热解温度及AAEM元素对生物质快速热解焦油的影响

doi:10.11949/j.issn.0438-1157.20151907

化工学报 ›› 2016, Vol. 67 ›› Issue (6): 2558-2567.DOI: 10.11949/j.issn.0438-1157.20151907

热解温度及AAEM元素对生物质快速热解焦油的影响

冯冬冬, 赵义军, 唐文博, 张宇, 钱娟, 孙绍增

哈尔滨工业大学能源科学与工程学院, 黑龙江哈尔滨 150001

收稿日期:2015-12-15 修回日期:2016-02-18 出版日期:2016-06-05 发布日期:2016-06-05
通讯作者: 赵义军
基金资助:
国家自然科学基金项目(51206037);中国博士后基金项目(2013M541376)。

Effect of temperature and AAEM species on fast pyrolysis of biomass tar

FENG Dongdong, ZHAO Yijun, TANG Wenbo, ZHANG Yu, QIAN Juan, SUN Shaozeng

School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China

Received:2015-12-15 Revised:2016-02-18 Online:2016-06-05 Published:2016-06-05
Supported by:
supported by the National Natural Science Foundation of China (51206037) and the Postdoctoral Fund in China (2013M541376).

摘要/Abstract

摘要：

生物质热解受热解温度、热解速率和碱金属及碱土金属(AAEM)元素影响显著。利用热裂解气相色谱质谱联用法(Py-GC/MS)针对热解温度及AAEM元素对生物质快速热解焦油的影响展开深入研究,通过样品热解前后的失重情况分析了热解温度及AAEM元素对生物质(稻壳和木屑、酸洗稻壳和酸洗木屑)热解特性的影响规律,利用气相色谱质谱仪(GC/MS)对热解焦油组分及含量进行了在线半定量分析,并对热解焦油组分分子量分布情况展开了讨论。结果表明生物质Py-GC/MS快速热解实验,酸洗脱除AAEM元素致使热解失重率减小。500~900℃范围内随温度的升高,大分子焦油成分逐渐减少,逐渐转化为轻质组分。AAEM元素限制了焦油前体的聚合,进一步抑制了含氧杂环类碳环(糠醛等)的生成。稻壳的热解焦油的相对分子质量主要分布在110~129。木屑快速热解焦油产率明显高于稻壳,且热解焦油中分子量分布广泛,含有更多较大分子量(150~209)的化合物成分。

关键词: 生物质, 快速热解, AAEM, Py-GC/MS, 焦油

Abstract:

Pyrolysis temperature, heating rate, alkali metal and alkaline earth metal (AAEM) species have significant effects on biomass pyrolysis. In this paper, by using the pyrolysis gas chromatography mass spectrometry (Py-GC/MS), the effect of temperature and AAEM species on fast pyrolysis of the biomass tar was investigated. The influence of pyrolysis temperature and AAEM species on the pyrolysis characteristics of biomass (rice husk and sawdust, H-form rice husk and H-form sawdust) was analyzed by means of mass loss of samples. The online semi quantitative analysis of pyrolysis tar was carried out by gas chromatography mass spectrometry (GC/MS). The distribution of molecular weight of pyrolysis tar was discussed. The results showed that during fast pyrolysis of biomass, the removal of AAEM species reduced the mass loss rate. With increasing pyrolysis temperature in the range of 500-900℃, the tar composition of high molecular weight decreased gradually. The polymerization of the tar precursor was limited by the AAEM species and the formation of the heterocyclic carbon ring was further inhibited. The molecular weight of tar of rice husk pyrolysis was mainly distributed in the range of 110-129. The tar yield of sawdust fast pyrolysis was higher than that of rice husk. The molecular weight distribution of sawdust tar was wide, containing more substances with high molecular weight (150-209).

Key words: biomass, fast pyrolysis, AAEM, Py-GC/MS, tar

中图分类号:

X382.1

冯冬冬, 赵义军, 唐文博, 张宇, 钱娟, 孙绍增. 热解温度及AAEM元素对生物质快速热解焦油的影响[J]. 化工学报, 2016, 67(6): 2558-2567.

FENG Dongdong, ZHAO Yijun, TANG Wenbo, ZHANG Yu, QIAN Juan, SUN Shaozeng. Effect of temperature and AAEM species on fast pyrolysis of biomass tar[J]. CIESC Journal, 2016, 67(6): 2558-2567.

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热解温度及AAEM元素对生物质快速热解焦油的影响

Effect of temperature and AAEM species on fast pyrolysis of biomass tar

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