化工学报 ›› 2021, Vol. 72 ›› Issue (2): 1036-1046.DOI: 10.11949/0438-1157.20201393

• 分离工程 • 上一篇    下一篇

快速变压吸附制氢工艺的模拟与分析

钮朝阳(),江南,沈圆辉,吴统波,刘冰,张东辉()   

  1. 天津大学化工学院,化学工程研究所,化学工程联合国家重点实验室,天津 300350
  • 收稿日期:2020-10-09 修回日期:2020-12-25 出版日期:2021-02-05 发布日期:2021-02-05
  • 通讯作者: 张东辉
  • 作者简介:钮朝阳(1997—),男,硕士研究生,1719842596@qq.com
  • 基金资助:
    国家重点研发计划项目(2019YFB1505000)

Simulation and analysis of rapid pressure swing adsorption for hydrogen production

NIU Zhaoyang(),JIANG Nan,SHEN Yuanhui,WU Tongbo,LIU Bing,ZHANG Donghui()   

  1. State Key Laboratory of Chemical Engineering, Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
  • Received:2020-10-09 Revised:2020-12-25 Online:2021-02-05 Published:2021-02-05
  • Contact: ZHANG Donghui

摘要:

目前工业上主要通过变压吸附技术从蒸汽甲烷重整气中制取氢产品气。然而,能源需求量的快速增加使得传统变压吸附技术在产量方面的不足越发明显。为此,进行了快速变压吸附从蒸汽甲烷重整气中制取氢气的模拟研究。采用活性炭和5A分子筛作为吸附剂,并以测得的原料气中各组分在两种吸附剂上的吸附数据为基础,进行了六塔快速变压吸附工艺的数值模拟与分析。在分析了塔内温度、压力和固相的浓度分布后,探究了进料流量、双层吸附剂高度比以及冲洗进料比三个操作参数对于快速变压吸附工艺性能的影响,结果表明:原料气组成为H2/CH4/CO/CO2=76%/3.5%/0.5%/20%,吸附压力为22 bar(1 bar=105 Pa),解吸吹扫压力为1.0 bar,处理量为0.8875 mol·s-1,吸附剂床层高度比为0.5∶0.5,冲洗进料比为22.37%时,可获得H2纯度99.90%,回收率69.88%,此时H2产量为0.4713 mol·s-1。相比之下,氢气纯度为99.90%时,尽管PSA工艺回收率为83.40%,但处理量只有0.39 mol·s-1,因此H2产量仅为0.2472 mol·s-1

关键词: 快速变压吸附, 双层吸附剂, 蒸汽甲烷重整, 制氢, 数值模拟

Abstract:

At present, pressure swing adsorption is the main technology to produce hydrogen product gas from steam methane reformed gas in the industry. However, the rapid increase in energy demand makes the shortcomings of traditional pressure swing adsorption technology more obvious in terms of productivity. For this reason, a simulation study of hydrogen production from steam methane reformed gas by rapid pressure swing adsorption was carried out. The activated carbon and 5A zeolite were used as adsorbents and the numerical simulation and analysis of six bed rapid pressure swing adsorption process were carried out based on the measured adsorption data of each component in the feed gas on the two adsorbents. After analyzing the temperature, pressure and gas and solid concentration distribution in the bed, the three operating parameters of the feed flow rate, the height ratio of the two-layer adsorbent and purge-to-feed ratio have been investigated for the effect of the rapid pressure swing adsorption process performance. When the feed gas composition is H2/CH4/CO/CO2=76%/3.5%/0.5%/20%, the adsorption pressure is 22 bar, the pressure of purge desorption is 1.0 bar, the feed flow rate is 0.8875 mol·s-1, the adsorbent bed height ratio is 0.5∶0.5, and purge-to-feed ratio is 22.37%, the purity of H2 is 99.90% and the recovery is 69.88%. At this time, the yield of H2 is 0.4713 mol·s-1. In contrast, although the H2 recovery of the PSA process is 83.40%, the processing capacity is only 0.39 mol·s-1, so the productivity is only 0.2472 mol·s-1 when the purity is 99.90%.

Key words: rapid pressure swing adsorption, double layer adsorbent, steam methane reforming, hydrogen production, numerical simulation

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