多相传质过程中的Marangoni效应

doi:10.3969/j.issn.0438-1157.2013.01.015

化工学报 ›› 2013, Vol. 64 ›› Issue (1): 124-132.DOI: 10.3969/j.issn.0438-1157.2013.01.015

多相传质过程中的Marangoni效应

汪洋, 陈杰, 王智慧, 杨超, 毛在砂

中国科学院过程工程研究所,绿色过程与工程重点实验室,北京 100190

收稿日期:2012-07-27 修回日期:2012-09-10 出版日期:2013-01-05 发布日期:2013-01-05
通讯作者: 杨超
作者简介:汪洋(1979—),男,博士后。
基金资助:
国家重点基础研究发展计划项目(2012CB224806);国家自然科学基金项目(21106150, 20990224);国家杰出青年科学基金项目(21025627);国家高技术研究发展计划项目(2012AA03A606)。

Marangoni effect accompanying mass transfer processes in multiphase systems

WANG Yang, CHEN Jie, WANG Zhihui, YANG Chao, MAO Zaisha

Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2012-07-27 Revised:2012-09-10 Online:2013-01-05 Published:2013-01-05
Supported by:
supported by the National Basic Research Program of China (2012CB224806),the National Natural Science Foundation of China (21106150, 20990224),the National Science Fund for Distinguished Young Scholars (21025627) and the High-tech Research and Development Program of China (2012AA03A606).

摘要/Abstract

摘要： Marangoni效应广泛存在于液液、气液相际传质过程中,通常会对传质速率产生重要影响。对Marangoni效应的实验及理论研究有助于增进对微观传质机理的理解,是强化相间传质过程效率的重要因素。重点介绍了液液体系中单液滴萃取的实验和模拟研究,对液液体系中Marangoni效应不稳定性的判据,对气液体系有效传质面积的影响,以及两种体系中利用表面活性剂进行传质调控的研究等方面的进展进行了综述,还探讨了传质过程中Marangoni效应应用研究的方向。

关键词: Marangoni效应, 传质, 表面活性剂, 液滴, 气泡, 数值模拟

Abstract: Marangoni effect, occurring frequently in interphase mass transfer processes in liquid-liquid and gas-liquid systems, plays an important role in determining the mass transfer rate.Experimental and theoretical studies on Marangoni effect will enhance the understanding on microscopic mechanism of interphase mass transfer and help in optimizing the operation of mass transfer units.The reported results on the criterion of instability in liquid-liquid systems, effective mass transfer area in gas-liquid systems, manipulation of Marangoni effect using surfactants in both systems, especially single droplet extraction, are reviewed.The topics of future study are also suggested.

Key words: Marangoni effect, mass transfer, surfactant, droplet, bubble, numerical simulation

中图分类号:

TQ021.4

汪洋, 陈杰, 王智慧, 杨超, 毛在砂. 多相传质过程中的Marangoni效应[J]. 化工学报, 2013, 64(1): 124-132.

WANG Yang, CHEN Jie, WANG Zhihui, YANG Chao, MAO Zaisha. Marangoni effect accompanying mass transfer processes in multiphase systems[J]. CIESC Journal, 2013, 64(1): 124-132.

参考文献 56

[1]	Sears F W.Mechanics, Wave Motion and Heat[M].Massachusetts:Addison-Wesley Pub.Co.,1958
[2]	Lewis J B, Pratt H R C.Oscillating droplets[J].Nature, 1953,171:1155-1156
[3]	Bakker C A P, van Buytenen P M, Beek W J.Interfacial phenomena and mass transfer[J].Chem.Eng.Sci., 1966,21(11):1039-1046
[4]	Perez de Ortiz E S, Sawistowski H.Interfacial stability of binary liquid-liquid systems(Ⅱ):Stability behaviour of selected systems[J].Chem.Eng.Sci., 1973,28(11):2063-2069
[5]	Sherwood T K, Wei J C.Interfacial phenomena in liquid extraction[J].Ind.Eng.Chem., 1957,49(6):1030-1034
[6]	Maroudas N G, Sawistowski H.Simultaneous transfer of two solutes across liquid-liquid interfaces[J].Chem. Eng. Sci., 1964,19(11):919-931
[7]	Wegener M, Grunig J, Stuber J, et al.Transient rise velocity and mass transfer of a single drop with interfacial instabilities-experimental investigations[J]. Chem. Eng. Sci., 2007,62(11):2967-2978
[8]	Sternling C V, Scriven L E.Interfacial turbulence:hydrodynamic instability and the Marangoni effect[J].AIChE J., 1959,5(4):514-523
[9]	Hennenberg M, Bisch P M, Vignes-Adler M, et al.Mass transfer, Marangoni effect and instability of interfacial longitudinal waves(Ⅰ):Diffusional exchanges[J].J.Colloid Interf.Sci., 1979,69(1):128-137
[10]	Nakache E, Dupeyrat M, Vignes-Adler M.Experimental and theoretical study of an interfacial instability at some oil-water interfaces involving a surface-active agent(Ⅰ):Physicochemical description and outlines for a theoretical approach[J].J.Colloid Interf.Sci., 1983,94(1):187-200
[11]	Slavtchev S, Hennenberg M, Legros J C, et al.Stationary solutal Marangoni instability in a two-layer system[J].J.Colloid Interf.Sci., 1998,203(2):354-368
[12]	Slavtchev S, Mendes-Tatsis M A.Marangoni instability in binary liquid-liquid systems[J].Int.J.Heat Mass Transfer, 2004,47(14/15/16):3269-3278
[13]	Agble D, Mendes-Tatsis M A.The prediction of Marangoni convection in binary liquid-liquid systems with added surfactants[J].Int.J.Heat Mass Transfer, 2001,44(7):1439-1449
[14]	Sawistowski H.Recent advances in liquid-liquid extraction//Hanson C.Solvent Extraction Processes[M].Oxford:Pergamon Press, 1971:293-365
[15]	Mao Z S, Chen J Y.Numerical simulation of the Marangoni effect on mass transfer to single slowly moving drops in the liquid-liquid system[J].Chem.Eng.Sci., 2004,59(8/9):1815-1828
[16]	Petera J, Weatherley L R.Modeling of mass transfer from falling droplets[J].Chem.Eng.Sci., 2001,56(16):4929-4947
[17]	Davidson M R, Rudman M.Volume-of-fluid calculation of heat or mass transfer across deforming interfaces in two-fluid flow[J].Num.Heat Transfer B Fundam., 2002,41(3/4):291-308
[18]	Kiran B D, William B Z.Simulation of interfacial mass transfer by droplet dynamics using the level set method[J].Chem.Eng.Sci., 2006,61(19):6486-6498
[19]	Wang J F, Yang C, Mao Z S.A simple weighted integration method for calculating curvature for suppression of parasitic flow in the level set approach[J].Chinese J.Chem.Eng., 2006,14(6):740-746
[20]	Wang J F, Yang C, Mao Z S.Numerical simulation of Marangoni effects induced by interphase mass transfer to single drops in liquid-liquid extraction systems by the level set method[J].Sci.China Ser.B-Chem., 2008,51(7):684-694
[21]	Wang J F, Wang Z H, Lu P, et al.Numerical simulation of the Marangoni effect on transient mass transfer from single moving deformable drops[J].AIChE J., 2011,57(10):2670-2683
[22]	Wang Z H, Lu P, Zhang G J, et al.Experimental investigation of Marangoni effect in 1-hexanol/water system[J].Chem.Eng.Sci., 2011,66:2883-2887
[23]	Wegener M, Paschedag A R, Kraume M.Mass transfer enhancement through Marangoni instabilities during single drop formation[J].Int.J.Heat Mass Transfer, 2009,52:2673-2677
[24]	Steiner L, Oezdemir G, Hartlant S.Single-drop mass transfer in the water-toluene-acetone system[J].Ind. Eng. Chem.Res., 1990,29(7):1313-1318
[25]	Temos J, Pratt H R C, Stevens G W.Mass transfer to freely moving drops[J].Chem.Eng.Sci., 1996,51(1):27-36
[26]	Wegener M, Eppinger T, Baumler K, et al.Transient rise velocity and mass transfer of a single drop with interfacial instabilities—numerical investigations[J].Chem. Eng. Sci., 2009,64(23):4835-4845
[27]	Arendt B, Eggers R. Interaction of Marangoni convection with mass transfer effects at droplets[J].Int.J.Heat Mass Transfer, 2007,50(13/14):2805-2815
[28]	Agble D, Mendes-Tatsis M A. The effect of surfactants on interfacial mass transfer in binary liquid-liquid systems[J].Int.J.Heat Mass Transfer, 2000,43(6):1025-1034
[29]	Wang Zhihui(王智慧).Effect of surfactants on Marangoni effect induced by mass transfer in liquid-liquid systems[D].Beijing:Institute of Process Engineering, Chinese Academy of Sciences, 2011
[30]	Wegener M, Paschedag A R.The effect of soluble anionic surfactants on rise velocity and mass transfer at single droplets in systems with Marangoni instabilities[J].Int.J.Heat Mass Transfer, 2012,55(5/6):1561-1573
[31]	Sobieszuk P, Pohorecki R, Cyganski P, et al.Marangoni effect in a falling film microreactor[J].Chem.Eng.J., 2010,164(1):10-15
[32]	Sun Z F, Yu K T, Wang S Y, et al.Absorption and desorption of carbon dioxide into and from organic solvents:effects of Rayleigh and Marangoni instability[J].Ind. Eng. Chem.Res., 2002,41(7):1905-1913
[33]	Buzek J.Some aspects of the mechanism of cellular convection[J].Chem.Eng.Sci., 1983,38(1):155-160
[34]	Brian P L T, Vivian J E, Mayr S T.Cellular convection in desorbing surface tension-lowering solutes from water[J].Ind.Eng.Chem.Fundam., 1971,10(1):75-83
[35]	Warmuzinski K, Buzek J.A model of cellular convection during absorption accompanied by chemical reaction[J].Chem.Eng.Sci., 1990,45(1):243-254
[36]	Imaishi N, Fujinawa K, Hozawa M, et al.Interfacial turbulence in gas-liquid mass transfer[J].Int. Chem. Eng., 1982,22(4):659-665
[37]	Zhou Chaofan(周超凡).Study on the influence of Marangoni effect and other factors on the mass transfer coefficients[D].Tianjin:Tianjin University, 2005
[38]	Ma Youguang(马友光), Wang Xiaohong(汪晓红), Cheng Hong(成弘), et al.Influence of surfactant on gas-liquid mass transfer[J].Journal of Chemical Industry and Engineering(China)(化工学报), 1998,49(3):358-361
[39]	Gomez-Diaz D, Navaza J M, Sanjurjo B.Mass-Transfer enhancement or reduction by surfactant presence at a gas-liquid interface[J].Ind.Eng.Chem.Res., 2009,48(5):2671-2677
[40]	Bond J, Donald M B.The effect of absorption on the wetted area of absorption towers[J].Chem.Eng.Sci., 1957,6(6):237-244
[41]	Moens F P.The effect of composition and driving force on the performance of packed distillation columns(Ⅰ)[J].Chem.Eng.Sci., 1972,27(2):275-284
[42]	Moens F P.The effect of composition and driving force on the performance of packed distillation columns(Ⅱ)[J].Chem.Eng.Sci., 1972,27(2):285-292
[43]	Proctor S J, Biddulph M W, Krishnamurthy K R.Effects of Marangoni surface tension forces on modern distillation packings[J].AIChE J., 1998,44(4):831-835
[44]	Zhang Zhibing(张志炳), Geng Jiao(耿皎), Zhang Feng(张锋), et al.Marangoni effect and vapour-liquid mass transfer process[J].Journal of Chemical Industry and Engineering(China)(化工学报), 2003,54:508-515
[45]	Boyadjiev C H R, Halatchev I.Non-linear mass transfer and Marangoni effect in gas-liquid systems[J].Int.J.Heat Mass Transfer, 1998,41(1):197-202
[46]	Arendt B, Dittmar D, Eggers R.Interaction of interfacial convection and mass transfer effects in the system CO2-water[J].Int.J.Heat Mass Transfer, 2004,47(17/18):3649-3657
[47]	Kim M H,Oh C Y, Kim D L.Transient Marangoni-buoyancy convection in rectangular tank with phase change[J].Int.Commun.Heat Mass Transfer, 2003,30(8):1115-1124
[48]	Lee C H, Ha J J, Chun B H, et al.Mathematical modeling and simulation for Marangoni convection by surfactants in liquid falling film[J].J.Chem.Eng.Japan, 2003,36(3):259-264
[49]	Yu Liming(余黎明).The study of Marangoni effect on the gas-liquid mass transfer process[D].Tianjin:Tianjin University, 2006
[50]	[JP2]Sawistowski H.Surface-tension-induced interfacial convection[JP] and its effect on rates of mass transfer[J].Chem. Ing. Tech., 1973,45(18):1093-1098
[51]	Mao Z S, Lu P, Zhang G J, et al.Numerical approach to the three-dimensional Marangoni effect in a two liquid layer system//International Solvent Extraction Conference(ISEC’2008)[C]. Tucson, AR, USA,2008
[52]	Chen S Y, Yuan X G, Fu B, et al.Simulation of interfacial Marangoni convection in gas-liquid mass transfer by lattice Boltzmann method[J].Front.Chem.Sci.Eng., 2011,5(4):448-454
[53]	Haeri S, Hashemabadi S H.Three dimensional CFD simulation and experimental study of power law fluid spreading on inclined plates[J].Int.Commun.Heat Mass Transfer, 2008,35(8):1041-1047
[54]	Rio E, Daerr A, Limat L.Probing with a laser sheet the contact angle distribution along a contact line[J].J.Colloid Interf.Sci., 2004,269(1):164-170
[55]	Gajewski A, Trela M.Effect of rivulet mass flow rate on the surface of wetted area[J].Arch.Thermodyn., 2002,23(1/2):101-125
[56]	Zhang Feng(张锋), Geng Jiao(耿皎), Wang Baorong(王宝荣), et al.Model for distribution of heated falling liquid film on vertical solid planar surface[J].Journal of Chemical Industry and Engineering(China)(化工学报), 2005,56(10):1837-1842

多相传质过程中的Marangoni效应

Marangoni effect accompanying mass transfer processes in multiphase systems

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