氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

doi:10.3969/j.issn.0438-1157.2013.02.028

化工学报 ›› 2013, Vol. 64 ›› Issue (2): 616-623.DOI: 10.3969/j.issn.0438-1157.2013.02.028

氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

艾宁^1,2, 姜哲¹, 徐茜³, 钱琪枫³, 伍希¹, 王家炜³

1. 浙江工业大学化学工程与材料学院,浙江杭州 310032;
2. 清华大学,化学工程联合国家重点实验室,北京 100084;
3. 宁波诺丁汉大学工程学院,浙江宁波 315100

收稿日期:2012-07-31 修回日期:2012-10-10 出版日期:2013-02-05 发布日期:2013-02-05
通讯作者: 王家炜
作者简介:艾宁(1977—),男,博士,副教授。
基金资助:
化学工程联合国家重点实验室开放课题项目(SKL-ChE-11A02)。

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂

AI Ning^1,2, JIANG Zhe¹, XU Qian³, QIAN Qifeng³, WU Xi¹, WANG Jiawei³

1. College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China;
2. State Key Laboratory of Chemical Engineering, Tsinghua University, Beijing 100084, China;
3. Division of Engineering, University of Nottingham Ningbo China, Ningbo 315100, Zhejiang, China

Received:2012-07-31 Revised:2012-10-10 Online:2013-02-05 Published:2013-02-05
Supported by:
supported by the State Key Laboratory of Chemical Engineering in Tsinghua University, China(SKL-ChE-11A02).

摘要/Abstract

摘要： 以氨基硅烷为改性剂,采用超声剥脱的方法合成了氨基改性的层状双氢氧化物。利用元素分析、X射线衍射(XRD)、漫反射红外傅里叶变换光谱(DRIFTS)和热重分析(TGA)等技术对样品进行了表征。研究了样品在25～150℃温度范围内的二氧化碳吸附能力。在80℃下,NiMgAl N2在纯CO₂和15% CO₂/N₂混合气中达到最大吸附容量,分别为2.02 mmol·g^-1和1.89 mmol·g^-1。吸附/脱附再生实验显示140℃为最佳的脱附温度。利用原位漫反射傅里叶红外光谱对二氧化碳在样品上的吸附进行了机理研究。

关键词: 二氧化碳, 吸附, 原位红外光谱, 层状双氢氧化物, 氨基

Abstract: An amine modified NiMgAl layered double hydroxide was synthesized via an exfoliation and grafting method.The samples were characterized by elemental analysis, X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and thermogravimetric analysis (TGA).Adsorption of carbon dioxide on the modified layered double hydroxide was investigated by TGA at 25—150℃.NiMgAl N2 shows a maximum CO₂ adsorption capacity of 2.02 mmol·g^-1 in pure CO₂ and 1.89 mmol·g^-1 in 15% CO₂/N₂ at 80℃.The optimum desorption temperature is 140℃ for NiMgAl N2 according to adsorption/desorption experiments.By in-situ DRIFTS, the adsorption of CO₂ on NiMgAl N2 follows the mechanism of formation of ammonium carbamate ion pairs.

Key words: carbon dioxide, adsorption, in-situ infrared spectrometer, layered double hydroxide, amine

中图分类号:

TQ028

艾宁, 姜哲, 徐茜, 钱琪枫, 伍希, 王家炜. 氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理[J]. 化工学报, 2013, 64(2): 616-623.

AI Ning, JIANG Zhe, XU Xi, QIAN Qifeng, WU Xi, WANG Jiawei. Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂[J]. CIESC Journal, 2013, 64(2): 616-623.

参考文献 28

[1]	IPCC. Climate change 2007:the physical science basis.Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change.Cambridge:C.U.Press, 2007
[2]	Drage T C, Snape C E, Stevens L A, Wood J, Wang J W, Cooper A I, Dawson R, Guo X, Satterley C,Irons R.Materials challenges for the development of solid sorbents for post-combustion carbon capture[J].Journal of Materials Chemistry, 2012, 22(7):2815-2823
[3]	Fei Weiyang(费维扬), Ai Ning(艾宁),Chen Jian(陈健).Capture and separation of greenhouse gases CO2—the challenge and opportunity for separation technology[J].Chemical Industry and Engineering Progress(化工进展), 2005, 24(1):1-4
[4]	Choi S, Drese J H,Jones C W.Adsorbent materials for carbon dioxide capture from large anthropogenic point sources[J].Chem.Sus.Chem., 2009, 2(9):796-854
[5]	Wang Q, Luo J, Zhong Z,Borgna A.CO2 capture by solid adsorbents and their applications:current status and new trends[J].Energy & Environmental Science, 2011, 4(1):42-55
[6]	Forano C, Hibino T, Lexoux F,Taviot-Gueho C.Layered double hydroxides//Bergaya F, Theng B K G,Lagaly G.Handbook of Clay Science[M].Oxford:Elsevier Science, 2006:1021-1095
[7]	Wang J, Stevens L A, Drage T C, Snape C E,Wood J. Preparation and CO2 adsorption of amine modified layered double hydroxide via anionic surfactant-mediated route[J].Chemical Engineering Journal, 2012, 181/182:267-275
[8]	Wang J, Stevens L A, Drage T C,Wood J.Preparation and CO2 adsorption of amine modified Mg-Al LDH via exfoliation route[J].Chemical Engineering Science, 2012, 68(1):424-431
[9]	Aschenbrenner O, McGuire P, Alsamaq S, Wang J, Supasitmongkol S, Al-Duri B, Styring P,Wood J. Adsorption of carbon dioxide on hydrotalcite-like compounds of different compositions[J].Chemical Engineering Research and Design, 2011, 89(9):1711-1721
[10]	Knoefel C, Descarpentries J, Benzaouia A, Zelenak V, Mornet S, Llewellyn P L,Hornebecq V.Functionalised micro-/mesoporous silica for the adsorption of carbon dioxide[J].Microporous and Mesoporous Materials, 2007, 99(1/2):79-85
[11]	Harlick P J E,Sayari A.Applications of pore-expanded mesoporous silicas(3):Triamine silane grafting for enhanced CO2 adsorption[J].Industrial & Engineering Chemistry Research, 2006, 45(9):3248-3255
[12]	Chuayplod P,Trakarnpruk W.Transesterification of rice bran oil with methanol catalyzed by Mg(Al)La hydrotalcites and metal/MgAl oxides[J].Industrial & Engineering Chemistry Research, 2009, 48(9):4177-4183
[13]	Xu Z, Liu Q,Finch J A.Silanation of stability of 3-aminopropyl triethoxy silane on nanosized superparamagnetic particles(Ⅰ):Direct silanation[J].Applied Surface Science, 1997, 120:269-278
[14]	Wypych F, Bail A, Halma M,Nakagaki S.Immobilization of iron(Ⅲ)porphyrins on exfoliated MgAl layered double hydroxide, grafted with(3-aminopropyl)triethoxysilane[J].Journal of Catalysis, 2005, 234(2):431-437
[15]	White L D,Tripp C P.Reaction of(3-aminopropyl)dimethylethoxysilane with amine catalysts on silica surfaces[J].Journal of Colloid and Interface Science, 2000, 232:400-407
[16]	Dobson K D, Roddick-Lanzilotta A D,McQuillan A J.An in situ infrared spectroscopic investigation of adsorption of sodium dodecylsulfate and of etyltrimethylammonium bromide surfactants to TiO2, ZrO2, Al2O3, and Ta2O5 particle films from aqueous solutions[J].Vibrational Spectroscopy, 2000, 24:287-295
[17]	Crepaldi E L, Pavan P C, Tronto J,Valim J B.Chemical, structural, and thermal properties of Zn(Ⅱ)-Cr(Ⅲ)layered double hydroxides intercalated with sulfated and sulfonated surfactants[J].Journal of Colloid and Interface Science, 2002, 248(2):429-442
[18]	da Fonseca M G, Silva C R,Airoldi C.Aminated phyllosilicates synthesized via a sol-gel process[J].Langmuir, 1999, 15:5048-5055
[19]	Kulikova G A,Parfenyuk E V.Surface properties of modified nanosized silica and their influence on human serum albumin immobilization[J].Protection of Metals and Physical Chemistry of Surfaces, 2010, 46(5):546-549
[20]	Romero A A, Alba M D, Zhou W,Klinowski J.Synthesis and characterization of the mesoporous silicate molecular sieve MCM-48[J].Journal of Physical Chemistry B, 1997, 101:5294-5300
[21]	Tao Q, He H, Frost R L, Yuan P,Zhu J.Nanomaterials based upon silylated layered double hydroxides[J].Applied Surface Science, 2009, 255(7):4334-4340
[22]	Gupta H,Fan L S.Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas[J].Industrial & Engineering Chemistry Research, 2002, 41(16):4035-4042
[23]	Drage T C, Arenillas A, Smith K M,Snape C E.Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies[J].Microporous and Mesoporous Materials, 2008, 116(1/2/3):504-512
[24]	Bacsik Z, Ahlsten N, Ziadi A, Zhao G, Garcia-Bennett A E, Martín-Matute B,Hedin N.Mechanisms and kinetics for sorption of CO2 on bicontinuous mesoporous silica modified with n-propylamine[J].Langmuir, 2011, 27(17):11118-11128
[25]	Knofel C, Martin C, Hornebecq V,Llewellyn P L.Study of carbon dioxide adsorption on mesoporous aminopropylsilane-functionalized silica and titania combining microcalorimetry and in situ infrared spectroscopy[J].Journal of Physical Chemistry C, 2009, 113(52):21726-21734
[26]	Chang A C C, Chuang S S C, Gray M,Soong Y.In-situ infrared study of CO2 adsorption on SBA-15 grafted with 3-(aminopropyl)triethoxysilane[J].Energy and Fuels, 2003, 17(2):468-473
[27]	Khatri R A, Chuang S S C, Soong Y,Gray M.Carbon dioxide capture by diamine-grafted SBA-15:a combined Fourier transform infrared and mass spectrometry study[J].Industrial & Engineering Chemistry Research, 2005, 44(10):3702-3708
[28]	Wang X, Schwartz V, Clark J C, Ma X, Overbury S H, Xu X,Song C.Infrared study of CO2 sorption over "molecular basket" sorbent consisting of polyethylenimine-modified mesoporous molecular sieve[J].Journal of Physical Chemistry C, 2009, 113(17):7260-7268

氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 28

相关文章 15

编辑推荐

Metrics

本文评价

[1]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[2]	宋瑞涛, 王派, 王云鹏, 李敏霞, 党超镔, 陈振国, 童欢, 周佳琦. 二氧化碳直接蒸发冰场排管内流动沸腾换热数值模拟分析[J]. 化工学报, 2023, 74(S1): 96-103.
[3]	张义飞, 刘舫辰, 张双星, 杜文静. 超临界二氧化碳用印刷电路板式换热器性能分析[J]. 化工学报, 2023, 74(S1): 183-190.
[4]	杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH₃的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755.
[5]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[6]	盛冰纯, 于建国, 林森. 铝基锂吸附剂分离高钠型地下卤水锂资源过程研究[J]. 化工学报, 2023, 74(8): 3375-3385.
[7]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[8]	杨菲菲, 赵世熙, 周维, 倪中海. Sn掺杂的In₂O₃催化CO₂选择性加氢制甲醇[J]. 化工学报, 2023, 74(8): 3366-3374.
[9]	洪瑞, 袁宝强, 杜文静. 垂直上升管内超临界二氧化碳传热恶化机理分析[J]. 化工学报, 2023, 74(8): 3309-3319.
[10]	高燕, 伍鹏, 尚超, 胡泽君, 陈晓东. 基于双流体喷嘴的磁性琼脂糖微球的制备及其蛋白吸附性能探究[J]. 化工学报, 2023, 74(8): 3457-3471.
[11]	陈吉, 洪泽, 雷昭, 凌强, 赵志刚, 彭陈辉, 崔平. 基于分子动力学的焦炭溶损反应及其机理研究[J]. 化工学报, 2023, 74(7): 2935-2946.
[12]	张琦钰, 高利军, 苏宇航, 马晓博, 王翊丞, 张亚婷, 胡超. 碳基催化材料在电化学还原二氧化碳中的研究进展[J]. 化工学报, 2023, 74(7): 2753-2772.
[13]	王杰, 丘晓琳, 赵烨, 刘鑫洋, 韩忠强, 许雍, 蒋文瀚. 聚电解质静电沉积改性PHBV抗氧化膜的制备与性能研究[J]. 化工学报, 2023, 74(7): 3068-3078.
[14]	毛磊, 刘冠章, 袁航, 张光亚. 可捕集CO₂的纳米碳酸酐酶粒子的高效制备及性能研究[J]. 化工学报, 2023, 74(6): 2589-2598.
[15]	王新悦, 王俊杰, 曹思贤, 王翠, 李灵坤, 吴宏宇, 韩静, 吴昊. 玻璃内包材界面修饰对机械应力诱导的单克隆抗体聚集体形成的影响[J]. 化工学报, 2023, 74(6): 2580-2588.

氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO2

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 28

相关文章 15

编辑推荐

Metrics

本文评价

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂