泡沫金属复合相变材料的制备与性能分析

doi:10.3969/j.issn.0438-1157.2013.10.011

化工学报 ›› 2013, Vol. 64 ›› Issue (10): 3565-3570.DOI: 10.3969/j.issn.0438-1157.2013.10.011

泡沫金属复合相变材料的制备与性能分析

盛强^1,2, 邢玉明¹, 王泽¹

1. 北京航空航天大学航空科学与工程学院, 北京 100191;
2. 黑龙江大学建筑工程学院, 黑龙江哈尔滨 150080

收稿日期:2013-02-22 修回日期:2013-04-27 出版日期:2013-10-05 发布日期:2013-10-05
通讯作者: 盛强(1981-),男,博士研究生,讲师
作者简介:盛强(1981-),男,博士研究生,讲师。
基金资助:
国家自然科学基金项目(50876004)

Preparation and performance analysis of metal foam composite phase change material

SHENG Qiang^1,2, XING Yuming¹, WANG Ze¹

1. School of Aeronautics Science and Technology, Beijing University of Aeronautics and Astronautics, Beijing 100191, China;
2. School of Civil Engineering, Heilongjiang University, Harbin 150080, Heilongjiang, China

Received:2013-02-22 Revised:2013-04-27 Online:2013-10-05 Published:2013-10-05
Supported by:
supported by the National Natural Science Foundation of China(50876004).

摘要/Abstract

摘要： 利用泡沫金属多孔结构的吸附性能,以八水氢氧化钡为相变材料,泡沫铜为基体,制备了结晶水合盐/泡沫金属复合相变材料。采用差示扫描量热法测定了八水氢氧化钡的热循环性能,随着热循环次数的增加,相变材料的相变温度基本不变,相变潜热略有减少,八水氢氧化钡具有较好的热稳定性。搭建了相变储能实验台,实验分析了3组不同实验方案,结果表明,填充泡沫铜不仅增强了相变材料的传热速率,而且有效地降低了八水氢氧化钡的过冷度。当泡沫金属使用较大孔密度后,结晶水合盐的过冷问题得到了比较明显的改善。

关键词: 泡沫铜, 相变材料, 热循环, 传热, 结晶水合盐

Abstract: Due to the adsorption performance of porous metal foam structure,a salt hydrate/metal foam composite phase change material(PCM)was prepared by using barium hydroxide octahydrate(Ba(OH)₂·8H₂O)as latent heat storage PCM and copper foams as supporting matrix.The thermal properties of Ba(OH)₂·8H₂O were measured by differential scanning calorimetry after a number of repeated thermal cycles.As the number of thermal cycles increases,the phase change temperature of Ba(OH)₂·8H₂O is almost constant and the latent heat of fusion decreases slightly,which implies that Ba(OH)₂·8H₂O has a good thermal stability.An experimental setup was built to study the heat transfer performance of Ba(OH)₂·8H₂O with/without copper foams.The results show that the high porosity metal foam not only enhances the heat transfer rate of Ba(OH)₂·8H₂O within thermal storage units,but also reduces the supercooling of PCM effectively.The supercooling of salt hydrates can be improved significantly by using larger pores per inch(PPI)metal foams.

Key words: copper foams, phase change material, thermal cycling, heat transfer, salt hydrate

中图分类号:

TK02

盛强, 邢玉明, 王泽. 泡沫金属复合相变材料的制备与性能分析[J]. 化工学报, 2013, 64(10): 3565-3570.

SHENG Qiang, XING Yuming, WANG Ze. Preparation and performance analysis of metal foam composite phase change material[J]. CIESC Journal, 2013, 64(10): 3565-3570.

参考文献 22

[1]	Abhat A.Low temperature latent heat thermal energy storage:heat storage materials[J].Sol.Energy,1983,30(4):313-332
[2]	Zalba B,Marín J M,Cabeza L F,et al.Review on thermal energy storage with phase change:materials,heat transfer analysis and applications[J].Appl.Therm.Eng.,2003,23:251-283
[3]	Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renew.Sustain.Energy Rev.,2009,13:318-345
[4]	Sharma S D,Sagara K.Latent heat storage materials and systems:a review[J].Int.J.Green Energy,2005,2:1-56
[5]	Fan L,Khodadadi J M.Thermal conductivity enhancement of phase change materials for thermal energy storage:a review[J].Renew.Sustain.Energy Rev.,2011,15:24-26
[6]	Fukai J,Kanou M,Kodama Y,et al.Thermal conductivity enhancement of energy storage media using carbon fibers[J].Energy Convers.Manage.,2000,41:1543-1556
[7]	Fukai J,Hamada Y,Morozumi Y,et al.Effect of carbon-fiber brushes on conductive heat transfer in phase change materials[J].Int.J.Heat Mass Transfer,2002,45:4781-4792
[8]	Ettouney H M,Alatiqi I,Al-Sahali M,et al.Heat transfer enhancement by metal screens and metal spheres in phase change energy storage systems[J].Renew.Energy,2004,29:841-860
[9]	Velraj R,Seeniraj R V,Hafner B,et al.Experimental analysis and numerical modeling of inward solidification on a finned vertical tube for a latent heat storage unit[J].Sol.Energy,1997,60(5):281-290
[10]	Stritih U.An experimental study of enhanced heat transfer in rectangular PCM thermal storage[J].Int.J.Heat Mass Transfer,2004,47:2841-2847
[11]	Hosseinizadeh S F,Tan F L,Moosania S M.Experimental and numerical studies on performance of PCM-based heat sink with different configurations of internal fins[J].Appl.Therm.Eng.,2011,31:3827-3838
[12]	Gong Z X,Mujumdar A S.Cyclic heat transfer in a novel storage unit of multiple phase change materials[J].Appl.Therm.Eng.,1996,16(10):807-815
[13]	Zhang Yinping(张寅平),Steiner D,Groll M. Experimental study on characteristics of heat transfer and thermal storage of indirect-contact galisol system[J].Acta Energiae Solaris Sinica(太阳能学报),1998,19(4):352-359
[14]	Zhou D,Zhao C Y.Experimental investigations on heat transfer in phase change materials(PCMs)embedded in porous materials[J].Appl.Therm.Eng.,2011,31:970-977
[15]	Cui H T.Experimental investigation on the heat charging process by paraffin filled with high porosity copper foam[J].Appl.Therm.Eng.,2012,39:26-28
[16]	Wu Zhigen(吴志根),Zhao Changying(赵长颖),Gu Qingzhi(顾清之).Heat transfer enhancement of high temperature thermal energy storage using porous materials[J].CIESC Journal(化工学报),2012,63(S1):119-122
[17]	Zhang Z,Fang X.Study on paraffin/expanded graphite composite phase change thermal energy storage material[J].Energy Convers.Manage.,2006,47:303-310
[18]	Rathod M K,Banerjee J.Thermal stability of phase change materials used in latent heat energy storage systems:a review[J].Renew.Sustain.Energy Rev.,2013,18:246-258
[19]	Naumann R,Emons H H.Results of thermal analysis for investigation of salt hydrates as latent heat-storage materials[J].J.Therm.Anal.,1989,35:1009-1031
[20]	Li Jing(李晶).Study on phase change heat storage material and phase change properties[D].Beijing:Beijing University of Technology,2005
[21]	Zhang Xuemei(张雪梅),Cai Luyin(蔡路茵),Su Zhongjie(苏忠杰),et al.Effects of ultrasound on phase separation and crystallization of sodium acetate trihydrate[J].CIESC Journal(化工学报),2010,61(1):104-108
[22]	Lafdi K,Mesalhy O,Shaikh S.Experimental study on the influence of foam porosity and pore size on the melting of phase change materials[J].J.Appl.Phys.,2007,102:1-5

泡沫金属复合相变材料的制备与性能分析

Preparation and performance analysis of metal foam composite phase change material

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