反气相色谱法与汉森溶解度参数软件测定原煤的三维溶解度参数

doi:10.11949/j.issn.0438-1157.20170609

化工学报 ›› 2017, Vol. 68 ›› Issue (12): 4494-4499.DOI: 10.11949/j.issn.0438-1157.20170609

反气相色谱法与汉森溶解度参数软件测定原煤的三维溶解度参数

潘薪羽^1,2, 赵丽^1,2, 马空军², 王强^1,2

1 新疆大学理化测试中心, 新疆乌鲁木齐 830046;
2 新疆大学化学化工学院, 煤炭清洁转化与化工过程自治区重点实验室, 新疆乌鲁木齐 830046

收稿日期:2017-05-12 修回日期:2017-09-09 出版日期:2017-12-05 发布日期:2017-12-05
通讯作者: 王强
基金资助:
国家自然科学基金项目（21366029，21566036）。

Determination of three-dimensional solubility parameters using IGC and HSPiP

PAN Xinyu^1,2, ZHAO Li^1,2, MA Kongjun², WANG Qiang^1,2

1 Center for Physical and Chemical Analysis, Xinjiang University, Urumqi 830046, Xinjiang, China;
2 Key Laboratory of Coal Cleaning Conversion and Chemical Engineering Process, Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, Xinjiang, China

Received:2017-05-12 Revised:2017-09-09 Online:2017-12-05 Published:2017-12-05
Supported by:
supported by the National Natural Science Foundation of China(21366029, 21566036).

摘要/Abstract

摘要：

采用反气相色谱法（IGC）研究原煤在温度433.15、443.15、453.15、463.15和473.15 K时的三维溶解度参数（HSP），并使用外推法得到原煤室温（298.15 K）时HSP的色散力分量（δ_d）、极性力分量（δ_p）、氢键力分量（δ_h）以及校正溶解度参数（δ_t）分别为δ_d=20.83（J·cm^-3）^1/2，δ_p=11.95（J·cm^-3）^1/2，δ_h=11.08（J·cm^-3）^1/2，δ_t=26.44（J·cm^-3）^1/2。同时，采用汉森三维溶解度参数软件（HSPiP）模拟原煤在室温下的HSP，得到δ_d=19.92（J·cm^-3）^1/2，δ_p=11.18（J·cm^-3）^1/2，δ_h=11.47（J·cm^-3）^1/2，δ_t=25.56（J·cm^-3）^1/2。IGC与HSPiP得出的数据一致，研究结果为煤的热力学性质研究及其溶胀剂的选择等应用提供了参考。

关键词: 煤, 热力学性质, 溶解度参数, 反气相色谱技术, 汉森三维溶解度参数软件

Abstract:

The three-dimensional solubility parameters(HSP) of raw coal were determined by inverse gas chromatography (IGC) in the temperature range 433.15 to 473.15 K. The HSP concept was applied to determine components (δ_d, δ_p and δ_h) of corrected solubility parameter (δ_t), and the HSP of raw coal was derived as δ_d=20.83(J·cm^-3)^1/2, δ_p=11.95(J·cm^-3)^1/2, δ_h=11.08(J·cm^-3)^1/2 and δ_t=26.44(J·cm^-3)^1/2 by extrapolation method at room temperature (298.15 K), the HSP of raw coal that was measured as δ_d=19.92(J·cm^-3)^1/2, δ_p=11.18(J·cm^-3)^1/2, δ_h=11.47(J·cm^-3)^1/2 and δ_t=25.56(J·cm^-3)^1/2by the HSPiP method at room temperature. The results are consistent through two approaches. The results of the study provide a reference for the study of the thermodynamic properties of coal and the choice of its swelling agent.

Key words: coal, thermodynamic properties, solubility parameters, inverse gas chromatography, HSPiP

中图分类号:

TQ511

潘薪羽, 赵丽, 马空军, 王强. 反气相色谱法与汉森溶解度参数软件测定原煤的三维溶解度参数[J]. 化工学报, 2017, 68(12): 4494-4499.

PAN Xinyu, ZHAO Li, MA Kongjun, WANG Qiang. Determination of three-dimensional solubility parameters using IGC and HSPiP[J]. CIESC Journal, 2017, 68(12): 4494-4499.

参考文献 30

[1]	JOSEPH J T. Liquefaction behaviour of solvent-swollen coals[J]. Fuel, 1991, 70(2):139-144.
[2]	SHUI H, WANG Z, CAO M. Effect of pre-swelling of coal on its solvent extraction and liquefaction properties[J]. Fuel, 2008, 87(13):2908-2913.
[3]	ZHANG Y, GANGWANI K K, LEMERT R M. Sorption and swelling of block copolymers in the presence of supercritical fluid carbon dioxide[J]. The Journal of Supercritical Fluids, 1997, 11(1):115-134.
[4]	ERTAS D, KELEMEN S R, HALSEY T C. Petroleum expulsion (Ⅰ):Theory of kerogen swelling in multicomponent solvents[J]. Energy & Fuels, 2006, 20(1):295-300.
[5]	JONES M B, ARGASINSKI J K. Predictors of solvent effectiveness for dissolution of coal preasphaltenes[J]. Fuel, 1985, 64(11):1547-1551.
[6]	HOMBACH H P. General aspects of coal solubility[J]. Fuel, 1980, 59(7):465-470.
[7]	WEINBERG V L, YEN T F. 'Solubility parameters' in coal and coal liquefaction products[J]. Fuel, 1980, 59(5):287-289.
[8]	REDELIUS P. Solubility parameters and bitumen[J]. Fuel, 2000, 79(1):27-35.
[9]	BALTISBERGER R, WOOLSEY N, SCHWAN J, et al. Solubility parameter relationships between lignite derived asphaltenes and preasphaltenes[J]. American Chemical Society Advances in Fuel Chemistry Division Preprints, 1984, 29:43-55.
[10]	HANSEN C M. Hansen Solubility Parameters:a User's Handbook[M]. CRC Press, 2007:2-6.
[11]	HUGHES J M, AHERNE D, COLEMAN J N. Generalizing solubility parameter theory to apply to one-and two-dimensional solutes and to incorporate dipolar interactions[J]. Journal of Applied Polymer Science, 2013, 127(6):4483-4491.
[12]	PAINTER P C, GRAF J, COLEMAN M M. Coal solubility and swelling(Ⅰ):1. Solubility parameters for coal and the Flory c parameter[J]. Energy & Fuels, 1990, 4(4):379-384.
[13]	BUCKTON G, DOVE J W, DAVIES P. Isothermal microcalorimetry and inverse phase gas chromatography to study small changes in powder surface properties[J]. International Journal of Pharmaceutics, 1999, 193(1):13-19.
[14]	CORDEIROA N, ORNELAS M, ASHORI A, et al. Investigation on the surface properties of chemically modified natural fibers using inverse gas chromatography[J]. Carbohydrate Polymers, 2012, 87(4):2367-2375.
[15]	DIECKMANN F, KLINGER C, UHLMANN P, et al. Surface properties of polyamidines investigated by inverse gas chromatography[J]. Polymer, 2001, 42(8):3463-3466.
[16]	KO?ODZIEJEK J, G?ÓWKA E, HYLA K, et al. Relationship between surface properties determined by inverse gas chromatography and ibuprofen release from hybrid materials based on fumed silica[J]. International Journal of Pharmaceutics, 2013, 441(1):441-448.
[17]	LIU G Y, HOCH M, LIU S S, et al. Quantitative exploration of the swelling response for carbon black filled hydrogenated nitrile rubber with three-dimensional solubility parameters[J]. Polymer Bulletin, 2015, 72(8):1961-1974.
[18]	倪海月, 任世学, 方桂珍, 等. 反气相色谱法与Hansen溶解度参数法测定聚乙烯醇溶解度参数及相关热力学性质[J]. 色谱, 2016, 34(9):933-939. NI H Y, REN S X, FANG G Z, et al. Determination of solubility parameters and the related thermodynamic properties of polyvinyl alcohol using inverse gas chromatography and Hansen solubility parameters[J]. Chinese Journal of Chromatography, 2016, 34(9):933-939.
[19]	MUTELET F, BUTET V, JAUBERT J N. Application of inverse gas chromatography and regular solution theory for characterization of ionic liquids[J]. Industrial & Engineering Chemistry Research, 2005, 44(11):4120-4127.
[20]	WANG J, ZHANG Z, YANG X, et al. Determination of solubility parameter for dicationic ionic liquid by inverse gas chromatography[J]. Chinese Journal of Chromatography, 2009, 27(4):480-483.
[21]	KAYA I S, I?LTER Z, ?ENOL D. Thermodynamic interactions and characterisation of poly[(glycidyl methacrylate-co-methyl, ethyl, butyl) methacrylate] by inverse gas chromatography[J]. Polymer, 2002, 43(24):6455-6463.
[22]	NIEDERER B, LE A, CANTERGIANI E. Thermodynamic study of two different chewing-gum bases by inverse gas chromatography[J]. Journal of Chromatography A, 2003, 996(1/2):189-194.
[23]	OHTA M, OGUCHI T, YAMAMOTO K. Evaluation of solubility parameter to predict apparent solubility of amorphous and crystalline cefditoren pivoxil[J]. Pharmaceutica Acta Helvetiae, 1999, 74(1):59-64.
[24]	YAZICI O, SAKAR D, CANKURTARAN O, et al. Thermodynamical study of poly(n-hexyl methacrylate) with some solvents by inverse gas chromatography[J]. Journal of Applied Polymer Science, 2011, 122(3):1815-1822.
[25]	BOUTBOUL A, LENFANT F, GIAMPAOLI P, et al. Use of inverse gas chromatography to determine thermodynamic parameters of aroma-starch interactions[J]. Journal of Chromatography A, 2002, 969(1/2):9-16.
[26]	PRICE G J, SHILLCOCK I M. Inverse gas chromatographic measurement of solubility parameters in liquid crystalline systems[J]. Journal of Chromatography A, 2002, 964(1):199-204.
[27]	BARTON A F M. CRC Handbook of Solubility Parameters and Other Cohesion Parameters[M]. 2nd ed. CRC Press, 1991:123-138
[28]	GUILLET J E, ROMANSKY M, PRICE G J, et al. Studies of polymer structure and interactions by automated inverse gas chromatography[M]//Inverse Gas Chromatography. American Chemical Society, 1989:20-32.
[29]	YOO B, AFZAL W, PRAUSNITZ J M. Solubility parameters for nine ionic liquids[J]. Industrial & Engineering Chemistry Research, 2012, 51(29):9913-9917.
[30]	DW V K. Chemical structure and properties of coal (ⅩⅩⅦ):Coal constitution and solvent extraction[J]. Fuel, 1966, 45:229.

反气相色谱法与汉森溶解度参数软件测定原煤的三维溶解度参数

Determination of three-dimensional solubility parameters using IGC and HSPiP

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 30

相关文章 15

编辑推荐

Metrics

本文评价

[1]	陈哲文, 魏俊杰, 张玉明. 超临界水煤气化耦合SOFC发电系统集成及其能量转化机制[J]. 化工学报, 2023, 74(9): 3888-3902.
[2]	赵佳佳, 田世祥, 李鹏, 谢洪高. SiO₂-H₂O纳米流体强化煤尘润湿性的微观机理研究[J]. 化工学报, 2023, 74(9): 3931-3945.
[3]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.
[4]	吴雷, 刘姣, 李长聪, 周军, 叶干, 刘田田, 朱瑞玉, 张秋利, 宋永辉. 低阶粉煤催化微波热解制备含碳纳米管的高附加值改性兰炭末[J]. 化工学报, 2023, 74(9): 3956-3967.
[5]	韩晨, 司徒友珉, 朱斌, 许建良, 郭晓镭, 刘海峰. 协同处理废液的多喷嘴粉煤气化炉内反应流动研究[J]. 化工学报, 2023, 74(8): 3266-3278.
[6]	倪文翔, 赵京, 李博, 魏小林, 吴东垠, 刘迪, 王强. 转炉煤气全干法显热回收工艺中余热锅炉积灰特性研究[J]. 化工学报, 2023, 74(8): 3485-3493.
[7]	康超, 乔金鹏, 杨胜超, 彭超, 付元鹏, 刘斌, 刘建荣, Aleksandrova Tatiana, 段晨龙. 煤矸石中有价关键金属活化提取研究进展[J]. 化工学报, 2023, 74(7): 2783-2799.
[8]	王光宇, 张锴, 张凯华, 张东柯. 微波加热干燥煤泥热质传递及其能耗特性分析[J]. 化工学报, 2023, 74(6): 2382-2390.
[9]	姚晓宇, 沈俊, 李健, 李振兴, 康慧芳, 唐博, 董学强, 公茂琼. 流体气液临界参数测量方法研究进展[J]. 化工学报, 2023, 74(5): 1847-1861.
[10]	黄磊, 孔令学, 白进, 李怀柱, 郭振兴, 白宗庆, 李平, 李文. 油页岩添加对准东高钠煤灰熔融行为影响的研究[J]. 化工学报, 2023, 74(5): 2123-2135.
[11]	陈科, 杜理, 曾英, 任思颖, 于旭东. 四元体系LiCl+MgCl₂+CaCl₂+H₂O 323.2 K相平衡研究及计算[J]. 化工学报, 2023, 74(5): 1896-1903.
[12]	白天昊, 王晓雯, 杨梦滋, 段新伟, 米杰, 武蒙蒙. 类水滑石衍生锌基氧化物高温煤气脱硫过程中COS释放行为及其抑制研究[J]. 化工学报, 2023, 74(4): 1772-1780.
[13]	王倩, 李神勇, 康帅, 庞薇, 郝龙龙, 秦身钧. 粉煤灰分质高效利用预处理技术的研究进展[J]. 化工学报, 2023, 74(3): 1010-1032.
[14]	毛元敬, 杨智, 莫松平, 郭浩, 陈颖, 罗向龙, 陈健勇, 梁颖宗. C₆~C₁₀烷醇的SAFT-VR Mie状态方程参数回归及其热物性研究[J]. 化工学报, 2023, 74(3): 1033-1041.
[15]	彭晓婉, 郭笑楠, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8浆液法分离CH₄/N₂的双吸收-吸附塔工艺流程建模与模拟[J]. 化工学报, 2023, 74(2): 784-795.