智能膜对传质和反应与分离过程的调控

doi:10.11949/j.issn.0438-1157.20150850

化工学报 ›› 2015, Vol. 66 ›› Issue (9): 3279-3286.DOI: 10.11949/j.issn.0438-1157.20150850

智能膜对传质和反应与分离过程的调控

谢锐, 巨晓洁, 汪伟, 刘壮, 褚良银

四川大学化学工程学院, 四川成都 610065

收稿日期:2015-06-08 修回日期:2015-07-03 出版日期:2015-09-05 发布日期:2015-09-05
通讯作者: 褚良银
基金资助:
国家自然科学基金项目(21490582,21276162)。

Regulation on rates of mass transfer, reaction and separation via smart membranes

XIE Rui, JU Xiaojie, WANG Wei, LIU Zhuang, CHU Liangyin

School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

Received:2015-06-08 Revised:2015-07-03 Online:2015-09-05 Published:2015-09-05
Supported by:
supported by the National Natural Science Foundation of China (21490582, 21276162).

摘要/Abstract

摘要：

智能膜能响应外界刺激而改变自身的表面特性和膜孔大小,从而改变其选择性和渗透性等性能参数,是化工与材料等交叉学科领域的重要课题。综述了近年来有关智能膜用于跨膜传质过程的调控、亲和分离过程的调控、催化反应过程速率的调控等方面的研究。基于智能膜的传质、反应与分离过程具有条件温和、易于操控、易调控、高效等特点,为简单、高效的传质分离与反应操作提供了新途径和新方法。

关键词: 膜, 环境响应, 反应, 分离, 传质, 亲和吸附

Abstract:

Smart membranes change their surface wettability and pore size, and thus selectivity and permeability in response to the environmental stimuli, which are active topics of interdisciplines based on chemical engineering and materials science etc. The recent studies on the regulation of trans-membrane mass transfer and catalytic reaction rates as well as affinity separation efficiency based on smart membranes have been reviewed. Such processes provide attractive features such as mild condition, easy operation and regulation, and high efficiency, which provide new ways to achieve simple and high-efficient operations of mass transfer, separation and reaction.

Key words: membranes, stimuli-response, reaction, separation, mass transfer, affinity adsorption

中图分类号:

TQ028.8

谢锐, 巨晓洁, 汪伟, 刘壮, 褚良银. 智能膜对传质和反应与分离过程的调控[J]. 化工学报, 2015, 66(9): 3279-3286.

XIE Rui, JU Xiaojie, WANG Wei, LIU Zhuang, CHU Liangyin. Regulation on rates of mass transfer, reaction and separation via smart membranes[J]. CIESC Journal, 2015, 66(9): 3279-3286.

参考文献 25

[1]	Li P F, Xie R, Jiang J C, Meng T, Yang M, Ju X J, Yang L, Chu L Y. Thermo-responsive gating membranes with controllable length and density of poly(N-isopropylacrylamide) chains grafted by ATRP method [J]. Journal of Membrane Science, 2009, 337(1/2): 310-317.
[2]	Xie R, Li Y, Chu L Y. Preparation of thermo-responsive gating membranes with controllable response temperature [J]. Journal of Membrane Science, 2007, 289(1/2): 76-85.
[3]	Luo T, Lin S, Xie R, Ju X J, Liu Z, Wang W, Mou C L, Zhao C S, Chen Q M, Chu L Y. pH-Responsive poly(ether sulfone) composite membranes blended with amphiphilic polystyrene-block-poly(acrylic acid) copolymers[J]. Journal of Membrane Science, 2014, 450: 162-173.
[4]	Xia L W, Xie R, Ju X J, Wang W, Chen Q M, Chu L Y. Nano-structured smart hydrogels with rapid response and high elasticity [J]. Nature Communications, 2013, 4: 2226. doi: 10.1038/ncomms3226.
[5]	Wang J Y, Jin Y, Xie R, Liu J Y, Ju X J, Meng T, Chu L Y. Novel calcium-alginate capsules with aqueous core and thermo-responsive membrane [J]. Journal of Colloid and Interface Science, 2011, 353(1): 61-68.
[6]	Song X L, Xie R, Luo T, Ju X J, Wang W, Chu L Y. Ethanol-responsive characteristics of polyethersulfone composite membranes blended with poly(N-isopropylacrylamide) nanogels [J]. Journal of Applied Polymer Science, 2014, 131: 41032.
[7]	Wang G, Xie R, Ju X J, Chu L Y. Thermo-responsive polyethersulfone composite membranes blended with poly(N-isopropylacrylamide) nanogels [J]. Chemical Engineering and Technology, 2012, 35(11): 2015-2022.
[8]	Wei J, Ju X J, Zou X Y, Xie R, Wang W, Liu Y M, Chu L Y. Multi-stimuli-responsive microcapsules for adjustable controlled- release [J]. Advanced Functional Materials, 2014, 24(22): 3312-3323.
[9]	Yu Y L, Zhang M J, Xie R, Ju X J, Wang J Y, Pi S W, Chu L Y. Thermo-responsive monodisperse core-shell microspheres with PNIPAM core and biocompatible porous ethyl cellulose shell embedded with PNIPAM gates [J]. Journal of Colloid and Interface Science, 2012, 376(1): 97-106.
[10]	Yang M, Xie R, Wang J Y, Ju X J, Yang L, Chu L Y. Gating characteristics of thermo-responsive and molecular-recognizable membranes based on poly(N-isopropylacrylamide) and β-cyclodextrin [J]. Journal of Membrane Science, 2010, 355(1/2): 142-150.
[11]	Zhang M J, Wang W, Xie R, Ju X J, Liu L, Gu Y Y, Chu L Y. Microfluidic fabrication of monodisperse microcapsules for glucose- response at physiological temperature [J]. Soft Matter, 2013, 9(16): 4150-4159.
[12]	Yanagioka M, Kurita H, Yamaguchi T, Nakao S I. Development of amolecular recognition separation membrane using cyclodextrin complexation controlled by thermosensitive polymer chains [J]. Industrial & Engineering Chemistry Research, 2003, 42: 380-385.
[13]	Ito T, Hioki T, Yamaguchi T, Shinbo T, Nakao S I, Kimura S. Development of a molecular recognition ion gating membrane and estimation of its pore size control [J]. Journal of the American Chemical Society, 2002, 124(26): 7840-7846.
[14]	Yang C, Xie R, Liang W G, Ju X J, Wang W, Zhang M J, Liu Z, Chu L Y. Beta-cyclodextrin-based molecular-recognizable smart microcapsules for controlled release [J]. Journal of Materials Science, 2014, 49(20): 6862-6871
[15]	Yang Chao (杨超), Xie Rui (谢锐), Ju Xiaojie (巨晓洁), Wang Wei (汪伟), Chu Liangyin (褚良银). Fabrication and controlled-release characteristics of molecular-recognizable smart microcapsules [J]. Chemical Industry and Engineering Process(化工进展),2014,34(1):183-187.
[16]	Meng T, Xie R, Chen Y C, Cheng C J, Li P F, Ju X J, Chu L Y. A thermo-responsive affinity membrane with nano-structured pores and grafted poly(N-isopropylacrylamide) surface layer for hydrophobic adsorption [J]. Journal of Membrane Science, 2010, 349(1/2): 258-267.
[17]	Xie R, Zhang S B, Wang H D, Yang M, Li P F, Zhu X L, Chu L Y. Temperature-dependent molecular-recognizable membranes based on poly(N-isopropylacrylamide) and b-cyclodextrin [J]. Journal of Membrane Science, 2009, 326(2): 618-626.
[18]	Yang M, Chu L Y, Wang H D, Xie R, Song H, Niu C H. A novel thermo-responsive membrane for chiral resolution [J]. Advanced Functional Materials, 2008, 18(4): 652-663.
[19]	Akamatsu K, Yamaguchi T. Novel preparation method for obtaining pH-responsive core-shell microcapsule reactors [J]. Industrial & Engineering Chemistry Research, 2007, 46(1): 124-130.
[20]	Kokufuta E, Shimizu N, Nakamura I. Preparation of polyelectrolyte-coated pH-sensitive poly (styrene) microcapsules and their application to initiation-essation control of an enzyme reaction [J]. Biotechnology and Bioengineering, 1988, 32(3): 289-294.
[21]	Zhang Y, Wu H, Li J, Li L, Jiang Y, Jiang Y, Jiang Z. Protamine-templated biomimetic hybrid capsules: efficient and stable carrier for enzyme encapsulation [J]. Chemistry of Materials, 2007, 20(3): 1041-1048.
[22]	Wang J Y, Yu H R, Xie R, Ju X J, Yu Y L, Zhang Z, Chu L Y. Alginate/protamine/silica hybrid capsules with ultrathin membranes for laccase immobilization [J] . AIChE Journal, 2013, 59(2): 380-389.
[23]	Wu F, Wang W, Liu L, Ju X J, Xie R, Liu Z, Chu L Y. Monodisperse hybrid microcapsules with ultrathin shell of submicron thickness for rapid enzyme reaction [J]. Journal of Materials Chemistry B, 2015, 3(5): 796-803.
[24]	Mei L, Xie R, Yang C, Ju X J, Wang J Y, Zhang Z, Chu L Y. Bio-inspired mini-eggs with pH-responsive membrane for enzyme immobilization [J]. Journal of Membrane Science, 2013, 429: 313-322.
[25]	Mei L, Xie R, Yang C, Ju X J, Wang W, Wang J Y, Chu L Y. pH-responsive Ca-alginate-based capsule membranes with grafted poly(methacrylic acid) brushes for controllable enzyme reaction [J]. Chemical Engineering Journal, 2013, 232: 573-581.

智能膜对传质和反应与分离过程的调控

Regulation on rates of mass transfer, reaction and separation via smart membranes

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