离子交换容量可控自交联型阴离子交换膜的制备

doi:10.11949/j.issn.0438-1157.20150362

CIESC Journal ›› 2015, Vol. 66 ›› Issue (S1): 237-241.DOI: 10.11949/j.issn.0438-1157.20150362

离子交换容量可控自交联型阴离子交换膜的制备

张雪飞^1,2, 王树博², 费哲君², 李薇薇², 赵阳², 谢晓峰², 齐士成¹, 吕亚非¹

1 北京化工大学材料科学与工程学院, 北京 100029;
2 清华大学核能与新能源技术研究院, 北京 100084

收稿日期:2015-03-20 修回日期:2015-03-27 出版日期:2015-06-30 发布日期:2015-06-30
通讯作者: 齐士成, 谢晓峰
基金资助:
国家高技术研究发展计划项目(2012AA051201);国家重点基础研究发展计划项目( 2012CB215505)。

Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes

ZHANG Xuefei^1,2, WANG Shubo², FEI Zhejun², LI Weiwei², ZHAO Yang², XIE Xiaofeng², QI Shicheng¹, LÜ Yafei¹

1 College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Received:2015-03-20 Revised:2015-03-27 Online:2015-06-30 Published:2015-06-30
Supported by:
supported by the National High Technology Research and Development Program of China (2012AA051201) and the National Basic Research Program of China( 2012CB215505).

摘要/Abstract

摘要： 以N-溴代丁二酰亚胺(NBS)为溴化试剂, 对十氟二唑与四甲基双酚A(TM-BPA)聚合的聚合物主链进行溴化, 随后以N-乙烯基咪唑作为双功能化试剂进行功能化, 制备了含有双功能化试剂的氟化聚二唑芳醚阴离子交换膜。其中, 功能化试剂(作为离子交换的功能基传导离子及作为膜内分子的交联点)改善膜物理性质。制备的阴离子交换膜在80℃下的离子传导率为9.02×10^-2 S·cm^-1, 甲醇渗透率为1.89×10^-7 cm²·s^-1(20℃), 在碱性燃料电池中具有应用潜力。

关键词: 电解质, 自交联, 双功能化试剂, 渗透率, 燃料电池

Abstract: Functionalized fluorinated poly (arylene ether oxadiazole) (FPAEO) based cross-linked anion exchange membranes (AEMs) with bifunctional agents were prepared via copolymerization, bromination and solution casting using a thermal cross-linking method. FPAEO-TM synthesized via copolymerization of 4, 4'-isopropylidenebis (2, 6-dimethylphenol) (TM-BPA) and 2, 5-bis(2, 3, 4, 5, 6-pentafluorophenyl)-1, 3, 4- oxadiazole(FPOx) was brominated by N-bromosuccinimide (NBS), thereby avoiding chloromethylation, which required carcinogenic reagents. 1-vinylimidazole acted as a bifunctional agent and played two roles: it served as an ion exchange functional group which provided membranes high conductivity, or as a crosslinking agent to improve the membranes' characteristics. The mambrane's conductivity is 9.02×10^-2 S·cm^-1 at 80℃ and methanol permeability is 1.89×10^-7 cm²·s^-1(20℃). Membranes had the potential to be used in alkaline fuel cell alkaline (AFC).

Key words: electrolytes, self-cross-linking, bifunctional agent, permeability, fuel cells

中图分类号:

TQ152

张雪飞, 王树博, 费哲君, 李薇薇, 赵阳, 谢晓峰, 齐士成, 吕亚非. 离子交换容量可控自交联型阴离子交换膜的制备[J]. CIESC Journal, 2015, 66(S1): 237-241.

ZHANG Xuefei, WANG Shubo, FEI Zhejun, LI Weiwei, ZHAO Yang, XIE Xiaofeng, QI Shicheng, LÜ Yafei. Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes[J]. , 2015, 66(S1): 237-241.

参考文献 15

[1]	Yang Congrong, Wang Suli, Jiang Luhua, Sun Gongquan, HuJinbo, Ma Wenjia. 1, 2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells [J]. International Journal of Hydrogen Energy, 2015, 40(5): 2363-2370.
[2]	Sarma Loka Subramanyam, Chen Ching-Hsiang, Wang Guo-Rung. Investigations of direct methanol fuel cell (DMFC) fading mechanisms [J]. Journal of Power Sources, 2007, 167(2): 358-365.
[3]	Vega J A, Chartier C, Mustain W E. Effect of hydroxide and carbonate alkaline media on anion exchange membranes [J]. Journal of Power Sources, 2010, 195(21): 7176-7180.
[4]	Liu Zhi, Zhu Xiuling, Wang Guangfu. Novel crosslinked alkaline exchange membranes based on poly(phthalazinone ether ketone) for anion exchange membrane fuel cell applications [J]. Journal of Polymer Science Part B: Polymer Physics, 2013, 51(22): 1632- 1639.
[5]	Zhang Shiman, Li Cunpu, Xie Xiaofeng. Novel cross-linked anion exchange membranes with diamines as ionic exchange functional groups and crosslinking groups [J]. International Journal of Hydrogen Energy, 2014, 39(25): 13718-13724.
[6]	Zhao Chengji, Ma Wenjia, Sun Wenmo, Na Hui. Preparation of anion exchange membrane based on homogeneous quaternization of bromomethylated poly(arylene ether sulfone) [J]. Journal of Applied Polymer Science, 2014, 131(10): 40256.
[7]	Lin Xiaochen, Liang Xuhao, Poynton Simon D, Varcoe John R, Ong Ai Lien, Ran Jin, Li Yan, Li Qiuhua, Xu Tongwen. Novel alkaline anion exchange membranes containing pendant benzimidazolium groups for alkaline fuel cells [J]. Journal of Membrane Science, 2013, 443: 193-200.
[8]	Wang Wenpin, Wang Shubo, Li Weiwei, Xie Xiaofeng, Lv Yafei. Synthesis and characterization of a fluorinated cross-linked anion exchange membrane [J]. International Journal of Hydrogen Energy, 2013, 38(25): 11045-11052.
[9]	Li Weiwei, Wang Shubo, Zhang Xuefei, Wang Wenpin, Xie Xiaofeng, Pei Pucheng. Degradation of guanidinium-functionalized anion exchange membrane during alkaline environment [J]. International Journal of Hydrogen Energy, 2014, 39(25): 13710- 13717.
[10]	Zhang Shouhai, Zhang Bengui, Xing Dongbo, Jian Xigao. Poly(phthalazinone ether ketone ketone) anion exchange membranes with pyridinium as ion exchange groups for vanadium redox flow battery applications [J]. Journal of Materials Chemistry A, 2013, 1(39): 12246-12254.
[11]	Gu Fenglou, Dong Huilong, Li Youyong, Si Zhihong, Yan Feng. Highly stable N3-substituted imidazolium-based alkaline anion exchange membranes: experimental studies and theoretical calculations [J]. Macromolecules, 2014, 47(1): 208-216.
[12]	Srinophakun, Thongchai, Martkumchan, Suwalee. Ionic conductivity in a chitosan membrane for a PEM fuel cell using molecular dynamics simulation [J]. Carbohydrate Polymers, 2012, 88(1): 194-200.
[13]	Ding Jianfu, Michael Day. Novel highly fluorinated poly(arylene ether-1, 3, 4-oxadiazole)s, their preparation, and sensory properties to fluoride anion [J]. Macromolecules, 2006, 39(18): 6054-6062.
[14]	Li Cunpu, Wang Shubo, Wang Wenpin, Xie Xiaofeng, Lv Yafei, Deng Changsheng. A cross-linked fluorinated poly(aryl ether oxadiazole)s using a thermal cross-linking for anion exchange membranes [J]. International Journal of Hydrogen Energy, 2013, 38(25): 11038-11044.
[15]	Zhang Yang, Fei Xu, Zhang Gang, Li Hongtao, Shao Ke, Zhu Jing, Zhao Chengji, Liu Zhongguo, Han Miaomiao, Na Hui. Preparation and properties of epoxy-based cross-linked sulfonated poly(arylene ether ketone) proton exchange membrane for direct methanol fuel cell applications [J]. International Journal of Hydrogen Energy, 2010, 35(12): 6409-6417.

离子交换容量可控自交联型阴离子交换膜的制备

Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献 15

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈哲文, 魏俊杰, 张玉明. 超临界水煤气化耦合SOFC发电系统集成及其能量转化机制[J]. 化工学报, 2023, 74(9): 3888-3902.
[2]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[3]	张蒙蒙, 颜冬, 沈永峰, 李文翠. 电解液类型对双离子电池阴阳离子储存行为的影响[J]. 化工学报, 2023, 74(7): 3116-3126.
[4]	贾晓宇, 杨剑, 王博, 林梅, 王秋旺. 金属丝网毛细特性的孔隙尺度数值分析[J]. 化工学报, 2023, 74(5): 1928-1938.
[5]	罗来明, 张劲, 郭志斌, 王海宁, 卢善富, 相艳. 1~5 kW高温聚合物电解质膜燃料电池堆的理论模拟与组装测试[J]. 化工学报, 2023, 74(4): 1724-1734.
[6]	钱志广, 樊越, 王世学, 岳利可, 王金山, 朱禹. 吹扫条件对PEMFC阻抗弛豫现象和低温启动的影响[J]. 化工学报, 2023, 74(3): 1286-1293.
[7]	程伟江, 汪何琦, 高翔, 李娜, 马赛男. 锂离子电池硅基负极电解液成膜添加剂的研究进展[J]. 化工学报, 2023, 74(2): 571-584.
[8]	郭祥, 乔金硕, 王振华, 孙旺, 孙克宁. 碳燃料固体氧化物燃料电池结构研究进展[J]. 化工学报, 2023, 74(1): 290-302.
[9]	雍加望, 赵倩倩, 冯能莲. 基于非线性动态模型的质子交换膜燃料电池故障诊断[J]. 化工学报, 2022, 73(9): 3983-3993.
[10]	张婉晨, 陈晓阳, 吕秋秋, 钟秦, 朱腾龙. Co掺杂SrTi_0.3Fe_0.7O_3-_δ 阳极SOFC在化工副产气燃料下的性能及稳定性[J]. 化工学报, 2022, 73(9): 4079-4086.
[11]	邵健, 冯军宗, 柳凤琦, 姜勇刚, 李良军, 冯坚. 酚醛树脂基炭微球结构调控与功能化制备研究进展[J]. 化工学报, 2022, 73(9): 3787-3801.
[12]	方辉煌, 程金星, 罗宇, 陈崇启, 周晨, 江莉龙. 氨电氧化催化剂及其低温直接氨碱性膜燃料电池性能的研究进展[J]. 化工学报, 2022, 73(9): 3802-3814.
[13]	张童, 杨扬, 叶丁丁, 陈蓉, 朱恂, 廖强. 催化剂分布对可渗透阳极微流体燃料电池性能特性影响的研究[J]. 化工学报, 2022, 73(9): 4156-4162.
[14]	艾承燚, 乔金硕, 王振华, 孙旺, 孙克宁. 原位析出纳米合金的PrBaFe₂O_6-_δ 基阳极构筑及其在固体碳燃料电池中的应用研究[J]. 化工学报, 2022, 73(8): 3708-3719.
[15]	葛旺鑫, 朱以华, 江宏亮, 李春忠. 二氧化碳电还原的电解质研究进展[J]. 化工学报, 2022, 73(8): 3433-3447.