生物质源多孔碳制备及其对废水中药物吸附研究进展

doi:10.11949/0438-1157.20200587

摘要/Abstract

摘要：

城市现代化与工业化的快速发展给环境造成的污染日趋严重，尤其以水体污染最为明显。近年来，工业废水中药物的含量逐年上升，污染程度已经不容忽视。因此，开发新型多孔材料用于废水中药物分子的吸附分离，已经成为了当前的研究热点。综述了近年来生物质源多孔碳（生物炭）在废水中污染物吸附分离方面的研究，首先简单介绍了废水中污染物的治理方法，在此基础上重点探讨了生物炭的制备与修饰，并结合碳材料表面化学性质与孔道结构，总结并展望了生物炭对药物的吸附性能。

关键词: 吸附, 热解, 药物, 生物质, 多孔碳

Abstract:

The rapid development of urban modernization and industrialization has caused increasingly serious pollution to the environment, especially water contamination. In recent years, the content of pharmaceuticals in industrial wastewater has increased year by year, and the pollution should not be ignored any more. Therefore, the development of new porous materials for the adsorption and separation of pharmaceutical molecules in wastewater has become a current research hotspot. This article summarizes the recent research on the adsorption and separation of pollutants in wastewater by biomass-derived porous carbons (biochars). First, it briefly introduces the treatment methods of pollutants in wastewater, and mainly focuses on the preparation and modification of biochars. Combined with the surface chemical properties and pore structure of the carbon materials, this paper summarizes and prospects the adsorption properties of biochar to pharmaceuticals.

Key words: adsorption, pyrolysis, pharmaceuticals, biomass, porous carbon

中图分类号:

TQ 09

欧阳金波,陈建,刘峙嵘,周利民,韩方泽,应昕. 生物质源多孔碳制备及其对废水中药物吸附研究进展[J]. 化工学报, 2020, 71(12): 5420-5429.

OUYANG Jinbo,CHEN Jian,LIU Zhirong,ZHOU Limin,HAN Fangze,YING Xin. Research progress on preparation of biomass-derived porous carbon and its adsorption of pharmaceuticals in wastewater[J]. CIESC Journal, 2020, 71(12): 5420-5429.

图/表 5

图1 药物废水治理方法

Fig.1 Treatment methods of pharmaceuticals wastewater

图2 生物质组成示意图[2]

Fig.2 Diagram of biomass composition[2]

图3 生物炭的物理化学性质

Fig.3 Physicochemical properties of biochars

图4 生物炭的制备与修饰

Fig.4 Preparation and modification of biochars

图5 生物炭吸附盐酸四环素机理[63]

Fig.5 Adsorption mechanism of tetracycline hydrochloride onto biochars[63]

参考文献 71

1	Ahmed M J. Adsorption of quinolone, tetracycline, and penicillin antibiotics from aqueous solution using activated carbons[J]. Environmental Toxicology and Pharmacology, 2017, 50: 1-10.
2	Yaashikaa P R, Kumar P S, Varjani S J, et al. Advances in production and application of biochar from lignocellulosic feedstocks for remediation of environmental pollutants[J]. Bioresource Technology, 2019, 292: 122030.
3	Liu L, Gao Z Y, Su X P, et al. Adsorption removal of dyes from single and binary solutions using a cellulose-based bioadsorbent[J]. ACS Sustainable Chemistry & Engineering, 2015, 3(3): 432-442.
4	Ge Y, Li Z. Application of lignin and its derivatives in adsorption of heavy metal ions in water: a review[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(5): 7181-7192.
5	Salman J M, Njoku V O, Hameed B H. Adsorption of pesticides from aqueous solution onto banana stalk activated carbon[J]. Chemical Engineering Journal, 2011, 174(1): 41-48.
6	罗玉, 黄斌, 金玉, 等. 污水中抗生素的处理方法研究进展[J]. 化工进展, 2014, 33(9): 2471-2477.
	Luo Y, Huang B, Jin Y, et al. Research progress in the degradation of antibiotics wastewater treatment[J]. Chemical Industry and Engineering Progress, 2014, 33(9): 2471-2477.
7	Xu J, Zhang Y, Zhou C, et al. Distribution, sources and composition of antibiotics in sediment, overlying water and pore water from Taihu Lake, China[J]. Science of the Total Environment, 2014, 497: 267-273.
8	Bilal M, Ashraf S S, Barceló D, et al. Biocatalytic degradation/redefining “removal” fate of pharmaceutically active compounds and antibiotics in the aquatic environment[J]. Science of the Total Environment, 2019, 691: 1190-1211.
9	陆杰, 徐高田, 张玲, 等. 制药工业废水处理技术[J]. 工业水处理, 2001, 21(10): 1-4.
	Lu J, Xu G T, Zhang L, et al. Advances in pharmaceutical wastewater treatment technology[J]. Industrial Water Treatment, 2001, 21(10): 1-4.
10	刘昔, 王智, 王学雷, 等. 我国典型区域地表水环境中抗生素污染现状及其生态风险评价[J]. 环境科学, 2019, 40(5): 2094-2100.
	Liu X, Wang Z, Wang X L, et al. Status of antibiotic contamination and ecological risks assessment of several typical Chinese surface-water environments [J]. Environmental Science, 2019, 40(5): 2094-2100.
11	许文豪, 白文杰, 曾希野, 等. 氧化石墨烯复合材料对废水中抗生素吸附分离的研究进展[J]. 现代盐化工, 2019, 3: 45-46.
	Xu W H, Bai W J, Zeng X Y, et al. Advances in the study on the adsorption and separation of antibiotics from wastewater by GO composites [J]. Modern Salt and Chemical Industry, 2019, 3: 45-46.
12	Homem V, Santos L. Degradation and removal methods of antibiotics from aqueous matrices—a review[J]. Journal of Environmental Management, 2011, 92(10): 2304-2347.
13	Kråkström M, Saeid S, Tolvanen P, et al. Catalytic ozonation of the antibiotic sulfadiazine: reaction kinetics and transformation mechanisms[J]. Chemosphere, 2020, 247: 125853.
14	Navalon S, Alvaro M, Garcia H. Reaction of chlorine dioxide with emergent water pollutants: product study of the reaction of three β-lactam antibiotics with ClO2[J]. Water Research, 2008, 42(8/9): 1935-1942.
15	吴汝林, 张凤华. 活性污泥法对制药废水的治理[J]. 山东化工, 2009, 38(1): 15-17.
	Wu R L, Zhang F H. The treatment of pharmaceutical wastewater through the method of activated sludge[J]. Shandong Chemical Industry, 2009, 38(1): 15-17.
16	Wang T, Pan X, Ben W, et al. Adsorptive removal of antibiotics from water using magnetic ion exchange resin[J]. Journal of Environmental Sciences, 2017, 52: 111-117.
17	Lan L, Kong X, Sun H, et al. High removal efficiency of antibiotic resistance genes in swine wastewater via nanofiltration and reverse osmosis processes[J]. Journal of Environmental Management, 2019, 231: 439-445.
18	Ahmaruzzaman M, Sharma D K. Adsorption of phenols from wastewater[J]. Journal of Colloid and Interface Science, 2005, 287(1): 14-24.
19	González-García P. Activated carbon from lignocellulosics precursors: a review of the synthesis methods, characterization techniques and applications[J]. Renewable and Sustainable Energy Reviews, 2018, 82: 1393-1414.
20	Danish M, Ahmad T. A review on utilization of wood biomass as a sustainable precursor for activated carbon production and application[J]. Renewable and Sustainable Energy Reviews, 2018, 87: 1-21.
21	Ao W, Fu J, Mao X, et al. Microwave assisted preparation of activated carbon from biomass: a review[J]. Renewable and Sustainable Energy Reviews, 2018, 92: 958-979.
22	Shakoor M B, Ali S, Rizwan M, et al. A review of biochar-based sorbents for separation of heavy metals from water[J]. International Journal of Phytoremediation, 2020, 22(2): 111-126.
23	Singh S, Kumar V, Datta S, et al. Current advancement and future prospect of biosorbents for bioremediation[J]. Science of the Total Environment, 2019, 709: 135895.
24	Kosheleva R I, Mitropoulos A C, Kyzas G Z. Synthesis of activated carbon from food waste[J]. Environmental Chemistry Letters, 2019, 17(1): 429-438.
25	Supanchaiyamat N, Jetsrisuparb K, Knijnenburg J T N, et al. Lignin materials for adsorption: current trend, perspectives and opportunities[J]. Bioresource Technology, 2019, 272: 570-581.
26	Correa C R, Kruse A. Biobased functional carbon materials: production, characterization, and applications—a review[J]. Materials, 2018, 11(9): 1568.
27	Ukanwa K S, Patchigolla K, Sakrabani R, et al. A review of chemicals to produce activated carbon from agricultural waste biomass[J]. Sustainability, 2019, 11(22): 6204.
28	Bridgwater A V, Peacocke G V C. Fast pyrolysis processes for biomass[J]. Renewable and Sustainable Energy Reviews, 2000, 4(1): 1-73.
29	Demirbas A, Arin G. An overview of biomass pyrolysis[J]. Energy Sources, 2002, 24(5): 471-482.
30	莫官海, 谢水波, 曾涛涛, 等. 污泥基生物炭处理酸性含U(Ⅵ)废水的效能与机理[J]. 化工学报, 2020, 71(5): 2352-2362.
	Mo G H, Xie S B, Zeng T T, et al. The efficiency and mechanism of U(Ⅵ) removal from acidic wastewater by sewage sludge-derived biochar[J]. CIESC Journal, 2020, 71(5): 2352-2362.
31	王怀臣, 冯雷雨, 陈银广. 废物资源化制备生物炭及其应用的研究进展[J]. 化工进展, 2012, 31(4): 907-914.
	Wang H C, Feng L Y, Chen Y G. Advances in biochar production from wastes and its applications[J]. Chemical Industry and Engineering Progress, 2012, 31(4): 907-914.
32	Stefanidis S D, Kalogiannis K G, Iliopoulou E F, et al. A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin[J]. Journal of Analytical and Applied Pyrolysis, 2014, 105: 143-150.
33	Bouchelta C, Medjram M S, Zoubida M, et al. Effects of pyrolysis conditions on the porous structure development of date pits activated carbon[J]. Journal of Analytical and Applied Pyrolysis, 2012, 94: 215-222.
34	Carrier M, Joubert J E, Danje S, et al. Impact of the lignocellulosic material on fast pyrolysis yields and product quality[J]. Bioresource Technology, 2013, 150: 129-138.
35	Cabal B, Budinova T, Ania C O, et al. Adsorption of naphthalene from aqueous solution on activated carbons obtained from bean pods[J]. Journal of Hazardous Materials, 2009, 161(2/3): 1150-1156.
36	García-Mateos F J, Ruiz-Rosas R, Marqués M D, et al. Removal of paracetamol on biomass-derived activated carbon: modeling the fixed bed breakthrough curves using batch adsorption experiments[J]. Chemical Engineering Journal, 2015, 279: 18-30.
37	Moro T R, Henrique F R, Malucelli L C, et al. Adsorption of pharmaceuticals in water through lignocellulosic fibers synergism[J]. Chemosphere, 2017, 171: 57-65.
38	Xie A, Dai J, Cui J, et al. Novel graphene oxide–confined nanospace directed synthesis of glucose-based porous carbon nanosheets with enhanced adsorption performance[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(12): 11566-11576.
39	Luo H, Zhang Y, Xie Y, et al. Iron-rich microorganism-enabled synthesis of magnetic biocarbon for efficient adsorption of diclofenac from aqueous solution[J]. Bioresource Technology, 2019, 282: 310-317.
40	Regkouzas P, Diamadopoulos E. Adsorption of selected organic micro-pollutants on sewage sludge biochar[J]. Chemosphere, 2019, 224: 840-851.
41	Sekulic M T, Boskovic N, Milanovic M, et al. An insight into the adsorption of three emerging pharmaceutical contaminants on multifunctional carbonous adsorbent: mechanisms, modelling and metal coadsorption[J]. Journal of Molecular Liquids, 2019, 284: 372-382.
42	Paunovic O, Pap S, Maletic S, et al. Ionisable emerging pharmaceutical adsorption onto microwave functionalised biochar derived from novel lignocellulosic waste biomass[J]. Journal of Colloid and Interface Science, 2019, 547: 350-360.
43	Shi Y, Liu G, Wang L, et al. Heteroatom-doped porous carbons from sucrose and phytic acid for adsorptive desulfurization and sulfamethoxazole removal: a comparison between aqueous and non-aqueous adsorption[J]. Journal of Colloid and Interface Science, 2019, 557: 336-348.
44	Kadam A A, Sharma B, Saratale G D, et al. Super-magnetization of pectin from orange-peel biomass for sulfamethoxazole adsorption[J]. Cellulose, 2020, 27(6): 3301-3318.
45	Zbair M, Ojala S, Khallok H, et al. Structured carbon foam derived from waste biomass: application to endocrine disruptor adsorption[J]. Environmental Science and Pollution Research, 2019, 26(31): 32589-32599.
46	Nielsen L, Zhang P, Bandosz T J. Adsorption of carbamazepine on sludge/fish waste derived adsorbents: effect of surface chemistry and texture[J]. Chemical Engineering Journal, 2015, 267: 170-181.
47	Álvarez-Torrellas S, Ribeiro R S, Gomes H T, et al. Removal of antibiotic compounds by adsorption using glycerol-based carbon materials[J]. Chemical Engineering Journal, 2016, 296: 277-288.
48	Varjani S, Joshi R, Srivastava V K, et al. Treatment of wastewater from petroleum industry: current practices and perspectives[J]. Environmental Science and Pollution Research, 2020, 27: 27172-27180.
49	Liu X, Zhang Y, Li Z, et al. Characterization of corncob-derived biochar and pyrolysis kinetics in comparison with corn stalk and sawdust[J]. Bioresource Technology, 2014, 170: 76-82.
50	Kołtowski M, Hilber I, Bucheli T D, et al. Activated biochars reduce the exposure of polycyclic aromatic hydrocarbons in industrially contaminated soils[J]. Chemical Engineering Journal, 2017, 310: 33-40.
51	Takaya C A, Fletcher L A, Singh S, et al. Recovery of phosphate with chemically modified biochars[J]. Journal of Environmental Chemical Engineering, 2016, 4(1): 1156-1165.
52	Lin L, Qiu W, Wang D, et al. Arsenic removal in aqueous solution by a novel Fe-Mn modified biochar composite: characterization and mechanism[J]. Ecotoxicology and Environmental Safety, 2017, 144: 514-521.
53	de Caprariis B, de Filippis P, Hernandez A D, et al. Pyrolysis wastewater treatment by adsorption on biochars produced by poplar biomass[J]. Journal of Environmental Management, 2017, 197: 231-238.
54	Iriarte-Velasco U, Sierra I, Zudaire L, et al. Preparation of a porous biochar from the acid activation of pork bones[J]. Food and Bioproducts Processing, 2016, 98: 341-353.
55	Qu H, Zhang X, Zhan J, et al. Biomass-based nitrogen-doped hollow carbon nanospheres derived directly from glucose and glucosamine: structural evolution and supercapacitor properties[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(6): 7380-7389.
56	Yang D, Wang L, Li Z, et al. Simultaneous adsorption of Cd(Ⅱ) and As(Ⅲ) by a novel biochar-supported nanoscale zero-valent iron in aqueous systems[J]. Science of the Total Environment, 2020, 708: 134823.
57	Inyang M, Gao B, Yao Y, et al. Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass[J]. Bioresource Technology, 2012, 110: 50-56.
58	Krishnan D, Raidongia K, Shao J, et al. Graphene oxide assisted hydrothermal carbonization of carbon hydrates[J]. ACS Nano, 2014, 8(1): 449-457.
59	Regmi P, Moscoso J L G, Kumar S, et al. Removal of copper and cadmium from aqueous solution using switchgrass biochar produced via hydrothermal carbonization process[J]. Journal of Environmental Management, 2012, 109: 61-69.
60	Chen B, Zhou D, Zhu L. Transitional adsorption and partition of nonpolar and polar aromatic contaminants by biochars of pine needles with different pyrolytic temperatures[J]. Environmental Science & Technology, 2008, 42(14): 5137-5143.
61	Liu Z, Zhang F S. Removal of lead from water using biochars prepared from hydrothermal liquefaction of biomass[J]. Journal of Hazardous Materials, 2009, 167(1/2/3): 933-939.
62	Kumar P S, Abhinaya R V, Lashmi K G, et al. Adsorption of methylene blue dye from aqueous solution by agricultural waste: equilibrium, thermodynamics, kinetics, mechanism and process design[J]. Colloid Journal, 2011, 73(5): 651.
63	Zeng Z, Ye S, Wu H, et al. Research on the sustainable efficacy of g-MoS2 decorated biochar nanocomposites for removing tetracycline hydrochloride from antibiotic-polluted aqueous solution[J]. Science of the Total Environment, 2019, 648: 206-217.
64	Li Y, Taggart M A, McKenzie C, et al. Utilizing low-cost natural waste for the removal of pharmaceuticals from water: mechanisms, isotherms and kinetics at low concentrations[J]. Journal of Cleaner Production, 2019, 227: 88-97.
65	Heo J, Yoon Y, Lee G, et al. Enhanced adsorption of bisphenol A and sulfamethoxazole by a novel magnetic CuZnFe2O4–biochar composite[J]. Bioresource Technology, 2019, 281: 179-187.
66	Tian S Q, Wang L, Liu Y L, et al. Enhanced permanganate oxidation of sulfamethoxazole and removal of dissolved organics with biochar: formation of highly oxidative manganese intermediate species and in situ activation of biochar[J]. Environmental Science & Technology, 2019, 53(9): 5282-5291.
67	Ashiq A, Sarkar B, Adassooriya N, et al. Sorption process of municipal solid waste biochar-montmorillonite composite for ciprofloxacin removal in aqueous media[J]. Chemosphere, 2019, 236: 124384.
68	Anfar Z, Zbair M, Ahsiane H A, et al. Microwave assisted green synthesis of Fe2O3/biochar for ultrasonic removal of nonsteroidal anti-inflammatory pharmaceuticals[J]. RSC Advances, 2020, 10(19): 11371-11380.
69	Hu Y, Zhu Y, Zhang Y, et al. An efficient adsorbent: simultaneous activated and magnetic ZnO doped biochar derived from camphor leaves for ciprofloxacin adsorption[J]. Bioresource Technology, 2019, 288: 121511.
70	Cui J, Xu X, Yang L, et al. Soft foam-like UiO-66/polydopamine/bacterial cellulose composite for the removal of aspirin and tetracycline hydrochloride[J]. Chemical Engineering Journal, 2020, 395: 125174.
71	Gupta K, Khatri O P. Fast and efficient adsorptive removal of organic dyes and active pharmaceutical ingredient by microporous carbon: effect of molecular size and charge[J]. Chemical Engineering Journal, 2019, 378: 122218.

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