化工学报 ›› 2021, Vol. 72 ›› Issue (S1): 554-559.doi: 10.11949/0438-1157.20201576

• 材料化学工程与纳米技术 • 上一篇    下一篇

基于活性碳纤维毡复合吸附剂的储热性能

罗伟莉(),王雯雯,潘权稳(),葛天舒,王如竹   

  1. 上海交通大学机械与动力工程学院，上海 200240
  • 收稿日期:2020-11-03 修回日期:2021-02-01 出版日期:2021-06-20 发布日期:2021-06-20
  • 通讯作者: 潘权稳 E-mail:luoweili@sjtu.edu.cn;sailote@sjtu.edu.cn
  • 作者简介:罗伟莉（1983—），女，硕士，助理工程师，luoweili@sjtu.edu.cn
  • 基金资助:
    上海市青年科技英才扬帆计划项目(19YF1423100);空调设备及系统运行节能国家重点实验室开放基金项目(ACSKL2018KT1203);上海交通大学“新进青年教师启动计划”项目

Heat storage performance of composite adsorbent with activated carbon fiber

LUO Weili(),WANG Wenwen,PAN Quanwen(),GE Tianshu,WANG Ruzhu   

  1. School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2020-11-03 Revised:2021-02-01 Published:2021-06-20 Online:2021-06-20
  • Contact: PAN Quanwen E-mail:luoweili@sjtu.edu.cn;sailote@sjtu.edu.cn

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摘要：

研制了一种以活性碳纤维毡为基质、氯化锂（LiCl）为吸湿盐的复合吸附剂，并辅以硅溶胶进行固化成型。该复合吸附剂可用于以水为吸附质的热化学吸附储热系统，并对其微观结构、吸附性能和储热性能进行了表征研究。制备了不同含盐量的复合吸附剂样品，并根据样品的溶液泄漏现象，确定ACFLi30为最佳样品。通过试验测量，获得ACFLi30样品的热导率、孔比表面积、孔体积和孔径等参数。并对多种温湿度工况下的平衡和动态吸附性能进行测试，研究了不同温湿度条件下样品的吸附特性。结果表明样品的吸水量可达1.1 g/g（20℃、75% RH）。利用同步热分析仪测试了复合吸附剂的储热密度，ACFLi30的质量和体积储热密度分别达到1.08 kW·h/kg和588.2 kW·h/m3。与膨胀蛭石和活性氧化铝等基质相比，活性碳纤维毡基质在体积储热密度更具优势。

关键词: 活性碳纤维毡, 吸附剂, 氯化锂, 吸附, 解吸, 储热

Abstract:

In order for efficient chemisorption heat storage system, an activated carbon fiber (ACF)-LiCl composite sorbent was developed while silica sol (SS) was used for shaping. Morphologies records, sorption kinetics and heat storage performance of ACF-LiCl composite sorbent were investigated. Samples with different salt contents were fabricated to store low-temperature thermal heat by impregnation methods. According to the test of the solution leakage phenomenon, the best sample was determined to be ACFLi30. Through the experimental study, thermal conductivity, specific surface area, pore volume and pore diameter were obtained. Sorption kinetics and equilibrium sorption capacity under conditions of multi temperature and relative humidity were studied by utilizing constant temperature and humidity chamber. The water uptake of ACFLi30 sample can be up to 1.1 g/g. Energy storage density was measured by simultaneous thermal analyzer. ACFLi30 sample had the good energy storage performance with 1.08 kW·h/kg mass energy storage density and 588.2 kW·h/m3 volumetric energy storage density. Compared with expanded vermiculite and activated alumina matrix, composite sorbent with ACF matrix has advantage in volumetric energy storage density. As a consequence, ACF-LiCl is promising sorbent in the field of chemisorption heat storage.

Key words: activated carbon fiber, sorbent, lithium chloride, adsorption, desorption, heat storage

中图分类号: 

  • TK 02

图1

复合吸附剂的制备过程"

表1

不同复合吸附剂的含盐量"

样品ACF占比/%SS占比/%LiCl占比/%
ACFLi200.0960.6540.250
ACFLi300.0800.5870.333
ACFLi400.0790.5330.388

表2

样品比表面积、孔体积和孔径"

样品比表面积/(m2/g)孔体积/(cm3/g)孔径/nm
ACF[28]1380.640.551.58
ACFLi30124.220.111.79

表3

样品热导率、热扩散系数和比热容"

样品表观密度/(kg/m3)

热导率/

(W/(m?K))

热扩散系数/(mm2/s)

比热容/

(MJ/(m3?K))

ACF80~850.06940.36300.1912
ACFLi30543.30.56490.18063.1280

图2

ACFLi30的平衡吸附曲线"

图3

ACFLi30的动态吸附曲线"

图4

ACFLi30的脱附过程吸水量和热流曲线"

表4

样品储热密度"

样品质量储热密度/(kW·h/kg)体积储热密度/(kW·h/m3)
ACFLi301.08588.2
EVM-LiCl[29]1.21171.6
EVM-LiCl[30]0.72253
AA-LiCl[20]0.29318.3
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