典型PPCPs与纳米铜颗粒理化性质的交互影响

doi:10.11949/j.issn.0438-1157.20160228

化工学报 ›› 2016, Vol. 67 ›› Issue (10): 4455-4460.DOI: 10.11949/j.issn.0438-1157.20160228

典型PPCPs与纳米铜颗粒理化性质的交互影响

孟迪, 陈红, 薛罡

东华大学环境科学与工程学院, 上海 201620

收稿日期:2016-03-01 修回日期:2016-06-22 出版日期:2016-10-05 发布日期:2016-10-05
通讯作者: 陈红
基金资助:
国家自然科学基金项目（51508081）；中国博士后科学基金项目（2015M581499）；中国博士后科学基金特别资助项目（2016T90322）。

Interaction effects of typical PPCPs and copper nanoparticles on physical-chemical properties

MENG Di, CHEN Hong, XUE Gang

College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China

Received:2016-03-01 Revised:2016-06-22 Online:2016-10-05 Published:2016-10-05
Supported by:
supported by the National Natural Science Foundation of China (51508081), the China Postdoctoral Science Foundation (2015M581499) and the Special Financial Grant of China Postdoctoral Science Foundation (2016T90322).

摘要/Abstract

摘要：

药品和个人护理用品（PPCPs）、金属纳米颗粒（NPs）等物质在环境中共存时，由于交互作用可能引起理化性质的改变，从而表现出有别于单一物质的复合毒性影响。分别对四环素和纳米铜、三氯生和纳米铜在水溶液中进行交互作用后物质理化性质的变化进行了研究。研究结果表明：四环素在与纳米铜作用过程中发生降解，浓度显著降低；三氯生在与纳米铜作用过程中主要吸附在纳米铜表面，引起浓度降低；另外，PPCPs作用于纳米铜时可能使其表面性质发生改变，从而显著促进Cu²⁺的溶出。因此PPCPs和纳米铜在水溶液中交互作用后理化性质都发生了不同类型、不同程度的改变。

关键词: 药品和个人护理用品, 金属纳米颗粒, 交互作用, 理化性质, 降解, 吸附, 团聚

Abstract:

When substances, such as pharmaceutical and personal care products (PPCPs) and metal nanoparticles (NPs) coexist in environment, their physical-chemical properties might be changed under the interaction process, which would result in their combined toxicity different from the single one. After the interactions of tetracycline and copper nanoparticles (CuNPs), triclosan and CuNPs in aqueous solution, and their physical-chemical property changes were investigated. The results indicated that the concentration of tetracycline decreasing mainly because of its degradation caused by CuNPs, and the adsorption of triclosan on CuNPs resulted in the triclosan concentration declining. In addition, the amount of dissolved Cu²⁺ from CuNPs was significantly increased probably due to its surface property change caused by tetracycline and triclosan. Thus, both the PPCPs and NPs had physical-chemical property changes in different type and various degrees under the interaction process.

Key words: pharmaceutical and personal care products, metal nanoparticles, interaction, physical-chemical property, degradation, adsorption, agglomeration

中图分类号:

X522

孟迪, 陈红, 薛罡. 典型PPCPs与纳米铜颗粒理化性质的交互影响[J]. 化工学报, 2016, 67(10): 4455-4460.

MENG Di, CHEN Hong, XUE Gang. Interaction effects of typical PPCPs and copper nanoparticles on physical-chemical properties[J]. CIESC Journal, 2016, 67(10): 4455-4460.

参考文献 20

[1]	乔铁军, 张锡辉, Doris W T AU. 活性炭工艺去除水中典型药品的效能与机理[J]. 化工学报, 2012, 63(4):1243-1248. QIAO T J, ZHANG X H, DORIS W T AU. Performance and mechanism of typical pharmaceuticals removed by granular activated carbon from water[J]. CIESC Journal, 2012, 63(4):1243-1248.
[2]	王晓, 严媛媛, 张萍, 等. 新兴污染物对污泥厌氧发酵的影响及其厌氧降解研究进展[J]. 化工进展, 2014, 33(12):3379-3386. WANG X, YAN Y Y, ZHANG P, et al. Research progress of effect of emerging contaminants on sludge anaerobic fermentation and their anaerobic degradation[J]. Chemical Industry and Engineering Progress, 2014, 33(12); 3379-3386.
[3]	温智皓, 段艳平, 孟祥周, 等. 城市污水处理厂及其受纳水体中5种典型PPCPs的赋存特征和生态风险[J]. 环境科学, 2013, 34(3):927-932. WEN Z H, DUAN Y P, MENG X Z, et al. Occurrence and risk assessment of five selected PPCPs in municipal wastewater treatment plant and the receiving water[J]. Environmental Science, 2013, 34(3):927-932.
[4]	徐维海, 张干, 邹世春, 等. 香港维多利亚港和珠江广州河段水体中抗生素的含量特征及其季节变化[J]. 环境科学, 2006, 27(12):2458-2462. XU W H, ZHANG G, ZOU S C, et al. Occurrence and seasonal changes of antibiotics in the Victoria Harbour and the Pearl River, South China[J]. Environmental Science, 2006, 27(12):2458-2462.
[5]	SACHER F, LANGE F T, BRAUCH H J, et al. Pharmaceuticals in groundwaters analytical methods and results of a monitoring program in Baden-Wurttemberg, Germany[J]. Journal of Chromatography A, 2001, 938(s 1/2):199-210.
[6]	贾俊彩, 王锋, 余济美. 斑马鱼在纳米金属及金属氧化物毒性研究中的应用[J]. 环境化学, 2011, 30(1):153-157. JIA J C, WANG F, YU J M. Application of zebrafish in the toxicity study of metal and metal oxide nanoparticles[J]. Environmental Chemistry, 2011, 30(1):153-157.
[7]	BIJU V, ITOH T, ANAS A, et al. Semiconductor quantum dots and metal nanoparticles:syntheses, optical properties, and biological applications[J]. Analytical & Bioanalytical Chemistry, 2008, 391(7):2469-2495.
[8]	CINCINELLI A, MARTELLINI T, COPPINI E, et al. Nanotechnologies for removal of pharmaceuticals and personal care products from water and wastewater[J]. Journal of Nanoscience and Nanotechnology, 2015, 15(5):3333-3347.
[9]	VAN WIEREN E M, SEYMOUR M D, PETERSON J W. Interaction of the fluoroquinolone antibiotic, ofloxacin, with titanium oxide nanoparticles in water:adsorption and breakdown[J]. Science of the Total Environment, 2012(20), 441(20):1-9.
[10]	黄文, 周梅芳. Fe3O4/SDS磁性纳米颗粒吸附水体中的Cd+和Zn+[J]. 环境工程学报, 2012, 6(4):1251-1256. HUANG W, ZHOU M F. SDS coated Fe3O4 magnetic nanoparticles for adsorption of Cd+ and Zn+ in aqueous solution[J]. Chinese Journal of Environmental Engineering, 2012, 6(4):1251-1256.
[11]	PAUL W, YEOMIN Y, SHANE S, et al. Fate of endocrine-disruptor, pharmaceutical, and personal care product chemicals during simulated drinking water treatment processes[J]. Environmental Science & Technology, 2005, 39(17):6649-6663.
[12]	MISRA S K, DYBOWSKA A, BERHANU D, et al. The complexity of nanoparticle dissolution and its importance in nanotoxicological studies[J]. Science of the Total Environment, 2012, 438(3):225-232.
[13]	李阳, 朱军峰, 张驰,等. 水中金属纳米颗粒对细菌的光致毒性机理[J]. 化学进展, 2014, 26(2/3):436-449. LI Y, ZHU J F, ZHANG C, et al. Photoinduced toxic mechanism of metallic nanoparticles toward bacteria in water[J]. Progress in Chemistry, 2014, 26(2/3):436-449.
[14]	王晰, 马春宏, 朱红,等. 离子液体萃取分光光度法测定水中四环素类抗生素[J]. 中国给水排水, 2010, 26(8):90-92. WANG X, MA C H, ZHU H, et al. Determination of tetracycline antibiotics by ionic liquid extraction and spectrophotometry[J]. China Water & Wastewater, 2010, 26(8):90-92.
[15]	李志刚. 基于固相萃取-高效液相色谱法的纺织品中三氯生的测定[J]. 纺织学报, 2014, 35(3):98-102. LI Z G. Determination of triclosan in textiles by solid phase extraction-high performance liquid chromatography[J]. Journal of Textile Research, 2014, 35(3):98-102.
[16]	陆祎品, 江淼, 郑芳芳. 多孔树脂及碳纳米管对环丙沙星的吸附行为与机理[J]. 化工学报, 2012, 63(11):3567-3573. LU Y P, JIANG M, ZHENG F F. Adsorption behavior and mechanism of ciprofloxacin[J]. CIESC Journal, 2012, 63(11):3567-3573.
[17]	YANG K, XING B. Desorption of polycyclic aromatic hydrocarbons from carbon nanomaterials in water[J]. Environmental Pollution, 2007, 145(2):529-537.
[18]	GUNAWAN C, TEOH W Y, MARQUIS C P, et al. Cytotoxic origin of copper(Ⅱ) oxide nanoparticles:comparative studies with micron-sized particles, leachate, and metal salts[J]. ACS Nano, 2011, 5(9):7214-7225.
[19]	巩宁, 邵魁双, 梁长华, 等. 两种粒径氧化镍纳米颗粒对小球藻的生物毒性[J]. 海洋环境科学, 2011, 30(4):457-460. GONG N, SHAO K S, LIANG C H, et al. Biotoxicity of two-size nickel oxide nanoparticles on Chlorella vulgaris[J]. Marine Environmental Science, 2011, 30(4):457-460.
[20]	CHOWDHURY I, CWIERTNY D M, WALKER S L. Combined factors influencing the aggregation and deposition of nano-TiO2 in the presence of humic acid and bacteria[J]. Environmental Science & Technology, 2012, 46(13):6968-6976.

典型PPCPs与纳米铜颗粒理化性质的交互影响

Interaction effects of typical PPCPs and copper nanoparticles on physical-chemical properties

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