疏水SiO2/PTFPMS杂化复合膜的制备及其气体分离性能

doi:10.3969/j.issn.0438-1157.2014.08.024

化工学报

疏水SiO₂/PTFPMS杂化复合膜的制备及其气体分离性能

聂飞¹, 贺高红¹, 赵薇², 鞠佳¹, 李皓¹

1 大连理工大学化工学院, 辽宁大连 116024;
2 沈阳化工大学石油化工学院, 辽宁辽阳 111003

收稿日期:2013-09-26 修回日期:2013-12-11 出版日期:2014-08-05 发布日期:2014-08-05
通讯作者: 贺高红
基金资助:
国家杰出青年科学基金项目（21125628）；国家高技术研究发展计划项目（2012AA03A611）。

Preparation and gas separation performance of hydrophobic SiO₂/PTFPMS hybrid composite membrane

NIE Fei¹, HE Gaohong¹, ZHAO Wei², JU Jia¹, LI Hao¹

1 School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
2 School of Chemical Engineering, Shenyang University of Technology Liaoyang Campus, Liaoyang 111003, Liaoning, China

Received:2013-09-26 Revised:2013-12-11 Online:2014-08-05 Published:2014-08-05
Supported by:
supported by the National Science Fund for Distinguished Young Scholars of China (21125628) and the National High Technology Research and Development Program of China (2012AA03A611).

摘要/Abstract

摘要： 为了提高气体分离膜的耐溶胀特性，以多孔聚醚酰亚胺（PEI）为支撑层，采用溶液共混法制备了疏水SiO₂/PTFPMS杂化复合膜，研究了疏水SiO₂质量共混比对膜形态、耐溶胀性以及不同操作压差下的纯气渗透分离性能的影响。光学显微照片显示，当共混比不超过0.018时，杂化膜的透明度较高，表明疏水SiO₂与PTFPMS具有较好的相容性；当SiO₂与PTFPMS的共混比超过0.018时，SiO₂团聚明显。SEM表征结果显示，杂化膜表面光洁，断面杂化涂层紧密贴合支撑层。疏水SiO₂/PTFPMS杂化膜在异辛烷中的溶胀度为0，在乙酸乙酯中的溶胀度比PTFPMS均质膜的下降了11.9%，显示了其优异的耐溶胀性能。在操作压力为1.0 MPa，操作温度为25℃下，SiO₂共混比为0.012时，疏水SiO₂/PTFPMS杂化复合膜的CO₂渗透通量达到最高156.1GPU，CO₂/N₂选择性为15.86。

关键词: PTFPMS, 气体分离, 膜, 复合材料, 二氧化硅

Abstract: To improve the solvent resistance property of gas separation membrane, a hydrophobic SiO₂/polytrifluoropropylsiloxane (PTFPMS) hybrid composite membrane was fabricated on a porous polyetherimide (PEI) support with solution blending method. The effects of mass ratio of hydrophobic SiO₂ to PTFPMS on the membrane morphology, solvent resistance, and gas separation performance of the hydrophobic SiO₂/PTFPMS hybrid composite membrane were investigated. The optical microscope images show good miscibility between SiO₂ and PTFPMS with the increase of blend ratio till 0.018. At blend ratios higher than 0.018, SiO₂ particles exhibit obvious aggregation in the hybrid membrane. SEM images show that no obvious defect is on the surface of the SiO₂/PTFPMS selective layer that is closely stuck on the PEI support. The swelling degree of the hydrophobic SiO₂/PTFPMS hybrid homogeneous film is 0 in nonpolar solvent octane and is declined by 11.9% in polar solvent ethyl acetate compared with PTFPMS homogeneous film, indicating the improved solvent resistance of the SiO₂/PTFPMS hybrid homogeneous film. The CO₂ gas permeation rate can reach as high as 156.1 GPU and the selectivity of CO₂/N₂ is 15.86 when the blend ratio of SiO₂ is 0.012 under the transmembrane pressure difference up to 1.0 MPa.

Key words: PTFPMS, gas separation, membrane, composite, silica

中图分类号:

TQ028.8

聂飞, 贺高红, 赵薇, 鞠佳, 李皓. 疏水SiO₂/PTFPMS杂化复合膜的制备及其气体分离性能[J]. 化工学报, DOI: 10.3969/j.issn.0438-1157.2014.08.024.

NIE Fei, HE Gaohong, ZHAO Wei, JU Jia, LI Hao. Preparation and gas separation performance of hydrophobic SiO₂/PTFPMS hybrid composite membrane[J]. CIESC Journal, DOI: 10.3969/j.issn.0438-1157.2014.08.024.

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疏水SiO₂/PTFPMS杂化复合膜的制备及其气体分离性能

Preparation and gas separation performance of hydrophobic SiO₂/PTFPMS hybrid composite membrane

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