化工学报 ›› 2020, Vol. 71 ›› Issue (5): 2382-2388.DOI: 10.11949/0438-1157.20191090

• 能源和环境工程 • 上一篇    下一篇

棉秆水热及水热氧化过程水相产物分析研究

孙梦圆1(),张守玉1(),王才威2,胡南3,宋晓冰1,刘宏宇1,李潇峰1   

  1. 1.上海理工大学能源与动力工程学院,上海 200093
    2.华南理工大学化学与化工学院,广东 广州 510640
    3.长春工程学院,吉林 长春 130012
  • 收稿日期:2019-10-07 修回日期:2020-02-01 出版日期:2020-05-05 发布日期:2020-05-05
  • 通讯作者: 张守玉
  • 作者简介:孙梦圆(1994—),女,硕士研究生,sunmengyuan321@163.com
  • 基金资助:
    吉林省产业技术研究与开发专项项目(2019C056-3);上海理工大学科技发展项目(2019KJFZ213)

Aqueous products prepared by hydrothermal and hydrothermal oxidation processes of cotton stalk

Mengyuan SUN1(),Shouyu ZHANG1(),Caiwei WANG2,Nan HU3,Xiaobing SONG1,Hongyu LIU1,Xiaofeng LI1   

  1. 1.School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
    2.School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
    3.Changchun Institute of Technology, Changchun 130012, Jilin, China
  • Received:2019-10-07 Revised:2020-02-01 Online:2020-05-05 Published:2020-05-05
  • Contact: Shouyu ZHANG

摘要:

水热及水热氧化处理技术可改变生物质的特性,从而提高热解产物的品质及热解效率。本研究使用高压反应釜在180~280℃下对棉秆进行水热及水热氧化过程处理,使用色谱质谱联用仪、波美密度计及pH酸度计对比分析了水热过程水相产物(HTAP)及水热氧化过程水相产物(HOAP)的有机组分、折光指数和pH。结果表明,HOAP中酸类有机物含量最高时的温度(200℃)低于HTAP(230℃)。200~230℃下HOAP中酚类化合物的含量明显高于HTAP。水热氧化过程抑制了HOAP中酮类化合物的生成。180~280℃下HOAP的折光指数高于HTAP,且随着温度增加而下降。HOAP的pH随着温度的升高而增加,并且180~260℃下HOAP的pH低于HTAP。HTAP与HOAP的理化性质和木醋液基本一致,有潜力应用于农业、林业等领域。

关键词: 生物质, 水热, 水热氧化, 木醋液, 有机组分

Abstract:

The characteristics of biomass could be changed by hydrothermal and hydrothermal oxidation process, so that the quality of pyrolytic products and pyrolytic efficiency are improved. In this study, the hydrothermal aqueous product (HTAP) and hydrothermal oxidation aqueous product (HOAP) were prepared by the processing of cotton stalk without or with oxidant at 180—280℃ in an autoclave reactor. The organic compounds, refraction indexes and pH values of HTAP/HOAP were investigated using gas chromatography-mass spectrometry, Baume densitometer and pH acidometer, respectively. The results show that the content of the acids in HOAP reached the maximum at 200℃, which is lower than that in HTAP (at 230℃). The content of the phenols in HOAP at 200—230℃ are significantly higher than that in HTAP. The formation of the ketones is inhibited under hydrothermal oxidation. The refraction indexes of HOAP at 180—280℃ show an obvious downtrend with the increase in temperature and are higher than that of HTAP. The pH values of HOAP at 180—280℃ increase with the increasing temperature. Besides, the pH values of HOAP at 180—260℃ are lower than that of HTAP. The physical and chemical properties of HTAP and HOAP are basically the same as those of wood vinegar, which has the potential to be used in agriculture, forestry and other fields.

Key words: biomass, hydrothermal, hydrothermal oxidation, wood vinegar, organic compounds

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