木质素/热塑性塑料复合材料界面增容的研究进展

doi:10.3969/j.issn.0438-1157.2014.03.002

化工学报 ›› 2014, Vol. 65 ›› Issue (3): 777-784.DOI: 10.3969/j.issn.0438-1157.2014.03.002

木质素/热塑性塑料复合材料界面增容的研究进展

陈福泉, 赵永青, 冯彦洪, 瞿金平

华南理工大学聚合物成型加工工程教育部重点实验室, 广东广州 510640

收稿日期:2013-06-27 修回日期:2013-07-30 出版日期:2014-03-05 发布日期:2014-03-05
通讯作者: 瞿金平
作者简介:陈福泉（1984—），男，博士研究生。
基金资助:
国家自然科学基金项目（10872071，51373058， 50903035，50973033）；国家自然科学基金-广东联合基金项目（U1201242）；国家重点基础研究发展计划项目（2012CB025902）；国家科技支撑计划课题（2011BAE15B02）；新世纪优秀人才支持计划项目（NCET-11-0152）；广州市珠江科技新星专项项目（2011J2200058）。

Progress of interfacial compatibilization methods of lignin/thermoplast composites

CHEN Fuquan, ZHAO Yongqing, FENG Yanhong, QU Jinping

Key Laboratory of Polymer Processing Engineering of Ministry of Education, South China University of Technology, Guangzhou 510640, Guangdong, China

Received:2013-06-27 Revised:2013-07-30 Online:2014-03-05 Published:2014-03-05
Supported by:
supported by the National Natural Science Foundation of China (10872071, 51373058, 50973035, 50903033), the National Natural Science Foundation of China-Guangdong Joint Foundation Project (U1201242), the National Basic Research Program of China (2012CB 025902), the New Century Excellent Talents in University (NCET-11-0152) and the Pearl River Talent Fund for Young Sci-Tech Researchers of Guangzhou City (2011J2200058).

摘要/Abstract

摘要： 将木质素作为一种有机颗粒填料添加到热塑性塑料中，可解决造纸黑液资源化利用、石油原料日渐紧张以及环境污染加剧等严峻问题。而木质素与热塑性塑料之间相容性直接影响木质素在塑料工业中的应用与发展。首先简要概述了木质素结构与性质和木质素/热塑性塑料复合材料的性能分析，然后系统地阐述国内外研究木质素/热塑性塑料复合材料界面增容方法及其原理；增容方法按添加相容剂、改性木质素和改性塑料进行归类，并对3种增容方法进行比较分析；接着综述了木质素复合材料中增容方法的交叉复合使用；最后对未来木质素/热塑性塑料复合材料界面增容的研究方向以及思路进行了展望。

关键词: 木质素, 热塑性塑料, 聚合物, 复合材料, 界面, 增容

Abstract: Lignin is mixed into thermoplast as organic particulate filler, which resolves the tough problems of resource utilization of black liquor from paper industry, growing tension of petroleum feedstock and increasing environmental pollution. The compatibility between lignin and thermoplast is directly related to application and development of lignin in the plastics industry. This paper begins with an overview of the structure and properties of lignin and performance analysis of lignin/thermoplastic composites, and then elaborates the methods and principles of interfacial compatibilization between lignin and thermoplast. The methods of compatibilization are divided into adding compatibilizer, modifying lignin and modifying thermoplastics, and the three methods are compared and analyzed. The methods of adding compatibilizer and modifying thermoplastics are more commonly used than the modifying lignin for interfacial compatibilizing of the composites. Esterified lignin has better compatibilization than alkylated lignin. Then alternate and compounded use of the compatibilizing methods for lignin-based composites are reviewed. Finally, future research directions and ideas of compatibilization in lignin/thermoplastic composites are discussed.

Key words: lignin, thermoplast, polymer, composite, interface, compatibilization

中图分类号:

TQ316.6⁺2

陈福泉, 赵永青, 冯彦洪, 瞿金平. 木质素/热塑性塑料复合材料界面增容的研究进展[J]. 化工学报, 2014, 65(3): 777-784.

CHEN Fuquan, ZHAO Yongqing, FENG Yanhong, QU Jinping. Progress of interfacial compatibilization methods of lignin/thermoplast composites[J]. CIESC Journal, 2014, 65(3): 777-784.

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木质素/热塑性塑料复合材料界面增容的研究进展

Progress of interfacial compatibilization methods of lignin/thermoplast composites

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