20170096

化工学报 ›› 2017, Vol. 68 ›› Issue (7): 2918-2924.DOI: 10.11949/j.issn.0438-1157.20170096

• 材料化学工程与纳米技术 • 上一篇下一篇

法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用

周王帆¹, 陈新^1,2, 曹红亮¹, 王海燕¹, 赵仰之¹, 贾晓博¹, 王曼¹

1 华东理工大学材料科学与工程学院, 超细材料制备与应用教育部重点实验室, 上海市先进聚合物材料重点实验室, 上海 200237;
2 中国科学院上海微系统与信息技术研究所信息功能材料国家重点实验室, 上海 200050

收稿日期:2017-01-20 修回日期:2017-04-17 出版日期:2017-07-05 发布日期:2017-07-05
通讯作者: 陈新
基金资助:
上海市重点学科和重点实验室项目（B502，08DZ2230500）。

Preparation of platanus leaf-based activated carbon and its application to supercapacitors

ZHOU Wangfan¹, CHEN Xin^1,2, CAO Hongliang¹, WANG Haiyan¹, ZHAO Yangzhi¹, JIA Xiaobo¹, WANG Man¹

1 Key Laboratory for Ultrafine Materials of Ministry of Education, Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China;
2 State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

Received:2017-01-20 Revised:2017-04-17 Online:2017-07-05 Published:2017-07-05
Contact: 10.11949/j.issn.0438-1157.20170096
Supported by:
supported by the Project of Shanghai Key Disciplines and Key Laboratories (B502, 08DZ2230500).

摘要/Abstract

摘要：

以生物质法国梧桐枯叶为原料，将炭化的枯叶通过KOH化学活化处理，制备法国梧桐枯叶基活性炭（PLAC）。采用扫描电子显微镜（SEM）、X射线能量色散谱（EDS）、X射线光电子能谱（XPS）、傅里叶变换红外光谱（FTIR）、氮气吸脱附对法国梧桐基枯叶活性炭的形貌、成分、比表面积、孔径分布等进行表征；运用三电极电化学体系，通过循环伏安，恒流充放电，循环稳定性测试，电化学阻抗谱分析法国梧桐枯叶基活性炭的超级电容器电极性能。结果显示，在800℃下碳化，通过KOH活化处理的法国梧桐基活性炭制备的电极，在1 A·g^-1电流密度下，比电容达到266 F·g^-1。电极在5 A·g^-1的电流密度下循环2000次后，比容量仍保留 97.0%，展示出良好的电极性能。

关键词: 生物质, 活性炭, 电化学, 法国梧桐, 超级电容器, 电极材料

Abstract:

Platanus leaf-based activated carbon (PLAC) was synthesized through high temperature carbonization and KOH chemical activation, using dry platanus leaves as raw materials. Scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption-desorption techniques were used to characterize the morphology, composition, specific surface area and pore size distribution of the PLAC. The cyclic voltammetric (CV), galvanostatic charge/discharge (GCD) and electrochemical impedance spectroscopy (EIS) characterizations were performed with a three electrode electrochemical system, to study the supercapacitor electrode performance of the PLAC. The result shows that the PLAC electrode obtained under 800℃ carbonization and KOH chemical activation has specific capacitance of 266 F·g^-1 at 1 A·g^-1, and it can remain 97.0% of the initial capacitance after 2000 cycles at 5 A·g^-1, demonstrating good electrode properties.

Key words: biomass, activated carbon, electrochemistry, platanus, supercapacitor, electrode material

中图分类号:

TB32
TB34

周王帆, 陈新, 曹红亮, 王海燕, 赵仰之, 贾晓博, 王曼. 法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用[J]. 化工学报, 2017, 68(7): 2918-2924.

ZHOU Wangfan, CHEN Xin, CAO Hongliang, WANG Haiyan, ZHAO Yangzhi, JIA Xiaobo, WANG Man. Preparation of platanus leaf-based activated carbon and its application to supercapacitors[J]. CIESC Journal, 2017, 68(7): 2918-2924.

参考文献 33

[1]	WANG G P, ZHANG L, ZHANG J J. A review of electrode materials for electrochemical supercapacitors [J]. Chemical Society Reviews, 2012, 41 (2): 797-828.
[2]	YAN J, WANG Q, WEI T, et al. Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities [J]. Advanced Energy Materials, 2014, 4 (4): 1300816.
[3]	BAO L H, LI X D. Towards textile energy storage from cotton T-shirts [J]. Advanced Materials, 2012, 24 (24): 3246-3252.
[4]	HE X J, LI R C, QIU J S, et al. Synthesis of mesoporous carbons for supercapacitors from coal tar pitch by coupling microwave-assisted KOH activation with a MgO template [J]. Carbon, 2012, 50 (13): 4911-4921.
[5]	LI M M, LIU E H, LI J, et al. A doped activated carbon prepared from polyaniline for high performance supercapacitors [J]. Journal of Power Sources, 2010, 195 (5): 1516-1521.
[6]	NIU Z Q, ZHOU W Y, CHEN J, et al. Compact-designed supercapacitors using free-standing single-walled carbon nanotube films [J]. Energy & Environmental Science, 2011, 4 (4): 1440-1446.
[7]	YAMAHA Y, Takeshi T, Kenji M, et al. Electrochemical behavior of metallic and semiconducting single-wall carbon nanotubes for electric double-layer capacitor [J]. Carbon, 2012, 50 (3): 1422-1424.
[8]	CHOI C, LEE J A, KIM Y T, et al. Flexible supercapacitor made of carbon nanotube yarn with internal pores [J]. Advanced Materials, 2014, 26 (13): 2059-2065.
[9]	WU X L, GUO H L, WANG J K, et al. Biomass-derived sponge-like carbonaceous hydrogels and aerogels for supercapacitors [J]. ACS Nano, 2013, 7 (4): 3589-3597.
[10]	WANG J Z, CHEN M M, WANG C Y, et al. A facile method to prepare carbon aerogels from amphiphilic carbon material [J]. Materials Letters, 2012, 68 (1): 446-449.
[11]	HAO P, ZHAO Z H, TIAN J, et al. Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode [J]. Nanoscale, 2014, 6 (20): 12120-12129.
[12]	CHEN Z, WEI D, SOHN H S, et al. High-performance aqueous supercapacitors based on hierarchically porous graphitized carbon [J]. RSC Advances, 2012, 2 (5): 1755-1758.
[13]	LIU B, SHIOYAMA H, JIANG H L, et al. Metal-organic framework as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor [J]. Carbon, 2010, 48 (2): 456-463.
[14]	ZHU Y W, Shanthi M, Meryl D S, et al. Carbon-based supercapacitors produced by activation of grapheme [J]. Science, 2011, 332 (24): 1537-1541.
[15]	LIU C G, YU Z N, NEFF D, et al. Graphene-based supercapacitor with an ultrahigh energy density [J]. Nano letters, 2010, 10 (12): 4863-4868.
[16]	KIM T Y, JUNG G, YOO S, et al. Activated graphene-based carbons as supercapacitor electrodes with macro-and mesopores [J]. Acs Nano, 2013, 7 (8): 6899-6905.
[17]	ZHAO S,WANG C Y, CHEN M M, et al. Potato starch-based activated carbon spheres as electrode material for electrochemical capacitor [J]. Journal of Physics and Chemistry of Solids, 2009, 70 (9): 1256-1260.
[18]	PENG C, YAN X B, WANG R T, et al. Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes [J]. Electrochimica Acta, 2013, 87 (1): 401-408.
[19]	LAN D, CHEN Y Y, CHEN P, et al. Mesoporous CoO nanocubes@ continuous 3D porous carbon skeleton of rose-based electrode for high-performance supercapacitor [J]. ACS Applied Materials & Interfaces, 2014, 6 (15): 11839-11845.
[20]	QIAN W J, SUN F X, XU Y H, et al. Human hair-derived carbon flakes for electrochemical supercapacitors [J]. Energy & Environmental Science, 2014, 7 (1): 379-386.
[21]	LI X L, HAN C L, CHEN X Y, et al. Preparation and performance of straw based activated carbon for supercapacitor in non-aqueous electrolytes [J]. Microporous and Mesoporous Materials, 2010, 131 (1): 303-309.
[22]	CHEN W X, ZHANG H, HUANG Y Q, et al. A fish scale based hierarchical lamellar porous carbon material obtained using a natural template for high performance electrochemical capacitors [J]. Journal of Materials Chemistry, 2010, 20 (23): 4773-4775.
[23]	CHEN H B, WANG H B, YANG L F, et al. High specific surface area rice hull based porous carbon prepared for EDLCs [J]. International Journal of Electrochemical Science, 2012, 7 (6): 4889-4897.
[24]	LI X, XING W, ZHUO S P, et al. Preparation of capacitor's electrode from sunflower seed shell [J]. Bioresource Technology, 2011, 102 (2): 1118-1123.
[25]	LEE S G, PARK K H, SHIM W G, et al. Performance of electrochemical double layer capacitors using highly porous activated carbons prepared from beer lees [J]. Journal of Industrial and Engineering Chemistry, 2011, 17 (3): 450-454.
[26]	LI B, DAI F, XIAO Q F, et al. Nitrogen-doped activated carbon for a high energy hybrid supercapacitor [J]. Energy & Environmental Science, 2016, 9 (1): 102-106.
[27]	PENG C, YAN X B, WANG R T, et al. Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes [J]. Electrochimica Acta, 2013, 87 (1): 401-408.
[28]	牛耀岚, 马承愚, 李登新, 等. KOH活化废弃麻制备活性炭及其结构表征 [J]. 高等学校化学学报, 2010, 31 (10):1929-1933.NIU Y L, MA C Y, LI D X, et al. Preparation of KOH activated hemp and structure characterization [J]. Chemical Journal of Chinese Universities, 2010, 31 (10):1929-1933.
[29]	CHEN X L, LI W S, TAN C L, et al. Improvement in electrochemical capacitance of carbon materials by nitric acid treatment [J]. Journal of Power Sources, 2008, 184 (2): 668-674.
[30]	CHEN L F, ZHANG X D, LIANG H W, et al. Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors [J]. ACS nano, 2012, 6 (8): 7092-7102.
[31]	XU B, HOU S S, CAO G P, et al. Sustainable nitrogen-doped porous carbon with high surface areas prepared from gelatin for supercapacitors [J]. Journal of Materials Chemistry, 2012, 22 (36): 19088-19093.
[32]	DENISA H J, MYKOLA S, GAO Q L, et al. Combined effect of nitrogen- and oxygen- containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors [J]. Advanced Functional Materials, 2009, 19 (3): 438-447.
[33]	李吉, 魏彤, 闫俊, 等. 石墨烯纳米片/CoS2复合材料的制备及其在超级电容器中的应用 [J]. 化工学报, 2014, 65 (7): 2849-2854.LI J, WEI T, YAN J, et al. Preparation of graphene nanosheet/CoS2 composite and its application in supercapacitors [J]. CIESC Journal, 2014, 65 (7): 2849-2854.

法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用

Preparation of platanus leaf-based activated carbon and its application to supercapacitors

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 33

相关文章 15

编辑推荐

Metrics

本文评价

[1]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[2]	郑佳丽, 李志会, 赵新强, 王延吉. 离子液体催化合成2-氰基呋喃反应动力学研究[J]. 化工学报, 2023, 74(9): 3708-3715.
[3]	吕龙义, 及文博, 韩沐达, 李伟光, 高文芳, 刘晓阳, 孙丽, 王鹏飞, 任芝军, 张光明. 铁基导电材料强化厌氧去除卤代有机污染物：研究进展及未来展望[J]. 化工学报, 2023, 74(8): 3193-3202.
[4]	陈佳起, 赵万玉, 姚睿充, 侯道林, 董社英. 开心果壳基碳点的合成及其对Q235碳钢的缓蚀行为研究[J]. 化工学报, 2023, 74(8): 3446-3456.
[5]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[6]	张琦钰, 高利军, 苏宇航, 马晓博, 王翊丞, 张亚婷, 胡超. 碳基催化材料在电化学还原二氧化碳中的研究进展[J]. 化工学报, 2023, 74(7): 2753-2772.
[7]	张蒙蒙, 颜冬, 沈永峰, 李文翠. 电解液类型对双离子电池阴阳离子储存行为的影响[J]. 化工学报, 2023, 74(7): 3116-3126.
[8]	吴文涛, 褚良永, 张玲洁, 谭伟民, 沈丽明, 暴宁钟. 腰果酚生物基自愈合微胶囊的高效制备工艺研究[J]. 化工学报, 2023, 74(7): 3103-3115.
[9]	葛加丽, 管图祥, 邱新民, 吴健, 沈丽明, 暴宁钟. 垂直多孔碳包覆的FeF₃正极的构筑及储锂性能研究[J]. 化工学报, 2023, 74(7): 3058-3067.
[10]	屈园浩, 邓文义, 谢晓丹, 苏亚欣. 活性炭/石墨辅助污泥电渗脱水研究[J]. 化工学报, 2023, 74(7): 3038-3050.
[11]	张谭, 刘光, 李晋平, 孙予罕. Ru基氮还原电催化剂性能调控策略[J]. 化工学报, 2023, 74(6): 2264-2280.
[12]	杨峥豪, 何臻, 常玉龙, 靳紫恒, 江霞. 生物质快速热解下行式流化床反应器研究进展[J]. 化工学报, 2023, 74(6): 2249-2263.
[13]	董茂林, 陈李栋, 黄六莲, 吴伟兵, 戴红旗, 卞辉洋. 酸性助水溶剂制备木质纳米纤维素及功能应用研究进展[J]. 化工学报, 2023, 74(6): 2281-2295.
[14]	李靖, 沈聪浩, 郭大亮, 李静, 沙力争, 童欣. 木质素基碳纤维复合材料在储能元件中的应用研究进展[J]. 化工学报, 2023, 74(6): 2322-2334.
[15]	李瑞康, 何盈盈, 卢维鹏, 王园园, 丁皓东, 骆勇名. 电化学强化钴基阴极活化过一硫酸盐的研究[J]. 化工学报, 2023, 74(5): 2207-2216.