氨丙基离子液体水溶液CO2吸收特性及计算模型

doi:10.11949/j.issn.0438-1157.20150732

化工学报 ›› 2015, Vol. 66 ›› Issue (S2): 238-243.DOI: 10.11949/j.issn.0438-1157.20150732

氨丙基离子液体水溶液CO₂吸收特性及计算模型

李松, 杨翠莲, 毕崟, 郭开华

中山大学工学院, 广东广州 510006

收稿日期:2015-05-27 修回日期:2015-06-12 出版日期:2015-08-31 发布日期:2015-08-31
通讯作者: 郭开华
基金资助:
国家自然科学基金项目(51076169);广东省自然科学基金重点项目(9251027501000001)。

Properties and mathematical model of carbon dioxide solubility in aminopropyl ionic liquid aqueous solutions

LI Song, YANG Cuilian, BI Yin, GUO Kaihua

School of Engineering, Sun Yat-Sen University, Guangzhou 510006, Guangdong, China

Received:2015-05-27 Revised:2015-06-12 Online:2015-08-31 Published:2015-08-31
Supported by:
supported by the National Natural Science Foundation of China(51076169)and the Key Program of the Natural Science Foundation of Guangdong Province(9251027501000001).

摘要/Abstract

摘要：

氨丙基功能型离子液体对CO₂具有良好的选择吸收特性,以[APMim]Br离子液体水溶液体系为例,在有效吸收(水含量大于55%)区间,水含量对CO₂的化学吸收和物理吸收都具有显著影响。依据[APMim]Br水溶液在278.15~348.15 K,0.1~4.5 MPa,水质量分数为55.90%、64.50%、76.80%和85.80%范围的CO₂吸收特性数据,对溶液体系的化学吸收和物理吸收模型进行分析研究,获得两种吸收机理的数学表达,并对实验数据进行回归分析,得到能够正确反映化学吸收和物理吸收的计算模型。结果表明,低压下化学吸收占主导作用,随水含量增大,溶液体系对CO₂吸收能力成倍增加,而且产生的物理吸收效应远大于离子液体本身的化学吸收能力。水的质量分数在0.65~0.85区间,[APMim]Br水溶液在相当大的温度和压力范围内具有优良的CO₂吸放气特性,显示出良好的工程应用前景。

关键词: 离子液体, 水溶液, 水含量, 二氧化碳, 吸收性能

Abstract:

Aminopropyl functional ionic liquids exhibit a good selectivity for carbon dioxide(CO₂)absorption.In order to reveal the effects of water concentration on the CO₂ solubility in 1-aminopropyl-3-methylimidazolium bromide([APMim]Br)aqueous solutions,the experiments based on an isochoric technique by using a high-pressure quartz glass cell were performed to test the solutions of 55.90%,65.78%,76.80% and 85.76% water mass fractions.The equilibrium data for CO₂ solubility in these aqueous solutions were obtained in range of 278.15-348.15 K and 0.1-4.5 MPa.A mathematical model that can correctly reflect the experimental data changes was obtained by mechanism analysis of absorption.The results indicated that the chemical absorption mechanism is predominant at lower pressure while the CO₂ solubility can be doubled comparing to the chemical one when the water concentration increased and the physical absorption ability prevailed.In 65%-85% water mass fraction,the solutions have an excellent CO₂ absorption and release ability in considerable large temperature and pressure ranges and may have a promised future for engineering application.

Key words: ionic liquid, aqueous solution, water concentration, carbon dioxide, absorption property

中图分类号:

TQ028.15

李松, 杨翠莲, 毕崟, 郭开华. 氨丙基离子液体水溶液CO₂吸收特性及计算模型[J]. 化工学报, 2015, 66(S2): 238-243.

LI Song, YANG Cuilian, BI Yin, GUO Kaihua. Properties and mathematical model of carbon dioxide solubility in aminopropyl ionic liquid aqueous solutions[J]. CIESC Journal, 2015, 66(S2): 238-243.

参考文献 28

[1]	Energy Information Administration.International energy outlook[R].Washington,D.C.:Energy Information Administration,2008.
[2]	Blanchard L A,Gu Zhiyong,Brennecke J F.High-pressure phase behavior of ionic liquid/CO2 systems[J].The Journal of Physical Chemistry B,2001,105(12):2437-2444.
[3]	Huang Junhua,Rüther T.Why are ionic liquids attractive for CO2 absorption[J].Australian Journal of Chemistry,2009,62(4):298-308.
[4]	Blanchard L A,Hancu D,Beckman&Amp E J,et al.Green processing using ionic liquids and CO2[J].Nature,1999,399(6731):28-29.
[5]	Jacquemin J,Husson P,Majer V,et al.Influence of the cation on the solubility of CO2 and H2 in ionic liquids based on the bis(trifluoromethylsulfonyl)imide anion[J].Journal of Solution Chemistry,2007,36(8):967-979.
[6]	Hong G,Jacquemin J,Deetlefs M,et al.Solubility of carbon dioxide and ethane in three ionic liquids based on the bis{(trifluoromethyl)sulfonyl}imide anion[J].Fluid Phase Equilibria,2007,257(1):27-34.
[7]	Pérez-Salado Kamps Á,Tuma D,Xia Jianzhong,et al.Solubility of CO2 in the Ionic Liquid[bmim] [PF6] [J].Journal of Chemical & Engineering Data,2003,48(3):746-749.
[8]	Husson-Borg P,Majer V,Costa Gomes M F.Solubilities of oxygen and carbon dioxide in butyl methyl imidazolium tetrafluoroborate as a function of temperature and at pressures close to atmospheric pressure[J].Journal of Chemical & Engineering Data,2003,48(3):480-485.
[9]	Baltus R E,Culbertson B H,Dai Sheng,Luo Huimin,et al.Low-pressure solubility of carbon dioxide in room-temperature ionic liquids measured with a quartz crystal microbalance[J].The Journal of Physical Chemistry B,2004,108(2):721-727.
[10]	Muldoon M J,Aki S N,Anderson J L,et al.Improving carbon dioxide solubility in ionic liquids[J].The Journal of Physical Chemistry B,2007,111(30):9001-9009.
[11]	Shariati A,Peters C J.High-pressure phase equilibria of systems with ionic liquids[J].The Journal of Supercritical Fluids,2005,34(2):171-176.
[12]	Gutkowski K I,Shariati A,Peters C J.High-pressure phase behavior of the binary ionic liquid system 1-octyl-3-methylimidazolium tetrafluoroborate+carbon dioxide[J].The Journal of Supercritical Fluids,2006,39(2):187-191.
[13]	Shariati A,Peters C J.High-pressure phase behavior of systems with ionic liquids(Ⅲ):The binary system carbon dioxide+1-hexyl-3-methylimidazolium hexafluorophosphate[J].The Journal of Supercritical Fluids,2004,30(2):139-144.
[14]	Anthony J L,Anderson J L,Maginn E J,et al.Anion effects on gas solubility in ionic liquids[J].The Journal of Physical Chemistry B,2005,109(13):6366-6374.
[15]	Cadena C,Anthony J L,Shah J K,et al.Why is CO2 so soluble in imidazolium-based ionic liquids?[J].Journal of the American Chemical Society,2004,126(16):5300-5308.
[16]	Aki S N,Mellein B R,Saurer E M,et al.High-pressure phase behavior of carbon dioxide with imidazolium-based ionic liquids[J].The Journal of Physical Chemistry B,2004,108(52):20355-20365.
[17]	Bates E D,Mayton R D,Ntai I,et al.CO2 capture by a task-specific ionic liquid[J].Journal of the American Chemical Society,2002,124(6):926-927.
[18]	Galan Sánchez L M,Meindersma G W,de Haan A B.Solvent properties of functionalized ionic liquids for CO2 absorption[J].Chemical Engineering Research & Design,2007,85(1):31-39.
[19]	Zhang Yi,Wu Zaikun,Chen Shaoli,Yu Ping,Luo Yunbai.CO2 capture by imidazolate-based ionic liquids:effect of functionalized cation and dication[J].Industrial & Engineering Chemistry Research,2013,52(18):6069-6075.
[20]	Goodrich B F,de la Fuente J C,Gurkan B E,et al.Effect of water and temperature on absorption of CO2 by amine-functionalized anion-tethered ionic liquids[J].The Journal of Physical Chemistry B,2011,115(29):9140-9150.
[21]	Romanos G E,Zubeir L F,Likodimos V,et al.Enhanced CO2 capture in binary mixtures of 1-alkyl-3-methylimidazolium tricyanomethanide ionic liquids with water[J].The Journal of Physical Chemistry B,2013,117(40):12234-12251.
[22]	Zhang Feng,Fang Chenggang,Wu Youting,Wang Yuantao,Li Aimin,Zhang Zhibing.Absorption of CO2 in the aqueous solutions of functionalized ionic liquids and MDEA[J].Chemical Engineering Journal,2010,160(2):691-697.
[23]	Wu Yongliang(吴永良),Jiao Zhen(焦真),Wang Guannan(王冠楠),Wu Youting(吴有庭),Zhang Zhibing(张志炳).Synthesis characterization and absorption efficiency of an ionic liquid for the absorption of CO2[J].Fine Chemicals(精细化工),2007,24(4):324-327.
[24]	Yang Tao(阳涛),Bi Yin(毕崟),Guo Kaihua(郭开华).Carbon dioxide absorption in 1-aminopropyl-3-methylimidazolium bromide aqueous solutions[J].CIESC Journal(化工学报),2012,63(10):3152-3157.
[25]	Yang Cuilian(杨翠莲),Li Song(李松),Bi Yin(毕崟),Guo Kaihua(郭开华).Absorption property of 1-aminopropyl-3-methylimidazolium bromide aqueous solutions to carbon dioxide[J].Petrochemical Technology(石油化工),2014,43(12):1433-1438.
[26]	Peng D Y,Robinson D B.A new two-constant equation of state[J].Industrial & Engineering Chemistry Fundamentals,1976,15(1):59-64.
[27]	Liu Yanxin(刘延鑫),Dong Lihu(董立户),Mi Jianguo(密建国),Chen Jian(陈健).Study on molecular structure of alkanolamines and their CO2 capture ability[J].SCIENTIA SINICA Chimica(中国科学化学),2012,42(3):291-296.
[28]	Duan Zhenhao,Sun Rrui.An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar[J].Chemical Geology,2003,193(3/4):257-271.

氨丙基离子液体水溶液CO₂吸收特性及计算模型

Properties and mathematical model of carbon dioxide solubility in aminopropyl ionic liquid aqueous solutions

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