化工学报 ›› 2011, Vol. 62 ›› Issue (S2): 165-168.DOI: 10.3969/j.issn.0438-1157.2011.z2.030

• 材料化学工程与纳米技术 • 上一篇    下一篇

新型冠醚功能化离子液体[A(benzo15C5)HIM][(CF3SO22N]的合成

王江,张贝贝,谢鹏飞,刘汉兰,何凌昊   

  1. 华中农业大学理学院
  • 收稿日期:2011-11-10 出版日期:2011-12-20 发布日期:2011-12-20
  • 通讯作者: 刘汉兰

Preparation of a novel crown ether functionalized ionic liquid[A(benzo15C5)HIM][(CF3SO22N]

WANG Jiang,ZHANG Beibei,XIE Pengfei,LIU Hanlan,HE Linghao   

  • Received:2011-11-10 Online:2011-12-20 Published:2011-12-20

摘要: 通过Williamson反应、Friedel-Crafts酰基化等反应合成了新型冠醚功能化离子液体1-烯丙基-3-(6′-氧代苯并-15-冠-5-己基)咪唑双三氟甲磺酰亚胺([A(benzo15C5)HIM][(CF3SO22N]),并以IR、1H NMR对其结构进行了表征。初步探讨了双酚A(BPA)在多壁碳纳米管-离子液体(MWCNTs-IL)修饰玻碳电极上的电化学行为。

关键词: 冠醚, 功能化, 离子液体, 合成

Abstract: A novel crown ether functionalized ionic liquid 1-allyl-3-(6′-oxo-benzo-15-crown-5 hexyl)imidazolium bis(trifluoromethanesulfonyl)imide ([A(benzo15C5)HIM][(CF3SO22N]was synthesized by Williamson reaction,Friedel-Crafts acylation of benzene reaction etc,its structures were characterized by IR,1H NMR,and the behavior of BPA in which MWCNTs-IL modified glassy carbon electrode was detected.

Key words: crown ether, functionalized, ionic liquid, synthesis