生物质化学链转化技术研究进展

doi:10.11949/0438-1157.20190309

摘要/Abstract

摘要：

生物质通过化学链转化制备燃料及化工原料是工程热化学领域发展的重要方向，如何有效借助化学链转化实现生物质能源的高效清洁利用是工业界和学术界关注的热点。本文回顾了生物质化学链燃烧、气化、氧解耦、重整/制氢研究进展，重点综述了载氧体在生物质化学链转化过程中的理化特性变化规律及热力学与动力学特性，对比分析了反应装置及系统的特性。基于生物质主要组分的化学特性探究预处理及灰成分对化学链转化的影响机制，充分考虑电子及氧离子传输特性的载氧体理性设计及精准构筑，在时间尺度和空间尺度上的反应器与反应本征特征匹配特性，生物质化学链转化与其他工程热化学技术耦合的多联产系统是后续研究需要关注的几个方面。

关键词: 生物质, 二氧化碳捕集, 化学链转化, 载氧体, 反应器, 过程系统

Abstract:

Preparation of fuels and chemical materials through biomass chemical looping is an important direction in the field of engineering thermochemistry. How to effectively use chemical conversion to achieve efficient and clean utilization of biomass energy is a hot spot in industry and academia. This paper reviews the research progress from the aspects of chemical-looping combustion(CLC), chemical-looping gasification(CLG), chemical looping with oxygen uncoupling(CLOU), chemical-looping reforming (CLR), and chemical-looping hydrogen generation (CLHG), and focuses on the changes of physicochemical properties of oxygen carriers in the of biomass chemical looping conversion process (BCLP). The characteristics of reaction devices and systems were compared and analyzed. Based on the chemical characteristics of the main components of biomass, the influence mechanism of pretreatment and ash composition on the chemical looping conversion process should be investigated. The rational design and accurate construction of oxygen carrier based on electron and oxygen ion transport characteristics should be fully considered. The matching of reactor and intrinsic characteristics of the reaction on time scale and spatial scale, polygeneration system coupled with biomass chemical looping conversion technology and other engineering thermochemical technologies are several aspects that need to be addressed in further research.

Key words: biomass, CO₂ capture, chemical looping conversion, oxygen carrier, reactors, process systems

中图分类号:

TQ 519

吴志强, 张博, 杨伯伦. 生物质化学链转化技术研究进展[J]. 化工学报, 2019, 70(8): 2835-2853.

Zhiqiang WU, Bo ZHANG, Bolun YANG. Research progress on biomass chemical-looping conversion technology[J]. CIESC Journal, 2019, 70(8): 2835-2853.

图/表 32

参考文献 114

1	史晓斐, 杨思宇, 钱宇 . 化学链技术在煤炭清洁高效利用中的研究进展[J]. 化工学报, 2018, 69(12): 4931-4946.
	Shi X F , Yang S Y , Qian Y . Chemical looping technology for clean and highly efficient coal processes[J]. CIESC Journal, 2018, 69(12): 4931-4946.
2	刘永卓, 郭庆杰, 田红景 . 煤化学链转化技术研究进展[J].化工进展, 2014, 33(6): 1357-1364.
	Liu Y Z , Guo Q J , Tian H J . Advance in the coal chemical-looping conversion technology[J]. Chemical Industry and Engineering Progress, 2014, 33(6): 1357-1364.
3	Niu P J , Ma Y X , Tian X , et al . Chemical looping gasification of biomass(Ⅰ): Screening Cu-Fe metal oxides as oxygen carrier and optimizing experimental conditions[J]. Biomass and Bioenergy, 2018, 108: 146-156.
4	Fan J M , Hong H , Zhu L , et al . Thermodynamic and environmental evaluation of biomass and coal co-fuelled gasification chemical looping combustion with CO₂ capture for combined cooling, heating and power production[J]. Applied Energy, 2017, 195: 861-876.
5	Huang Z , Deng Z B , Chen D Z , et al . Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier[J]. Energy, 2017, 141(Supplement C): 1836-1844.
6	Mehrpooya M , Sharifzadeh M M M , Rajabi M , et al . Design of an integrated process for simultaneous chemical looping hydrogen production and electricity generation with CO₂ capture[J]. International Journal of Hydrogen Energy, 2017, 42(12): 8486-8496.
7	Adánez-Rubio I , Pérez-Astray A , Mendiara T , et al . Chemical looping combustion of biomass: CLOU experiments with a Cu-Mn mixed oxide[J]. Fuel Processing Technology, 2018, 172: 179-186.
8	Zhao X , Zhou H , Sikarwar V S , et al . Biomass-based chemical looping technologies: the good, the bad and the future[J]. Energy & Environmental Science, 2017, 10(9): 1885-1910.
9	曾亮, 巩金龙 . 化学链重整直接制氢技术进展[J]. 化工学报, 2015, 66(8): 2854-2862.
	Zeng L , Gong J L . Advances in chemical looping reforming for direct hydrogen production[J]. CIESC Journal, 2015, 66(8): 2854-2862.
10	Skulimowska A , Di Felice L , Kaminska-Pietrzak N , et al . Chemical looping with oxygen uncoupling (CLOU) and chemical looping combustion (CLC) using copper-enriched oxygen carriers supported on fly ash[J]. Fuel Processing Technology, 2017, 168: 123-130.
11	Aghaie M , Mehrpooya M , Pourfayaz F . Introducing an integrated chemical looping hydrogen production, inherent carbon capture and solid oxide fuel cell biomass fueled power plant process configuration[J]. Energy Conversion and Management, 2016, 124: 141-154.
12	罗明, 王树众, 王龙飞, 等 . 基于化学链技术制氢的研究进展[J]. 化工进展, 2014, 33(5): 1123-1133.
	Luo M , Wang S Z , Wang L F , et al . Advances in hydrogen production using chemical-looping technology[J]. Chemical Industry and Engineering Progress, 2014, 33(5): 1123-1133.
13	许迪恺, Tong Andrew , 曾亮, 等 . 铁基移动床化学链技术进展[J]. 化工学报, 2014, 65(7): 2410-2416.
	Xu D K , Tong A , Zeng L , et al . Development on iron-based moving bed chemical looping process[J]. CIESC Journal, 2014, 65(7): 2410-2416.
14	刘帅, 黄振, 何方, 等 . NiFe₂O₄为载氧体的生物质半焦化学链燃烧热力学模拟研究[J]. 新能源进展, 2016, 4(3): 172-178.
	Liu S , Huang Z , He F , et al . Thermodynamic analysis of biomass char chemical looping combustion with NiFe₂O₄ as oxygen carrier[J]. Advances in New and Renewable Energy, 2016, 4(3): 172-178.
15	肖申, 沈来宏, 牛欣, 等 . 含氮模型化合物用于化学链燃烧的氮氧化物释放特性[J]. 化工学报, 2015, 66(11): 4588-4596.
	Xiao S , Shen L H , Niu X , et al . NO _x release in chemical looping combustion of N-containing model compounds[J]. CIESC Journal, 2015, 66(11): 4588-4596.
16	郝建刚, 吴家桦, 王雷, 等 . 基于Fe基载氧体的生物质化学链燃烧试验研究[J]. 锅炉技术, 2010, 41(2): 65-70.
	Hao J G , Wu J H , Wang L , et al . Experiments on chemical looping combustion of biomass with a Fe₂O₃ based oxygen carrier[J]. Boiler Technology, 2010, 41(2): 65-70.
17	Sarvaramini A , Larachi F . Integrated biomass torrefaction — chemical looping combustion as a method to recover torrefaction volatiles energy[J]. Fuel, 2014, 116: 158-167.
18	Huang H B , Aisyah L , Ashman P J , et al . Chemical looping combustion of biomass-derived syngas using ceria-supported oxygen carriers[J]. Bioresource Technology, 2013, 140: 385-391.
19	魏国强, 何方, 黄振, 等 . 化学链燃烧技术的研究进展[J]. 化工进展, 2012, 31(4): 713-725.
	Wei G Q , He F , Huang Z , et al . Research development in chemical-looping combustion[J]. Chemical Industry and Engineering Progress, 2012, 31(4): 713-725.
20	王国贤, 王树众, 罗明 . 固体燃料化学链燃烧技术的研究进展[J]. 化工进展, 2010, 29(8): 1443-1450.
	Wang G X , Wang S Z , Luo M . Research advances in chemical-looping combustion for solid fuels[J]. Chemical Industry and Engineering Progress, 2010, 29(8): 1443-1450.
21	吴家桦, 沈来宏, 肖军, 等 . 10 kW_th级串行流化床中木屑化学链燃烧试验[J].化工学报, 2009, 60(8): 2080-2088.
	Wu J H , Shen L H , Xiao J , et al . Chemical looping combustion of sawdust in a 10 kW_th interconnected fluidized bed[J]. CIESC Journal, 2009, 60(8): 2080-2088.
22	Mendiara T , Pérez-Astray A , Izquierdo M T , et al . Chemical looping combustion of different types of biomass in a 0.5 kW_th unit[J]. Fuel, 2018, 211: 868-875.
23	Mendiara T , Adanez-Rubio I , Gayan P , et al . Process comparison for biomass combustion: in situ gasification-chemical looping combustion (iG-CLC) versus chemical looping with oxygen uncoupling (CLOU)[J]. Energy Technology, 2016, 4(10): 1130-1136.
24	高正平, 黄启龙, 顾海明, 等 . 基于草木灰修饰铁矿石的串行流化床化学链燃烧[J]. 热科学与技术, 2016, 15(5): 397-405.
	Gao Z P , Huang Q L , Gu H M , et al . Experimental investigation of chemical looping combustion in interconnected fluidized bed reactor using iron ore oxygen carrier modified by plant ash[J]. Journal of Thermal Science and Technology, 2016, 15(5): 397-405.
25	Wang X , Chen Z H , Hu M , et al . Chemical looping combustion of biomass using metal ferrites as oxygen carriers[J]. Chemical Engineering Journal, 2017, 312: 252-262.
26	Huang Z , He F , Feng Y P , et al . Biomass char direct chemical looping gasification using NiO-modified iron ore as an oxygen carrier[J]. Energy & Fuels, 2014, 28(1): 183-191.
27	Chen J , Zhao K , Zhao Z L , et al . Reaction schemes of barium ferrite in biomass chemical looping gasification for hydrogen-enriched syngas generation via an outer-inner looping redox reaction mechanism[J]. Energy Conversion and Management, 2019, 189: 81-90.
28	王旭锋, 刘晶, 刘丰, 等 . 基于CoFe₂O₄载氧体的生物质化学链气化反应特性[J]. 化工学报, 2019, 70(4): 1583-1590.
	Wang X F , Liu J , Liu F , et al . Characteristics of biomass chemical looping gasification with CoFe₂O₄ as oxygen carrier[J]. CIESC Journal, 2019, 70(4): 1583-1590.
29	Tian X , Niu P J , Ma Y X , et al . Chemical-looping gasification of biomass(Ⅱ): Tar yields and distributions[J]. Biomass and Bioenergy, 2018,108(Supplement C): 178-189.
30	Aghabararnejad M , Patience G S , Chaouki J . Techno-economic comparison of a 7 MW_th biomass chemical looping gasification unit with conventional systems[J]. Chemical Engineering & Technology, 2015, 38(5): 867-878.
31	郭万军, 葛晖骏, 沈来宏, 等 . 基于铁矿石载氧体25 kW_th串行流化床生物质化学链气化实验研究[J]. 热科学与技术, 2017, 16(1): 78-86.
	Guo W J , Ge H J , Shen L H , et al . Experimental study on chemical looping gasification of biomass with hematite base on 25 kW_th fluidized beds[J]. Journal of Thermal Science and Technology, 2017, 16(1): 78-86.
32	Zeng J M , Xiao R , Zhang H Y , et al . Chemical looping pyrolysis-gasification of biomass for high H₂/CO syngas production[J]. Fuel Processing Technology, 2017, 168: 116-122.
33	Zeng J M , Xiao R , Zhang H Y , et al . Syngas production via biomass self-moisture chemical looping gasification[J]. Biomass & Bioenergy, 2017, 104: 1-7.
34	曾骥敏, 肖睿, 衡丽君, 等 . 生物质化学链气化制备高H₂/CO物质的量比的合成气[J]. 燃烧科学与技术, 2016, 22(3): 229-235.
	Zeng J M , Xiao R , Heng L J , et al . Chemical looping gasification of biomass for high H₂/CO-ratio syngas[J]. Journal of Combustion Science and Technology, 2016, 22(3): 229-235.
35	张云鹏, 刘永卓, 杨勤勤, 等 . 废弃咖啡渣化学链气化反应特性[J]. 化工学报, 2016, 67(4): 1303-1312.
	Zhang Y P , Liu Y Z , Yang Q Q , et al . Reaction characteristics of chemical-looping gasification for waste coffee grounds[J]. CIESC Journal, 2016, 67(4): 1303-1312.
36	王博, 刘永卓, 王东营, 等 . 废弃活性炭化学链气化制富氢合成气[J].化工学报, 2017, 68(9): 3541-3550.
	Wang B , Liu Y Z , Wang D Y , et al . Chemical looping gasification of waste activated carbon for hydrogen-enriched syngas production[J]. CIESC Journal, 2017, 68(9): 3541-3550.
37	郭万军, 张海峰, 葛晖骏, 等 . 基于铁矿石载氧体的生物质化学链气化机理研究[J]. 热科学与技术, 2016, 15(3): 249-258.
	Guo W J , Zhang H F , Ge H J , et al . Mechanism study of biomass chemical looping gasification based on iron ores oxygen carrier[J]. Journal of Thermal Science and Technology, 2016, 15(3): 249-258.
38	肖申, 沈来宏, 肖军, 等 . 基于赤铁矿的生物质化学链燃烧过程中氮氧化物的释放特性[J].燃料化学学报, 2015, 43(4): 490-498.
	Xiao S , Shen L H , Xiao J , et al . NO _x release in chemical looping combustion of biomass based on hematite[J]. Journal of Fuel Chemistry and Technology, 2015, 43(4): 490-498.
39	葛晖骏, 郭万军, 沈来宏, 等 . 铁矿石载氧体生物质化学链气化实验研究[J]. 工程热物理学报, 2015, 36(6): 1371-1375.
	Ge H J , Guo W J , Shen L H , et al . Experiments on chemical looping gasification of biomass with natural hematite as oxygen carrier[J]. Journal of Engineering Thermophysics, 2015, 36(6): 1371-1375.
40	黄振, 何方, 李新爱, 等 . Fe₂O₃-水蒸气生物质化学链共气化制合成气[J]. 太阳能学报, 2013, 34(12): 2056-2062.
	Huang Z , He F , Li X A , et al . Syngas generated by chemical-looping gasification of biomass using Fe₂O₃ as oxygen carriers in presence of steam[J]. Acta Energiae Solaris Sinica, 2013, 34(12): 2056-2062.
41	黄振, 何方, 李海滨, 等 . 天然铁矿石为氧载体的生物质化学链气化制合成气实验研究[J]. 燃料化学学报, 2012, 40(3): 300-308.
	Huang Z , He F , Li H B , et al . Synthesis gas generation by chemical-looping gasification of biomass using natural hematite as oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 300-308.
42	郭磊, 赵海波, 杨伟进, 等 . 基于铜基氧载体的生物质化学链氧解耦[J]. 燃烧科学与技术, 2014, 20(6): 523-528.
	Guo L , Zhao H B , Yang W J , et al . Biomass direct chemical looping with oxygen uncoupling using Cu-based oxygen carrier[J]. Journal of Combustion Science and Technology, 2014, 20(6): 523-528.
43	Zeng D W , Xiao R , Zhang S , et al . Bio-oil heavy fraction for hydrogen production by iron-based oxygen carrier redox cycle[J]. Fuel Processing Technology, 2015, 139: 1-7.
44	Xiao R , Zhang S , Peng S H , et al . Use of heavy fraction of bio-oil as fuel for hydrogen production in iron-based chemical looping process[J]. International Journal of Hydrogen Energy, 2014, 39(35): 19955-19969.
45	Mendiara T , Abad A , de Diego L F , et al . Biomass combustion in a CLC system using an iron ore as an oxygen carrier[J]. International Journal of Greenhouse Gas Control, 2013, 19: 322-330.
46	Shen L H , Wu J H , Xiao J , et al . Chemical-looping combustion of biomass in a 10 kW_th reactor with iron oxide as an oxygen carrier[J]. Energy & Fuels, 2009, 23(5): 2498-2505.
47	Wei G Q , He F , Zhao Z L , et al . Performance of Fe-Ni bimetallic oxygen carriers for chemical looping gasification of biomass in a 10 kW_th interconnected circulating fluidized bed reactor[J]. International Journal of Hydrogen Energy, 2015, 40(46): 16021-16032.
48	Liu G C , Liao Y F , Wu Y T , et al . Characteristics of microalgae gasification through chemical looping in the presence of steam[J]. International Journal of Hydrogen Energy, 2017, 42(36): 22730-22742.
49	Huang Z , He F , Zhu H Q , et al . Thermodynamic analysis and thermogravimetric investigation on chemical looping gasification of biomass char under different atmospheres with Fe₂O₃ oxygen carrier[J]. Applied Energy, 2015, 157: 546-553.
50	Niu X , Shen L H , Gu H M , et al . Sewage sludge combustion in a CLC process using nickel-based oxygen carrier[J]. Chemical Engineering Journal, 2015, 260: 631-641.
51	Ge H J , Shen LH , Feng F , et al . Experiments on biomass gasification using chemical looping with nickel-based oxygen carrier in a 25 kW_th reactor[J]. Applied Thermal Engineering, 2015, 85: 52-60.
52	Lea-Langton A , Zin R M , Dupont V , et al . Biomass pyrolysis oils for hydrogen production using chemical looping reforming[J]. International Journal of Hydrogen Energy, 2012, 37(2): 2037-2043.
53	Zhao H B , Guo L , Zou X X . Chemical-looping auto-thermal reforming of biomass using Cu-based oxygen carrier[J]. Applied Energy, 2015, 157: 408-415.
54	Wang K , Yu Q B , Qin Q , et al . Thermodynamic analysis of syngas generation from biomass using chemical looping gasification method[J]. International Journal of Hydrogen Energy, 2016, 41(24): 10346-10353.
55	魏国强, 何方, 赵增立, 等 . 基于层状氢氧化物衍生复合氧载体的生物质化学链气化实验研究[J]. 燃料化学学报, 2016, 44(3): 349-356.
	Wei G Q , He F , Zhao Z L , et al . Chemical looping gasification of biomass based on the oxygen carrier derived from the layered double hydroxide (LDH) precursor[J]. Journal of Fuel Chemistry and Technology, 2016, 44(3): 349-356.
56	Adanez-Rubio I , Abad A , Gayan P , et al . Biomass combustion with CO₂ capture by chemical looping with oxygen uncoupling (CLOU)[J]. Fuel Processing Technology, 2014, 124: 104-114.
57	Siriwardane R , Riley J , Tian H J , et al . Chemical looping coal gasification with calcium ferrite and barium ferrite via solid-solid reactions[J]. Applied Energy, 2016, 165: 952-966.
58	Chen J , Zhao K , Zhao Z L , et al . Identifying the roles of MFe₂O₄ (M= Cu, Ba, Ni, and Co) in the chemical looping reforming of char, pyrolysis gas and tar resulting from biomass pyrolysis[J]. International Journal of Hydrogen Energy, 2019, 44(10): 4674-4687.
59	Wei G Q , He F , Zhao W N , et al . Experimental investigation of Fe-Ni-Al oxygen carrier derived from hydrotalcite-like precursors for the chemical looping gasification of biomass char[J]. Energy & Fuels, 2017, 31(5): 5174-5182.
60	Huang Z , Deng Z B , He F , et al . Reactivity investigation on chemical looping gasification of biomass char using nickel ferrite oxygen carrier[J]. International Journal of Hydrogen Energy, 2017, 42(21): 14458-14470.
61	Niu X , Shen L H , Jiang S X , et al . Combustion performance of sewage sludge in chemical looping combustion with bimetallic Cu-Fe oxygen carrier[J]. Chemical Engineering Journal, 2016, 294: 185-192.
62	Huang Z , He F , Feng Y P , et al . Synthesis gas production through biomass direct chemical looping conversion with natural hematite as an oxygen carrier[J]. Bioresource Technology, 2013, 140: 138-145.
63	Linderholm C , Schmitz M , Biermann M , et al . Chemical-looping combustion of solid fuel in a 100 kW unit using sintered manganese ore as oxygen carrier[J]. International Journal of Greenhouse Gas Control, 2017, 65: 170-181.
64	Guo L , Zhao H B , Zheng C G . Synthesis gas generation by chemical-looping reforming of biomass with natural copper ore as oxygen carrier[J]. Waste and Biomass Valorization, 2015, 6(1): 81-89.
65	Schmitz M , Linderholm C , Hallberg P , et al . Chemical-looping combustion of solid fuels using manganese ores as oxygen carriers[J]. Energy & Fuels, 2016, 30(2): 1204-1216.
66	Hanning M , Corcoran A , Lind F , et al . Biomass ash interactions with a manganese ore used as oxygen-carrying bed material in a 12 MW_th CFB boiler[J]. Biomass & Bioenergy, 2018, 119: 179-190.
67	Wei L G , Xu S P , Liu J G , et al . Hydrogen production in steam gasification of biomass with CaO as a CO₂ absorbent[J]. Energy & Fuels, 2008, 22(3): 1997-2004.
68	Udomsirichakorn J , Basu P , Salam P A , et al . CaO-based chemical looping gasification of biomass for hydrogen-enriched gas production with in situ CO₂ capture and tar reduction[J]. Fuel Processing Technology, 2014, 127: 7-12.
69	Moghtaderi B , Zanganeh J , Shah K , et al . Application of concrete and demolition waste as CO₂ sorbent in chemical looping gasification of biomass[J]. Energy & Fuels, 2012, 26(4): 2046-2057.
70	Pimenidou P , Rickett G , Dupont V , et al . High purity H₂ by sorption-enhanced chemical looping reforming of waste cooking oil in a packed bed reactor[J]. Bioresource Technology, 2010, 101(23): 9279-9286.
71	Linderholm C , Schmitz M . Chemical-looping combustion of solid fuels in a 100 kW dual circulating fluidized bed system using iron ore as oxygen carrier[J]. Journal of Environmental Chemical Engineering, 2016, 4(1): 1029-1039.
72	王杰, 王文举, 朱曙光, 等 . 化学链燃烧技术中载氧体的研究进展[J]. 现代化工, 2012, 32(11): 13-17.
	Wang J , Wang W J , Zhu S G , et al . Development of oxygen carriers in chemical-looping combustion technology[J]. Modern Chemical Industry, 2012, 32(11): 13-17.
73	Wang X , Xu T T , Jin X Y , et al . CuO supported on olivine as an oxygen carrier in chemical looping processes with pine sawdust used as fuel[J]. Chemical Engineering Journal, 2017, 330: 480-490.
74	赵坤, 何方, 黄振, 等 . 三维有序大孔Fe₂O₃为载氧体的生物质热解气化实验研究[J]. 燃料化学学报, 2013, 41(3): 277-284.
	Zhao K , He F , Huang Z , et al . Biomass pyrolysis /gasification using three dimensional ordered macroporous (3DOM) Fe₂O₃ as an oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2013, 41(3): 277-284.
75	吴宪爽, 何方, 魏国强, 等 . 生物炭模板构筑Fe-Ni复合载氧体及其化学链制氢反应性能研究[J]. 燃料化学学报, 2018, 46(4): 500-512.
	Wu X S , He F , Wei G Q , et al . Performance evaluation of Fe-Ni compound oxygen carriers derived from biochar template for chemical looping hydrogen generation[J]. Journal of Fuel Chemistry and Technology, 2018, 46(4): 500-512.
76	Huseyin S , Wei G Q , Li H B , et al . Chemical-looping gasification of biomass in a 10 kW_th interconnected fluidized bed reactor using Fe₂O₃/Al₂O₃ oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2014, 42(8): 922-931.
77	Wei G Q , He F , Huang Z , et al . Continuous operation of a 10 kW_th chemical looping integrated fluidized bed reactor for gasifying biomass using an iron-based oxygen carrier[J]. Energy & Fuels, 2015, 29(1): 233-241.
78	Huang Z , Zhang Y , Fu J J , et al . Chemical looping gasification of biomass char using iron ore as an oxygen carrier[J]. International Journal of Hydrogen Energy, 2016, 41(40): 17871-17883.
79	Gu H M , Shen L H , Zhong Z P , et al . Interaction between biomass ash and iron ore oxygen carrier during chemical looping combustion[J]. Chemical Engineering Journal, 2015, 277: 70-78.
80	黄振, 何方, 赵坤, 等 . 赤铁矿用于生物质化学链气化氧载体的反应性能[J].农业工程学报, 2011, 27(S1): 105-111.
	Huang Z , He F , Zhao K , et al . Reaction properties of hematite for biomass chemical looping gasification[J]. Transactions of the CSAE, 2011, 27(S1): 105-111.
81	Lancee R J , Dugulan A I , Thune P C , et al . Chemical looping capabilities of olivine, used as a catalyst in indirect biomass gasification[J]. Applied Catalysis B-Environmental, 2014, 145(SI): 216-222.
82	梁志永, 王建业, 覃吴, 等 . Fe₂O₃(1 -1 2)作用下CO化学链燃烧反应机理研究[J].环境科学学报, 2017, 37(5): 1826-1834.
	Liang Z Y , Wang J Y , Qin W , et al . Theoretical analysis of the CO reaction mechanism on Fe₂O₃ (1 -1 2) surface during chemical looping combustion[J]. Acta Science Circumstantiae, 2017, 37(5): 1826-1834
83	黄振, 刘帅, 李德波, 等 . 基于Fe₂O₃载氧体的生物质化学链气化热力学模拟研究[J].太阳能学报, 2017, 38(5): 1421-1430.
	Huang Z , Liu S , Li D B , et al . Thermodynamic investigation on biomass chemical looping gasification with Fe₂O₃ oxygen carrier[J]. Acta Energiae Solaris Sinica, 2017, 38(5): 1421-1430.
84	冉景煜, 禹建功, 秦昌雷, 等 . 钙基载氧体松木半焦反应动力学研究[J].工程热物理学报, 2016, 37(3): 680-683.
	Ran J Y , Yu J G , Qin C L , et al . Study on dynamics analysis of pine char using CaSO₄ as oxygen carrier[J]. Journal of Engineering Thermophysics, 2016, 37(3): 680-683.
85	赵坤, 何方, 黄振, 等 . 基于热重-红外联用分析的生物质化学链气化实验研究[J]. 太阳能学报, 2013, 34(3): 357-364.
	Zhao K , He F , Huang Z , et al . Study of biomass chemical-looping gasification by TG-FTIR[J]. Acta Energiae Solaris Sinica, 2013, 34(3): 357-364.
86	Hu Z F , Ma X Q , Jiang E C . The effect of microwave pretreatment on chemical looping gasification of microalgae for syngas production[J]. Energy Conversion and Management, 2017, 143: 513-521.
87	Zhang S , Xiao R . Performance of iron ore oxygen carrier modified by biomass ashes in coal-fueled chemical looping combustion[J]. Greenhouse Gases-Science and Technology, 2016, 6(5): 695-709.
88	Li F X , Sun Z C , Luo S W , et al . Ionic diffusion in the oxidation of iron-effect of support and its implications to chemical looping applications[J]. Energy & Environmental Science, 2011, 4(3): 876-880.
89	廖艳芬, 张横锦, 吴宇婷, 等 . 碱金属对生物质化学链气化过程的影响[J]. 华南理工大学学报(自然科学版), 2018, 46(4): 67-74.
	Liao Y F , Zhang H J , Wu Y T , et al . Investigation of the influence of potassium on biomass chemical looping gasification[J]. Journal of South China University of Technology (Nature Science Edition), 2018, 46(4): 67-74.
90	Liu S , Xiang D , Xu Y , et al . Relationship between electronic properties of Fe₃O₄ substituted by Ca and Ba and their reactivity in chemical looping process: a first-principles study[J]. Applied Energy, 2017, 202: 550-557.
91	陈秋銮 . 密度泛函研究Fe₂O₃与载体协同作用于化学链燃烧系统[D]. 北京: 华北电力大学, 2013.
	Chen Q L . Density function study of Fe₂O₃ synergy with inser in chemical-looping combustion system[D]. Beijing: North China Electric Power University, 2013.
92	桂进发, 张永亮, 赵海波 . CuO与负载间相互作用的密度泛函理论[J]. 燃烧科学与技术, 2017, 23(2): 173-179.
	Gui J F , Zhang Y L , Zhao H B . Density functional theory calculation for CuO-support interactionism Cu-based oxygen carriers[J]. Journal of Combustion Science and Technology, 2017, 23(2): 173-179.
93	郭磊 . 基于铜基氧载体的生物质化学链利用研究[D]. 武汉: 华中科技大学, 2015.
	Guo L . Chemical-looping utilization of biomass with copper-based oxygen carrier[D]. Wuhan: Huazhong University of Science and Technology, 2015.
94	冉景煜, 禹建功, 秦昌雷, 等 . 基于钙基载氧体的核桃壳半焦化学链气化研究[J].太阳能学报, 2016, 37(7): 1643-1649.
	Ran J Y , Yu J G , Qin C L , et al . Study on walnut shell char chemical-looping gasification using CaSO₄ as oxygen carrier[J]. Acta Energiae Solaris Sinica, 2016, 37(7): 1643-1649.
95	冉景煜, 张松, 秦昌雷, 等 . 生物质半焦/铜基载氧体气化反应特性研究[J]. 燃料化学学报, 2014, 42(11): 1316-1323.
	Ran J Y , Zhang S , Qin C L , et al . Gasification reactivity of biomass char with oxygen carrier CuO[J]. Journal of Fuel Chemistry and Technology, 2014, 42(11): 1316-1323.
96	Hsieh T L , Zhang Y T , Xu D K , et al . Chemical looping gasification for producing high purity, H₂ rich syngas in a cocurrent moving bed reducer with coal and methane cofeeds[J]. Industrial & Engineering Chemistry Research, 2018, 57(7): 2461-2475.
97	Luo S , Majumder A , Chung E , et al . Conversion of woody biomass materials by chemical looping process-kinetics, light tar cracking, and moving bed reactor behavior[J]. Industrial & Engineering Chemistry Research, 2013, 52(39): 14116-14124.
98	Boot-Handford M E , Florin N , Fennell P S . Investigations into the effects of volatile biomass tar on the performance of Fe-based CLC oxygen carrier materials[J]. Environmental Research Letters, 2016, 11(11) : 115001.
99	Yan J C , Shen L H , Jiang S X , et al . Combustion performance of sewage sludge in a novel CLC system with a two-stage fuel reactor[J]. Energy & Fuels, 2017, 31(11): 12570-12581.
100	魏国强, 何方, Sozen H , 等 . 生物质气化串行流化床反应器设计及冷态模拟实验研究[J].天然气化工(C1化学与化工), 2013, 38(4): 34-41.
	Wei G Q , He F , Sozen H , et al . Design and experimental investigation of a cold model for an interconnected fluidized bed reactor for biomass gasification[J]. Natural Gas Chemical Industry, 2013, 38(4): 34-41.
101	魏国强, 何方, Sozen H , 等 . 生物质化学链气化串行流化床二元物系冷态实验研究[J]. 新能源进展, 2014, 2(1): 18-24.
	Wei G Q , He F , Sozen H , et al . Flow characteristic of binary mixtures on a cold model of interconnected fluidized beds for chemical looping gasification[J]. Advances in New and Renewable Energy, 2014, 2(1): 18-24.
102	Ge H J , Guo W J , Shen L H , et al . Experimental investigation on biomass gasification using chemical looping in a batch reactor and a continuous dual reactor[J]. Chemical Engineering Journal, 2016, 286: 689-700.
103	Niu X , Shen L H , Gu H M , et al . Characteristics of hematite and fly ash during chemical looping combustion of sewage sludge[J]. Chemical Engineering Journal, 2015, 268: 236-244.
104	Jiang S X , Shen L H , Niu X , et al . Chemical looping co-combustion of sewage sludge and Zhundong coal with natural hematite as the oxygen carrier[J]. Energy & Fuels, 2016, 30(3): 1720-1729.
105	黄振, 何方, 李新爱, 等 . Fe基氧载体的生物质化学链气化过程热力学分析及实验研究[J].太阳能学报, 2013, 34(11): 1943-1949.
	Huang Z , He F , Li X A , et al . Thermodynamic analysis and experimental investigation of chemical-looping gasification of biomass with Fe-based oxygen carriers[J]. Acta Energiae Solaris Sinica, 2013, 34(11): 1943-1949.
106	Penthor S , Mayer K , Kern S , et al . Chemical-looping combustion of raw syngas from biomass steam gasification—coupled operation of two dual fluidized bed pilot plants[J]. Fuel, 2014, 127: 178-185.
107	Yan L B , He B S , Pei X H , et al . Design and comparisons of three biomass based hydrogen generation systems with chemical looping process[J]. International Journal of Hydrogen Energy, 2014, 39(31): 17540-17553.
108	Gopaul S G , Dutta A , Clemmer R . Chemical looping gasification for hydrogen production: a comparison of two unique processes simulated using ASPEN Plus[J]. International Journal of Hydrogen Energy, 2014, 39(11): 5804-5817.
109	诸林, 邓亚欣, 陈虎, 等 . 基于化学链制氧的生物质气化产氢工艺[J]. 过程工程学报, 2017, 17(2): 306-312.
	Zhu L , Deng Y X , Chen H , et al . Integrated biomass gasification with chemical looping air separation for hydrogen production[J]. Chin. J.Proc Eng., 2017,17(2):306-312.
110	赵坤, 何方, 黄振, 等 . 生物质化学链气化制取合成气模拟研究[J]. 煤炭转化, 2011, 34(4): 87-92.
	Zhao K , He F , Huang Z , et al . Simulation study on chemical-looping gasification of biomass for syngas[J]. Coal Conversion, 2011, 34(4): 87-92.
111	范峻铭, 洪慧, 金红光 . 基于化学链燃烧生物质煤互补的天然气动力联产系统研究[J].工程热物理学报, 2017, 38(7): 1466-1471.
	Fan J M , Hong H , Jin H G . System performance of SNG and power polygeneration system with chemical looping combustion driven by hybrid coal and biomass[J]. Journal of Engineering Thermophysics, 2017, 38(7): 1466-1471.
112	Udomchoke T , Wongsakulphasatch S , Kiatkittipong W , et al . Performance evaluation of sorption enhanced chemical-looping reforming for hydrogen production from biomass with modification of catalyst and sorbent regeneration[J]. Chemical Engineering Journal, 2016, 303: 338-347.
113	Cormos C . Biomass direct chemical looping for hydrogen and power co-production: process configuration, simulation, thermal integration and techno-economic assessment[J]. Fuel Processing Technology, 2015, 137: 16-23.
114	Heng L J , Zhang H Y , Xiao R . Hydrogen production from heavy fraction of bio-oil using iron-based chemical looping process: Thermodynamic simulation and performance analysis[J]. International Journal of Hydrogen Energy, 2016, 41(40): 17771-17783.

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