光催化CO2还原制碳氢燃料系统优化策略研究

doi:10.11949/0438-1157.20221120

摘要/Abstract

摘要：

光催化CO₂还原制碳氢燃料技术由太阳能直接驱动，将CO₂转化为可直接利用的化学品，是助力碳达峰、碳中和的变革性技术。该技术的高效、低成本运行受光吸收利用、光催化剂形貌结构、界面催化反应及传质等因素影响，其内部能质传输是多时空尺度、多物理场耦合的复杂过程，需要从理论和应用两方面结合多个学科展开系统研究。梳理了光催化CO₂还原基本理论及国内外研究进展，并针对技术瓶颈从光吸收拓展与利用、光生载流子分离强化、氧化/还原半反应优化及传质强化四个优化策略指出了该技术发展方向，探讨了该技术全流程能量传递和物质转化之间的耦合匹配准则，为降低反应能耗、促进性能及产率提升甚至未来工业化大规模太阳能驱动CO₂还原应用铺垫道路。

关键词: 太阳能, 光催化, CO₂还原, 碳氢燃料, 优化策略

Abstract:

The photocatalytic CO₂ reduction to hydrocarbon fuel technology is directly driven by solar energy and converts CO₂ into directly usable chemicals. It is a transformative technology to help carbon peak and carbon neutrality. The efficient and low-cost operation of this technology is determined by light absorption and utilization, the morphology and structure of photocatalysts, the interfacial catalytic reaction, and mass transfer etc. In general, the internal energy and mass transfer of this technology is a multi-scale spatio-temporal process and needs to be studied by using a multi-physics field coupling model from both theoretical and application aspects. In this paper, the fundamental theory and the state-of-the-art are summarized. Also, we present the development tendency of photocatalytic CO₂ reduction technology from aspects of light absorption expansion and utilization, photogenerated carrier separation enhancement, oxidation/reduction half-reaction optimization, and mass transfer enhancement. Then we discuss the matching strategy between energy transfer and chemical reaction within the whole process, which provide the way for reducing the energy loss, promoting performance, and future industrial application of solar-driven CO₂ reduction.

Key words: solar energy, photocatalytic, CO₂ reduction, hydrocarbon fuel, optimization strategy

中图分类号:

TK 01

王峰, 张顺鑫, 余方博, 刘亚, 郭烈锦. 光催化CO₂还原制碳氢燃料系统优化策略研究[J]. 化工学报, 2023, 74(1): 29-44.

Feng WANG, Shunxin ZHANG, Fangbo YU, Ya LIU, Liejin GUO. Optimization strategy for producing carbon based fuels by photocatalytic CO₂ reduction[J]. CIESC Journal, 2023, 74(1): 29-44.

图/表 9

表1 CO2还原过程常见产物及其简化的氧化还原方程和pH=7下的氧化还原电位

Table 1 Common products of CO2 reduction and their simplified Redox equations and Redox potentials at pH=7

产物	反应	氧化还原电位(vs NHE)/V
O₂	H₂O $→$ 1/2O₂+2H⁺+2e^-	+0.82
H₂	2H⁺+2e^- $→$ H₂	-0.41
CH₄	CO₂+8H⁺+8e^- $→$ CH₄+2H₂O	-0.24
C₂H₆	2CO₂+14H⁺+14e^- $→$ C₂H₆+4H₂O	-0.27
CO	CO₂+2H⁺+2e^- $→$ CO+H₂O	-0.51
CH₃OH	CO₂+6H⁺+6e^- $→$ CH₃OH+H₂O	-0.39
C₂H₅OH	2CO₂+12H⁺+12e^- $→$ C₂H₅OH+3H₂O	-0.33
CH₃CH₂CH₂OH	3CO₂+18H⁺+18e^- $→$ CH₃CH₂CH₂OH+5H₂O	-0.31
CH₃CH(OH)CH₃	3CO₂+18H⁺+18e^- $→$ CH₃CH(OH)CH₃+5H₂O	-0.30
HCHO	CO₂+4H⁺+4e^- $→$ HCHO+H₂O	-0.55
CH₃CHO	2CO₂+10H⁺+10e^- $→$ CH₃CHO+3H₂O	-0.36
CH₃CH₂CHO	3CO₂+16H⁺+16e^- $→$ CH₃CH₂CHO+5H₂O	-0.32
CH₃COCH₃	3CO₂+16H⁺+16e^- $→$ CH₃COCH₃+5H₂O	-0.31
HCOOH	CO₂+2H⁺+2e^- $→$ HCOOH	-0.58
CH₃COOH	2CO₂+8H⁺+8e^- $→$ CH₃COOH+2H₂O	-0.31

表1 CO2还原过程常见产物及其简化的氧化还原方程和pH=7下的氧化还原电位

Table 1 Common products of CO2 reduction and their simplified Redox equations and Redox potentials at pH=7

产物	反应	氧化还原电位(vs NHE)/V
O₂	H₂O $→$ 1/2O₂+2H⁺+2e^-	+0.82
H₂	2H⁺+2e^- $→$ H₂	-0.41
CH₄	CO₂+8H⁺+8e^- $→$ CH₄+2H₂O	-0.24
C₂H₆	2CO₂+14H⁺+14e^- $→$ C₂H₆+4H₂O	-0.27
CO	CO₂+2H⁺+2e^- $→$ CO+H₂O	-0.51
CH₃OH	CO₂+6H⁺+6e^- $→$ CH₃OH+H₂O	-0.39
C₂H₅OH	2CO₂+12H⁺+12e^- $→$ C₂H₅OH+3H₂O	-0.33
CH₃CH₂CH₂OH	3CO₂+18H⁺+18e^- $→$ CH₃CH₂CH₂OH+5H₂O	-0.31
CH₃CH(OH)CH₃	3CO₂+18H⁺+18e^- $→$ CH₃CH(OH)CH₃+5H₂O	-0.30
HCHO	CO₂+4H⁺+4e^- $→$ HCHO+H₂O	-0.55
CH₃CHO	2CO₂+10H⁺+10e^- $→$ CH₃CHO+3H₂O	-0.36
CH₃CH₂CHO	3CO₂+16H⁺+16e^- $→$ CH₃CH₂CHO+5H₂O	-0.32
CH₃COCH₃	3CO₂+16H⁺+16e^- $→$ CH₃COCH₃+5H₂O	-0.31
HCOOH	CO₂+2H⁺+2e^- $→$ HCOOH	-0.58
CH₃COOH	2CO₂+8H⁺+8e^- $→$ CH₃COOH+2H₂O	-0.31

图1 光催化还原CO2示意图

Fig.1 Schematic diagram of photocatalytic CO2 reduction

表2 近年来光催化CO2还原代表性工作

Table 2 Representative work of photocatalytic CO2 reduction in recent years

体系	催化剂	反应体系	还原产物	氧化产物	产率	文献
无牺牲剂体系	In₄SnS₈	H₂O+CO₂	CH₄ CO	O₂	10.70 μl·h^-1 9.39 μl·h^-1	[29]
	Pt-TiO₂	H₂O+CO₂	CH₄		1361 μmol·g^-1·h^-1	[30]
	SnS₂-C	H₂O+CO₂	CH₃CHO		96.66 μmol·g^-1·h^-1	[31]
	CdS/Mn₂O₃/PAA	H₂O+CO₂	HCOOH CH₃CH₂OH H₂		1392.3 μmol·g^-1·h^-1 52.2 μmol·g^-1·h^-1 2766 μmol·g^-1·h^-1	[32]
	In₂S₃/Bi₂MoO₆	H₂O+CO₂	CO		28.54 μmol·g^-1·h^-1	[33]
	CuIn₅S₈	H₂O+CO₂	CH₄		8.7 μmol·g^-1·h^-1	[34]
	Cu₂O	H₂O+CO₂	CH₃OH		1.2 mol·g^-1·h^-1	[17]
	^mCD/CN	H₂O+CO₂	CH₃OH		13.9 μmol·g^-1·h^-1	[35]
	g-CN-MI-40	H₂O+CO₂	CH₃OH	H₂O₂	4.18 mmol·g^-1	[36]
	Ag-MnO _x /CaTiO₃	H₂O+CO₂	CO	H₂O₂	11.8 μmol·h^-1	[37]
牺牲剂体系	Ni-ZnS	K₂CO₃+K₂SO₃	HCOOH	—	427.5 μmol·g^-1·h^-1	[38]
	VZn-3D-ZnIn₂S₄	H₂O+TEOA	CO	—	276.7 μmol·g^-1·h^-1	[39]
	CdIn₂S₄/Co₃O₄	H₂O+TEOA+Co $3 2 +$	CO	—	5300 μmol·g^-1·h^-1	[40]
	O-ZnIn₂S₄	H₂O+TEOA+CH₃CN+Co $3 2 +$	CO	—	1680 μmol·g^-1·h^-1	[41]
	CdS/TiO₂	H₂O+NaHCO₃+HCl	CH₄	—	11.9 mmol·m^-2·h^-1	[42]
	CdS/NH₂-UiO-66	H₂O+TEOA	CO	—	87 μmol·g^-1·h^-1	[43]
	COF-5/CoAl-LDH	H₂O+ acetonitrile	CO	—	53.08 μmol·g^-1·h^-1	[44]
	Cu/Cd_0.5Zn_0.5S	TEOA+KHCO₃(aq)	C₂₊	—	6.54 μmol·h^-1	[45]

表2 近年来光催化CO2还原代表性工作

Table 2 Representative work of photocatalytic CO2 reduction in recent years

体系	催化剂	反应体系	还原产物	氧化产物	产率	文献
无牺牲剂体系	In₄SnS₈	H₂O+CO₂	CH₄ CO	O₂	10.70 μl·h^-1 9.39 μl·h^-1	[29]
	Pt-TiO₂	H₂O+CO₂	CH₄		1361 μmol·g^-1·h^-1	[30]
	SnS₂-C	H₂O+CO₂	CH₃CHO		96.66 μmol·g^-1·h^-1	[31]
	CdS/Mn₂O₃/PAA	H₂O+CO₂	HCOOH CH₃CH₂OH H₂		1392.3 μmol·g^-1·h^-1 52.2 μmol·g^-1·h^-1 2766 μmol·g^-1·h^-1	[32]
	In₂S₃/Bi₂MoO₆	H₂O+CO₂	CO		28.54 μmol·g^-1·h^-1	[33]
	CuIn₅S₈	H₂O+CO₂	CH₄		8.7 μmol·g^-1·h^-1	[34]
	Cu₂O	H₂O+CO₂	CH₃OH		1.2 mol·g^-1·h^-1	[17]
	^mCD/CN	H₂O+CO₂	CH₃OH		13.9 μmol·g^-1·h^-1	[35]
	g-CN-MI-40	H₂O+CO₂	CH₃OH	H₂O₂	4.18 mmol·g^-1	[36]
	Ag-MnO _x /CaTiO₃	H₂O+CO₂	CO	H₂O₂	11.8 μmol·h^-1	[37]
牺牲剂体系	Ni-ZnS	K₂CO₃+K₂SO₃	HCOOH	—	427.5 μmol·g^-1·h^-1	[38]
	VZn-3D-ZnIn₂S₄	H₂O+TEOA	CO	—	276.7 μmol·g^-1·h^-1	[39]
	CdIn₂S₄/Co₃O₄	H₂O+TEOA+Co $3 2 +$	CO	—	5300 μmol·g^-1·h^-1	[40]
	O-ZnIn₂S₄	H₂O+TEOA+CH₃CN+Co $3 2 +$	CO	—	1680 μmol·g^-1·h^-1	[41]
	CdS/TiO₂	H₂O+NaHCO₃+HCl	CH₄	—	11.9 mmol·m^-2·h^-1	[42]
	CdS/NH₂-UiO-66	H₂O+TEOA	CO	—	87 μmol·g^-1·h^-1	[43]
	COF-5/CoAl-LDH	H₂O+ acetonitrile	CO	—	53.08 μmol·g^-1·h^-1	[44]
	Cu/Cd_0.5Zn_0.5S	TEOA+KHCO₃(aq)	C₂₊	—	6.54 μmol·h^-1	[45]

图2 不同优化策略下光催化剂的光吸收拓展与利用

Fig.2 Light absorption expansion and utilization of photocatalysts under different optimization strategies

图3 形貌、异质结及表面工程对载流子分离强化的影响

Fig.3 Effect of morphology, heterojunction and surface engineering on carrier separation and enhancement

图4 界面化学反应调控对CO2还原及水氧化半反应的影响

Fig.4 Effects of interfacial chemical reaction regulation on CO2 reduction and water oxidation half reactions

图5 光催化过程的能量损失示意图[7]

Fig.5 Schematic diagram of energy losses in the whole photocatalytic process [7]

图6 传质强化对光催化性能影响

Fig.6 Effect of enhanced mass transfer on photocatalytic performance

图7 光催化CO2还原体系未来挑战

Fig.7 Future challenges for photocatalytic CO2 reduction systems

参考文献 87

1	Kweku D, Bismark O, Maxwell A, et al. Greenhouse effect: greenhouse gases and their impact on global warming[J]. Journal of Scientific Research and Reports, 2018, 17(6): 1-9.
2	Guo Y, Guan W, Lei C, et al. Scalable super hygroscopic polymer films for sustainable moisture harvesting in arid environments [J]. Nature Communications, 2022, 13(1): 2761.
3	Ao H, Rohling E J, Zhang R, et al. Global warming-induced Asian hydrological climate transition across the Miocene-Pliocene boundary[J]. Nature Communications, 2021, 12: 6935.
4	Zhou N, Khanna N, Feng W, et al. Scenarios of energy efficiency and CO₂ emissions reduction potential in the buildings sector in China to year 2050[J]. Nature Energy, 2018, 3(11): 978-984.
5	Guo Y, de Vasconcelos L S, Manohar N, et al. Highly elastic interconnected porous hydrogels through self-assembled templating for solar water purification [J]. Angewandte Chemie, 2022, 134(3): e202114074.
6	Chen Y B, Liu Y, Wang F, et al. Toward practical photoelectrochemical water splitting and CO₂ reduction using earth-abundant materials[J]. Journal of Energy Chemistry, 2021, 61: 469-488.
7	Guo L J, Chen Y B, Su J Z, et al. Obstacles of solar-powered photocatalytic water splitting for hydrogen production: a perspective from energy flow and mass flow[J]. Energy, 2019, 172: 1079-1086.
8	戚新刚, 路利波, 陈渝楠, 等. 造纸黑液超临界水气化制氢与高附加值化学品回收研究进展[J]. 化工学报, 2022, 73(8): 3338-3354.
	Qi X G, Lu L B, Chen Y N, et al. Review of black liquor supercritical water gasification for hydrogen production with high value-added chemicals recovery[J]. CIESC Journal, 2022, 73(8): 3338-3354.
9	欧阳述昕, 王文中. CO₂绿色转化[J]. 无机材料学报, 2022, 37(1): 1-2.
	Ouyang S X, Wang W Z. Green conversion of CO₂ [J]. Journal of Inorganic Materials, 2022, 37(1): 1-2.
10	Liu Y, Wang F, Jiao Z H, et al. Photochemical systems for solar-to-fuel production[J]. Electrochemical Energy Reviews, 2022, 5(3): 1-41.
11	Bushuyev O S, de Luna P, Dinh C T, et al. What should we make with CO₂ and how can we make it?[J]. Joule, 2018, 2(5): 825-832.
12	Bie C B, Zhu B C, Xu F Y, et al. In situ grown monolayer N-doped graphene on CdS hollow spheres with seamless contact for photocatalytic CO₂ reduction[J]. Advanced Materials, 2019, 31(42): 1902868.
13	Li Y, Li B, Zhang D, et al. Crystalline carbon nitride supported copper single atoms for photocatalytic CO₂ reduction with nearly 100% CO selectivity[J]. ACS Nano, 2020, 14(8): 10552-10561.
14	Wang H P, Zhang L, Wang K F, et al. Enhanced photocatalytic CO₂ reduction to methane over WO₃·0.33H₂O via Mo doping[J]. Applied Catalysis B: Environmental, 2019, 243: 771-779.
15	Tian F Y, Zhang H L, Liu S, et al. Visible-light-driven CO₂ reduction to ethylene on CdS: enabled by structural relaxation-induced intermediate dimerization and enhanced by ZIF-8 coating[J]. Applied Catalysis B: Environmental, 2021, 285: 119834.
16	Xu F H, Li Z Z, Zhu R L, et al. Narrow band-gapped perovskite oxysulfide for CO₂ photoreduction towards ethane[J]. Applied Catalysis B: Environmental, 2022, 316: 121615.
17	Wu Y A, McNulty I, Liu C, et al. Facet-dependent active sites of a single Cu₂O particle photocatalyst for CO₂ reduction to methanol[J]. Nature Energy, 2019, 4(11): 957-968.
18	Li N X, Liu X C, Zhou J C, et al. Encapsulating CuO quantum dots in MIL-125(Ti) coupled with g-C₃N₄ for efficient photocatalytic CO₂ reduction[J]. Chemical Engineering Journal, 2020, 399: 125782.
19	Wang Q, Warnan J, Rodríguez-Jiménez S, et al. Molecularly engineered photocatalyst sheet for scalable solar formate production from carbon dioxide and water[J]. Nature Energy, 2020, 5(9): 703-710.
20	Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238(5358): 37-38.
21	Mao L H, Lu B R, Shi J W, et al. Rapid high-temperature hydrothermal post treatment on graphitic carbon nitride for enhanced photocatalytic H₂ evolution[J]. Catalysis Today, 2023, 409: 94-102.
22	Halmann M. Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells[J]. Nature, 1978, 275(5676): 115-116.
23	Liang L, Li X D, Zhang J C, et al. Efficient infrared light induced CO₂ reduction with nearly 100% CO selectivity enabled by metallic CoN porous atomic layers[J]. Nano Energy, 2020, 69: 104421.
24	Fu J W, Jiang K X, Qiu X Q, et al. Product selectivity of photocatalytic CO₂ reduction reactions[J]. Materials Today, 2020, 32: 222-243.
25	Zeng S, Kar P, Thakur U K, et al. A review on photocatalytic CO₂ reduction using perovskite oxide nanomaterials[J]. Nanotechnology, 2018, 29(5): 052001.
26	Li K, An X Q, Park K H, et al. A critical review of CO₂ photoconversion: catalysts and reactors[J]. Catalysis Today, 2014, 224: 3-12.
27	Wang Y, Shang X T, Shen J N, et al. Direct and indirect Z-scheme heterostructure-coupled photosystem enabling cooperation of CO₂ reduction and H₂O oxidation[J]. Nature Communications, 2020, 11: 3043.
28	Tafreshi S S, Moshfegh A Z, de Leeuw N H. Mechanism of photocatalytic reduction of CO₂ by Ag₃PO₄(111)/g-C₃N₄ nanocomposite: a first-principles study[J]. The Journal of Physical Chemistry C, 2019, 123(36): 22191-22201.
29	Chai Y, Chen Y M, Shen J N, et al. Distortion of the coordination structure and high symmetry of the crystal structure in In₄SnS₈ microflowers for enhancing visible-light photocatalytic CO₂ reduction[J]. ACS Catalysis, 2021, 11(17): 11029-11039.
30	Wang W N, An W J, Ramalingam B, et al. Size and structure matter: enhanced CO₂ photoreduction efficiency by size-resolved ultrafine Pt nanoparticles on TiO₂ single crystals[J]. Journal of the American Chemical Society, 2012, 134(27): 11276-11281.
31	Shown I, Samireddi S, Chang Y C, et al. Carbon-doped SnS₂ nanostructure as a high-efficiency solar fuel catalyst under visible light[J]. Nature Communications, 2018, 9: 169.
32	Kandy M M, Gaikar V G. Enhanced photocatalytic reduction of CO₂ using CdS/Mn₂O₃ nanocomposite photocatalysts on porous anodic alumina support with solar concentrators[J]. Renewable Energy, 2019, 139: 915-923.
33	Yu B, Wu Y X, Meng F M, et al. Formation of hierarchical Bi₂MoO₆/In₂S₃ S-scheme heterojunction with rich oxygen vacancies for boosting photocatalytic CO₂ reduction[J]. Chemical Engineering Journal, 2022, 429: 132456.
34	Li X D, Sun Y F, Xu J Q, et al. Selective visible-light-driven photocatalytic CO₂ reduction to CH₄ mediated by atomically thin CuIn₅S₈ layers[J]. Nature Energy, 2019, 4(8): 690-699.
35	Wang Y O, Liu X, Han X Y, et al. Unique hole-accepting carbon-dots promoting selective carbon dioxide reduction nearly 100% to methanol by pure water[J]. Nature Communications, 2020, 11: 2531.
36	Samanta S, Yadav R, Kumar A, et al. Surface modified C, O co-doped polymeric g-C₃N₄ as an efficient photocatalyst for visible light assisted CO₂ reduction and H₂O₂ production[J]. Applied Catalysis B: Environmental, 2019, 259: 118054.
37	Soltani T, Yamamoto A, Singh S P, et al. Simultaneous formation of CO and H₂O₂ from CO₂ and H₂O with a Ag-MnO _x /CaTiO₃ photocatalyst[J]. ACS Applied Energy Materials, 2021, 4(7): 6500-6510.
38	Pang H, Meng X G, Song H, et al. Probing the role of nickel dopant in aqueous colloidal ZnS nanocrystals for efficient solar-driven CO₂ reduction[J]. Applied Catalysis B: Environmental, 2019, 244: 1013-1020.
39	He Y Q, Rao H, Song K P, et al. 3D hierarchical ZnIn₂S₄ nanosheets with rich Zn vacancies boosting photocatalytic CO₂ reduction[J]. Advanced Functional Materials, 2019, 29(45): 1905153.
40	Huang L J, Li B F, Su B, et al. Fabrication of hierarchical Co₃O₄@CdIn₂S₄ p-n heterojunction photocatalysts for improved CO₂ reduction with visible light[J]. Journal of Materials Chemistry A, 2020, 8(15): 7177-7183.
41	Pan B, Wu Y, Rhimi B, et al. Oxygen-doping of ZnIn₂S₄ nanosheets towards boosted photocatalytic CO₂ reduction[J]. Journal of Energy Chemistry, 2021, 57: 1-9.
42	Low J, Dai B Z, Tong T, et al. In situ irradiated X-ray photoelectron spectroscopy investigation on a direct Z-scheme TiO₂/CdS composite film photocatalyst[J]. Advanced Materials, 2019, 31(5): 1807920.
43	Zhao H, Yang X, Xu R, et al. CdS/NH₂-UiO-66 hybrid membrane reactors for the efficient photocatalytic conversion of CO₂ [J]. Journal of Materials Chemistry A, 2018, 6(41): 20152-20160.
44	Qu S Y, Zhou M, Chen W, et al. COF-5/CoAl-LDH nanocomposite heterojunction for enhanced visible-light-driven CO₂ reduction[J]. ChemSusChem, 2022, 15(7): e202200184.
45	Bai S J, Qiu H R, Song M M, et al. Porous fixed-bed photoreactor for boosting C—C coupling in photocatalytic CO₂ reduction[J]. eScience, 2022, 2(4): 428-437.
46	Lo C C, Hung C H, Yuan C S, et al. Photoreduction of carbon dioxide with H₂ and H₂O over TiO₂ and ZrO₂ in a circulated photocatalytic reactor[J]. Solar Energy Materials and Solar Cells, 2007, 91(19): 1765-1774.
47	Xin C Y, Hu M C, Wang K, et al. Significant enhancement of photocatalytic reduction of CO₂ with H₂O over ZnO by the formation of basic zinc carbonate[J]. Langmuir, 2017, 33(27): 6667-6676.
48	Yu X X, Yang Z Z, Qiu B, et al. Eosin Y-functionalized conjugated organic polymers for visible-light-driven CO₂ reduction with H₂O to CO with high efficiency[J]. Angewandte Chemie International Edition, 2019, 58(2): 632-636.
49	Bian J, Feng J N, Zhang Z Q, et al. Dimension-matched zinc phthalocyanine/BiVO₄ ultrathin nanocomposites for CO₂ reduction as efficient wide-visible-light-driven photocatalysts via a cascade charge transfer[J]. Angewandte Chemie International Edition, 2019, 58(32): 10873-10878.
50	Di T M, Zhu B C, Cheng B, et al. A direct Z-scheme g-C₃N₄/SnS₂ photocatalyst with superior visible-light CO₂ reduction performance[J]. Journal of Catalysis, 2017, 352: 532-541.
51	Wang J C, Zhang L, Fang W X, et al. Enhanced photoreduction CO₂ activity over direct Z-scheme α-Fe₂O₃/Cu₂O heterostructures under visible light irradiation[J]. ACS Applied Materials & Interfaces, 2015, 7(16): 8631-8639.
52	Liang L, Li X D, Sun Y F, et al. Infrared light-driven CO₂ overall splitting at room temperature[J]. Joule, 2018, 2(5): 1004-1016.
53	Jin J R, He T. Facile synthesis of Bi₂S₃ nanoribbons for photocatalytic reduction of CO₂ into CH₃OH[J]. Applied Surface Science, 2017, 394: 364-370.
54	Nishiyama H, Yamada T, Nakabayashi M, et al. Photocatalytic solar hydrogen production from water on a 100-m² scale[J]. Nature, 2021, 598(7880): 304-307.
55	Takata T, Jiang J Z, Sakata Y, et al. Photocatalytic water splitting with a quantum efficiency of almost unity[J]. Nature, 2020, 581(7809): 411-414.
56	Liang L, Lei F C, Gao S, et al. Single unit cell bismuth tungstate layers realizing robust solar CO₂ reduction to methanol[J]. Angewandte Chemie International Edition, 2015, 54(47): 13971-13974.
57	Liu Y, Yu F, Wang F, et al. Construction of Z-scheme In₂S₃-TiO₂ for CO₂ reduction under concentrated natural sunlight[J]. Chinese Journal of Structural Chemistry, 2022, 41(1): 2201034-2201039.
58	Low J, Yu J, Jaroniec M, et al. Heterojunction photocatalysts[J]. Advanced Materials, 2017, 29(20): 1601694.
59	Xu F Y, Meng K, Cheng B, et al. Unique S-scheme heterojunctions in self-assembled TiO₂/CsPbBr₃ hybrids for CO₂ photoreduction[J]. Nature Communications, 2020, 11(1): 4613.
60	Zhang L Y, Zhang J J, Yu H G, et al. Emerging S-scheme photocatalyst[J]. Advanced Materials, 2022, 34(11): e2107668.
61	Wang L, Zhao B H, Wang C H, et al. Thermally assisted photocatalytic conversion of CO₂-H₂O to C₂H₄over carbon doped In₂S₃nanosheets[J]. Journal of Materials Chemistry A, 2020, 8(20): 10175-10179.
62	Wang L B, Zang L L, Shen F T, et al. Preparation of Cu modified g-C₃N₄ nanorod bundles for efficiently photocatalytic CO₂ reduction[J]. Journal of Colloid and Interface Science, 2022, 622: 336-346.
63	Shen M, Zhang L X, Shi J L. Defect engineering of photocatalysts towards elevated CO₂ reduction performance[J]. ChemSusChem, 2021, 14(13): 2635-2654.
64	Gong S Q, Niu Y L, Teng X, et al. Visible light-driven, selective CO₂ reduction in water by In-doped Mo₂C based on defect engineering[J]. Applied Catalysis B: Environmental, 2022, 310: 121333.
65	Xu F Y, Meng K, Zhu B C, et al. Graphdiyne: a new photocatalytic CO₂ reduction cocatalyst[J]. Advanced Functional Materials, 2019, 29(43): 1904256.
66	Dong C Y, Xing M Y, Zhang J L. Double-cocatalysts promote charge separation efficiency in CO₂ photoreduction: spatial location matters[J]. Materials Horizons, 2016, 3(6): 608-612.
67	Wu H K, Li Y H, Qi M Y, et al. Enhanced photocatalytic CO₂ reduction with suppressing H₂ evolution via Pt cocatalyst and surface SiO₂ coating[J]. Applied Catalysis B: Environmental, 2020, 278: 119267.
68	Jiang Z, Ding D, Wang L, et al. Interfacial effects of MnO _x -loaded TiO₂ with exposed {001} facets and its catalytic activity for the photoreduction of CO₂ [J]. Catalysis Science & Technology, 2017, 7(14): 3065-3072.
69	Dong C Y, Hu S C, Xing M Y, et al. Enhanced photocatalytic CO₂ reduction to CH₄ over separated dual co-catalysts Au and RuO₂ [J]. Nanotechnology, 2018, 29(15): 154005.
70	Di J, Chen C, Zhu C, et al. Cobalt nitride as a novel cocatalyst to boost photocatalytic CO₂ reduction[J]. Nano Energy, 2021, 79: 105429.
71	Li K, Peng T Y, Ying Z H, et al. Ag-loading on brookite TiO₂ quasi nanocubes with exposed {210} and {001} facets: activity and selectivity of CO₂ photoreduction to CO/CH₄ [J]. Applied Catalysis B: Environmental, 2016, 180: 130-138.
72	Chen Q, Mo W, Yang G, et al. Significantly enhanced photocatalytic CO₂ reduction by surface amorphization of cocatalysts[J]. Small, 2021, 17(45): e2102105.
73	Yoshino S, Sato K, Yamaguchi Y, et al. Z-schematic CO₂ reduction to CO through interparticle electron transfer between SrTiO₃:‍Rh of a reducing photocatalyst and BiVO₄ of a water oxidation photocatalyst under visible light[J]. ACS Applied Energy Materials, 2020, 3(10): 10001-10007.
74	Wagner A, Sahm C D, Reisner E. Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO₂ reduction[J]. Nature Catalysis, 2020, 3(10): 775-786.
75	Hao Y C, Chen L W, Li J N, et al. Metal-organic framework membranes with single-atomic centers for photocatalytic CO₂ and O₂ reduction[J]. Nature Communications, 2021, 12: 2682.
76	Song M M, Jiao Z H, Jing W H, et al. Revealing the nature of C—C coupling sites on a Cu surface for CO₂ reduction[J]. The Journal of Physical Chemistry Letters, 2022, 13(20): 4434-4440.
77	Das R, Chakraborty S, Peter S C. Systematic assessment of solvent selection in photocatalytic CO₂ reduction[J]. ACS Energy Letters, 2021, 6(9): 3270-3274.
78	Kuramochi Y, Kamiya M, Ishida H. Photocatalytic CO₂ reduction in N, N-dimethylacetamide/water as an alternative solvent system[J]. Inorganic Chemistry, 2014, 53(7): 3326-3332.
79	Yu F, Wang C H, Ma H, et al. Revisiting Pt/TiO₂ photocatalysts for thermally assisted photocatalytic reduction of CO₂ [J]. Nanoscale, 2020, 12(13): 7000-7010.
80	Galli F, Compagnoni M, Vitali D, et al. CO₂ photoreduction at high pressure to both gas and liquid products over titanium dioxide[J]. Applied Catalysis B: Environmental, 2017, 200: 386-391.
81	Khan A A, Tahir M. Recent advancements in engineering approach towards design of photo-reactors for selective photocatalytic CO₂ reduction to renewable fuels[J]. Journal of CO₂ Utilization, 2019, 29: 205-239.
82	Ola O, Maroto-Valer M M. Review of material design and reactor engineering on TiO₂ photocatalysis for CO₂ reduction[J]. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2015, 24: 16-42.
83	Li Y, Li R Z, Li Z H, et al. Recent advances in photothermal CO _x conversion[J]. Solar RRL, 2022, 6(10): 2200493.
84	Zhao L, Qi Y, Song L, et al. Solar-driven water-gas shift reaction over CuO _x /Al₂O₃ with 1.1% of light-to-energy storage[J]. Angewandte Chemie International Edition, 2019, 58(23): 7708-7712.
85	Tong Y X, Song L Z, Ning S B, et al. Photocarriers-enhanced photothermocatalysis of water-gas shift reaction under H₂-rich and low-temperature condition over CeO₂/Cu_1.5Mn_1.5O₄ catalyst[J]. Applied Catalysis B: Environmental, 2021, 298: 120551.
86	Ning S B, Sun Y H, Ouyang S X, et al. Solar light-induced injection of hot electrons and photocarriers for synergistically enhanced photothermocatalysis over Cu-Co/SrTiO₃ catalyst towards boosting CO hydrogenation into C₂—C₄ hydrocarbons[J]. Applied Catalysis B: Environmental, 2022, 310: 121063.
87	闫帅杨海平, 陈应泉, 等. CO₂光热催化还原研究进展[J]. 化工学报, 2022, 73(10): 4298-4310.
	Yan S, Yang H P, Chen Y Q, et al. Recent advances in photothermal catalysis of CO₂ reduction[J]. CIESC Journal, 2022, 73(10): 4298-4310.

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光催化CO₂还原制碳氢燃料系统优化策略研究

Optimization strategy for producing carbon based fuels by photocatalytic CO₂ reduction

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