短程混凝-膜过滤工艺清洗过程中气液两相流对絮体形成的影响

doi:10.3969/j.issn.0438-1157.2014.04.012

化工学报 ›› 2014, Vol. 65 ›› Issue (4): 1236-1242.DOI: 10.3969/j.issn.0438-1157.2014.04.012

短程混凝-膜过滤工艺清洗过程中气液两相流对絮体形成的影响

王捷^1,2, 吴义², 耿全月³, 张宏伟^1,2, 李莉⁴

1 天津工业大学中空纤维膜材料与膜过程教育部重点实验室, 天津 300387;
2 天津工业大学环境与化学工程学院, 天津 300387;
3 河北省唐山市迁安市环境保护局, 河北唐山 064400;
4 天津膜天膜科技股份有限公司, 天津 300457

收稿日期:2013-07-08 修回日期:2013-12-07 出版日期:2014-04-05 发布日期:2014-04-05
通讯作者: 王捷（1979—），男，博士，副教授。
作者简介:王捷（1979—），男，博士，副教授。
基金资助:
国家自然科学基金项目（51108314，51378349）；长江学者和创新团队发展计划项目（IRT13084）；天津市科技兴海项目（KJXH2012-5）。

Influence of gas-liquid flow on flocs formation in cleaning procedure of integrated coagulation-membrane filtration process

WANG Jie^1,2, WU Yi², GENG Quanyue³, ZHANG Hongwei^1,2, LI Li ⁴

1 State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin Polytechnic University, Tianjin 300387, China;
2 School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China;
3 Qian'an Environmental Protection Bureau, Tangshan 064400, Hebei, China;
4 Tianjin MOTIMO Membrane Technology Co., Ltd., Tianjin 300457, China

Received:2013-07-08 Revised:2013-12-07 Online:2014-04-05 Published:2014-04-05
Supported by:
supported by the National Natural Science Foundation of China (51108314,51378349) and the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT) of Minstry of Education of China(IRT13084).

摘要/Abstract

摘要： 基于数值模拟的方法研究了不同填充密度和不同曝气强度下短程混凝-膜过滤工艺中膜清洗过程反应器内流场特性。结合絮凝动力学理论，引入微涡旋尺度参数来判定影响絮体形成的流场状态，以评估膜清洗过程中曝气强度对絮体形成及膜清洗效果的影响，并用实时图像技术对模拟结果进行验证。研究结果表明，反应器填充密度为7.38%，气水比为15：1时，反应器内平均有效能耗适中，且形成的微涡旋尺度也适中，不会对絮体产生明显的破坏作用，有利于形成较大尺寸的絮体；同时在膜组件附近产生较强的水流剪切速度，使膜面得到有效的清洗。结合实验分析，反应器填充密度为7.38%，气水比为15：1时，反应器内形成的絮体粒径较大且与数值模拟得到的微涡旋尺度相近，上清液UV₂₅₄和TOC值最低，去除效果最好。

关键词: 混凝-膜过滤, 混凝动力学, 气液两相流, 曝气, 数值模拟

Abstract: Based on numerical simulation, the flow field characteristics of integrated coagulation-membrane filtration process were investigated at different aeration intensities and module packing densities. According to the flocculation kinetics theory, the micro-vortex scale was introduced to analyze the flow field state. It was used to evaluate the effect of aeration intensity on flocs formation and membrane cleaning during the cleaning process. The simulation results were validated experimentally by the real-time imaging technology. When module packing density and air-water ratio were 7.38% and 15:1 respectively, mean effective energy consumption was moderate and vortex scale was sufficiently large. Moreover, under such conditions damage of flocs was not obvious, meaning that larger vortex was conducive to flocs formation. Meanwhile, a strong shear speed generated by the field near the membrane module was beneficial to membrane cleaning and hindered flocs breakage. Combining with experiment analysis, when module packing density and air-water ratio were 7.38% and 15:1 respectively, the size of flocs particle formed in the experiment was the largest, close to the micro eddy scale obtained from numerical simulation. The values of UV₂₅₄ and TOC were minimum and flocculation effect was the best.

Key words: coagulation-membrane filtration, flocculation kinetics, gas-liquid flow, aeration, numerical simulation

中图分类号:

王捷, 吴义, 耿全月, 张宏伟, 李莉. 短程混凝-膜过滤工艺清洗过程中气液两相流对絮体形成的影响[J]. 化工学报, 2014, 65(4): 1236-1242.

WANG Jie, WU Yi, GENG Quanyue, ZHANG Hongwei, LI Li . Influence of gas-liquid flow on flocs formation in cleaning procedure of integrated coagulation-membrane filtration process[J]. CIESC Journal, 2014, 65(4): 1236-1242.

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短程混凝-膜过滤工艺清洗过程中气液两相流对絮体形成的影响

Influence of gas-liquid flow on flocs formation in cleaning procedure of integrated coagulation-membrane filtration process

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