化工学报 ›› 2021, Vol. 72 ›› Issue (S1): 421-429.doi: 10.11949/0438-1157.20201315
WU Zhongjie1(),LIU Zeyan2,XIE Lianke1,CUI Mei2,HUANG Renliang2(
)
摘要:
聚偏氟乙烯(PVDF)膜因其优异的化学和力学稳定性而被广泛应用于水处理领域,但PVDF膜本身的疏水性,容易使其在处理含油废水的过程中被油滴污染,造成膜孔堵塞。以PVDF微滤膜为基底,通过单宁酸(TA)和聚乙烯亚胺(PEI)共沉积形成了TA/PEI黏附层,经戊二醛共价交联和接枝半胱氨酸(Cys),制备了一种PVDF改性膜(PVDF@TA/PEI-Cys)。改性后的PVDF膜具有良好的亲水性和水下超疏油性,水接触角和水下油接触角分别为22.2°和150.2°。在0.09 MPa下,PVDF@TA/PEI-Cys膜的纯水通量达6328 L/(m2·h),水包油型乳液分离效率高达99.9%。此外,该改性膜还可同时吸附水中的汞离子,最大吸附量为24.7 mg/g。
中图分类号:
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