双极膜电渗析法分离发酵液中乳酸及离子迁移规律

doi:10.3969/j.issn.0438-1157.2014.12.024

化工学报 ›› 2014, Vol. 65 ›› Issue (12): 4823-4830.DOI: 10.3969/j.issn.0438-1157.2014.12.024

双极膜电渗析法分离发酵液中乳酸及离子迁移规律

林晗¹, 汪群慧^1,2, 王丽娟³, 李岩¹, 陈焕玺¹

1. 北京科技大学土木与环境工程学院, 北京 100083;
2. 工业典型污染物资源化处理北京市重点实验室, 北京 100083;
3. 山西省环境科学研究院, 山西太原 030027

收稿日期:2014-05-30 修回日期:2014-07-22 出版日期:2014-12-05 发布日期:2014-12-05
通讯作者: 汪群慧
基金资助:
国际合作项目(2013DFG92600).

Lactic acid recovery from fermentation by bipolar membrane electrodialysis and ionic migration

LIN Han¹, WANG Qunhui^1,2, WANG Lijuan³, LI Yan¹, CHEN Huanxi¹

1. Department of Environmental Engineering, School of Civil and Environmental Engineering, University of Science and Technology, Beijing 100083, China;
2. Beijing Key Laboratory on Resource-oriented Treatment of Industrial Pollutants, Beijing 100083, China;
3. Shanxi Academy of Environmental Science, Taiyuan 030027, Shanxi, China

Received:2014-05-30 Revised:2014-07-22 Online:2014-12-05 Published:2014-12-05
Supported by:
supported by the International Cooperation Project (2013DFG92600).

摘要/Abstract

摘要： 考察了双极膜电渗析法分离酒糟发酵液中乳酸的影响因素,结果表明:当进料浓度13.5 g·L^-1,工作电压27 V,进料浓度比1.3,流量20 L·h^-1,电渗析10 h,产品罐中的乳酸浓度增加至20.95 g·L^-1,是电渗析前进料罐中的乳酸浓度的1.6倍,具有显著的浓缩效果.酸根离子迁移规律的研究表明,乳酸根离子的迁移速率明显高于其他酸根离子,且丙酸和乙酸的乳酸分离率相对较低.

关键词: 发酵, 动力学, 离子迁移, 电渗析, 乳酸, 分离

Abstract: A series of factors were examined in the separation of lactic acid (HLa) from lees fermentation by bipolar membrane electrodialysis. When the fermentation with the initial HLa concentration of 13.5 g·L^-1 was treated by bipolar membrane electrodialysis under the conditions of voltage 27 V, feeding concentration ratio 1.3, and flow rate 20 L·h^-1 for 10 h, HLa concentration of discharging tank was 20.95 g·L^-1, which was 1.6 times the initial concentration, a significant concentrated effect. Moreover, the analysis of acid ion migration shows that immigration rate of lactic acid ions is significantly higher than that of other acid ions. The relative separation efficiency of HLa to propionate and acetic acid are lower.

Key words: fermentation, kinetics, ion mobility, electrodialysis, lactic acid, separation

中图分类号:

林晗, 汪群慧, 王丽娟, 李岩, 陈焕玺. 双极膜电渗析法分离发酵液中乳酸及离子迁移规律[J]. 化工学报, 2014, 65(12): 4823-4830.

LIN Han, WANG Qunhui, WANG Lijuan, LI Yan, CHEN Huanxi. Lactic acid recovery from fermentation by bipolar membrane electrodialysis and ionic migration[J]. CIESC Journal, 2014, 65(12): 4823-4830.

参考文献 20

[1]	Ye L, Zhou X, Hudari M S B, Li Z, Wu J C. Highly efficient production of l-lactic acid from xylose by newly isolated Bacillus coagulans C106 [J]. Bioresource Technology, 2013, 132: 38-44
[2]	Ouyang J, Ma R, Zheng Z, Cai C, Zhang M, Jiang T. Open fermentative production of l-lactic acid by Bacillus sp. strain NL01 using lignocellulosic hydrolyzates as low-cost raw material [J]. Bioresource Technology, 2013, 135: 475-480
[3]	Shen Xueliang (沈雪亮), Xia Liming (夏黎明). Synergetic saccharification and lactic acid fermentation by coimmobilized cells using cellulosic materials [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2008, 59 (1): 167-172
[4]	Xu Zhong (徐忠), Wang Qunhui (汪群慧), Jiang Zhaohua (姜兆华). Enzymatic hydrolysis of soybean straw and l-lactic acid fermentation [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2004, 55 (11): 1849-1852
[5]	Yan Zhihui (闫智慧), Gao Jing (高静), Zhou Liya (周丽亚), Zhao Xueming (赵学明). Review on application and production technology of lactic acid by fermentation [J]. Journal of Hebei University of Technology (河北工业大学学报), 2004, 33 (3): 15-19
[6]	Shi Anhui (施安辉). Present and future of environmentally friendly distillers' grains in China [J]. China Brewing (中国酿造), 2006 (3): 4-7
[7]	Abdel-Rahman M A, Tashiro Y, Sonomoto K. Recent advances in lactic acid production by microbial fermentation processes [J]. Biotechnology Advances, 2013, 31 (6): 877-902
[8]	Yuan Jie (袁颉), Qiu Shuyi (邱树毅), Peng Zhengdong (彭正东). Research advance in the reclamation of distiller's grains in liquor production by solid fermentation [J]. Liquor-Making Science & Technology (酿酒科技), 2012 (5): 88-91
[9]	Tonova K, Svinyarov I, Bogdanov M G. Hydrophobic 3-alkyl-1-methylimidazolium saccharinates as extractants for l-lactic acid recovery [J]. Separation and Purification Technology, 2014, 125: 239-246
[10]	Xu Zhiyong (徐芝勇), Zhang Jianguo (张建国). Applications of bipolar membrane electrodialysis in the production of organic acids [J].Membrane Science and Technology (膜科学与技术), 2007, 27 (3): 75-79
[11]	Cheng Guishi (程桂石), Wang Qunhui (汪群慧), Qi Hong (齐虹),Sun Xiaohong (孙晓红), Zhao Ying (赵莹). Effects of pH on recovery of lactic acid from kitchen garbage fermentation broth by electrodialysis [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2005, 56 (11): 2200-2203
[12]	Cheng G, Wang Q, Sun X, Meng H, Li J. Experimental study on concentration of ammonium lactate solution from kitchen garbage fermentation broth by two-compartment electrodialysis [J]. Separation and Purification Technology, 2008, 62 (1): 205-211
[13]	Wang Q, Cheng G, Sun X, Jin B. Recovery of lactic acid from kitchen garbage fermentation broth by four-compartment configuration electrodialyzer [J]. Process Biochemistry, 2006, 41 (1): 152-158
[14]	Zhang Meng (张猛), Ma Li (马利), Yang Jichu (杨基础), Xu Yongmao (徐用懋). Non-equilibrium stage static simulation of lactic acid purification reactive distillation process [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2005, 56 (6): 1031-1034
[15]	Wu Yuqiong (吴宇琼), Li Dinghuo (李定或), Wu Yuanxin (吴元欣). Research progress in extraction and purification of lactic acid produced by fermentation [J]. Science and Technology of Food Industry (食品工业科技), 2003, 24 (1): 106-108
[16]	Wang Qunhui (汪群慧), Cheng Guishi (程桂石), Yu Xiujuan (于秀娟), Sun Lixin (孙丽欣). Recovery of lactic acid from fermentation broths of kitchen garbage by electrodialysis [J]. Journal of Harbin Institute of Technology (哈尔滨工业大学学报), 2005, 37 (3): 314-316
[17]	Zhang Caihua (张才华), Wang Kun (王昆), Li Weixing (李卫星), Fan Yiqun (范益群), Xing Weihong (邢卫红). Influence factors for extracting lactic acid with bipolar membrane electrodialysis [J]. Journal of Nanjing University of Technology: Natural Science Edition (南京工业大学学报:自然科学版), 2012, 34 (5): 65-69
[18]	Nie Yongfeng (聂永丰). Waste Treatment Engineering Technical Manual: Solid Waste Volume (三废处理工程技术手册: 固体废物卷) [M]. Beijing: Chemical Industry Press, 2000: 179
[19]	Kemperman A J B. Handbook on Bipolar Membrane Technology (双极膜技术手册) [M]. Xu Tongwen (徐铜文), Fu Rongqiang (傅荣强), trans. Beijing: Chemical Industry Press, 2004: 13-14
[20]	Wilhelm F G, Pünt I, van der Vegt N F A,Wessling M, Strathmann H. Optimisation strategies for the preparation of bipolar membranes with reduced salt ion leakage in acid-base electrodialysis [J]. Journal of Membrane Science, 2001, 182 (1/2): 13-28

双极膜电渗析法分离发酵液中乳酸及离子迁移规律

Lactic acid recovery from fermentation by bipolar membrane electrodialysis and ionic migration

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