化工学报 ›› 2013, Vol. 64 ›› Issue (2): 407-414.DOI: 10.3969/j.issn.0438-1157.2013.02.003

• 综述与专论 • 上一篇    下一篇

酶催化合成聚酯的研究进展

朱晶莹, 安思源, 卢滇楠, 刘铮   

  1. 清华大学化学工程系,化学工程联合国家重点实验室,北京 100084
  • 收稿日期:2012-07-30 修回日期:2012-10-02 出版日期:2013-02-05 发布日期:2013-02-05
  • 通讯作者: 卢滇楠
  • 作者简介:朱晶莹(1987—),女,博士研究生。
  • 基金资助:

    中国石油科技创新基金项目(2010D-5006-0503)。

Development and prospects of enzymatic polymerization

ZHU Jingying, AN Siyuan, LU Diannan, LIU Zheng   

  1. State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  • Received:2012-07-30 Revised:2012-10-02 Online:2013-02-05 Published:2013-02-05
  • Supported by:

    supported by CNPC Innovation Foundation(2010D-5006-0503).

摘要: 酶催化反应具有条件温和、选择性高以及环境友好等特点,酶催化合成聚酯有望成为制备绿色和功能化聚酯材料的新途径。本文首先概述了目前酶催化合成不同类型聚酯的研究进展,重点介绍了酶催化合成聚酯的催化剂及其催化机理方面的研究成果,讨论了酶催化合成聚酯研究中的若干基础问题,如高效酶催化剂的设计与制备、反应过程的调控与强化等,最后展望了酶催化合成聚酯的发展前景。

关键词: 酶, 酶催化聚合, 聚酯

Abstract: The proven efficiency of enzyme catalysis, in terms of high stereo- and regio-selectivity, mildness and environmental friendliness, makes the enzymatic synthesis of polyester a promising route for functional polyester-based materials.This review begins by a survey of recent progress in the enzymatic synthesis of polyesters with emphasis on enzyme catalysts and catalytic process.Then the fundamentals for enzymatic synthesis are discussed with highlight on development of catalysts and intensification of synthesis process from the viewpoint of chemical engineering.The prospects for enzymatic synthesis polyesters are presented.

Key words: enzyme, enzymatic catalyzed polymerization, polyester

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