Pb2+识别响应型智能高分子功能材料的研究进展

doi:10.3969/j.issn.0438-1157.2014.05.003

化工学报 ›› 2014, Vol. 65 ›› Issue (5): 1571-1576.DOI: 10.3969/j.issn.0438-1157.2014.05.003

Pb²⁺识别响应型智能高分子功能材料的研究进展

刘壮, 巨晓洁, 谢锐, 汪伟, 褚良银

四川大学化学工程学院, 四川成都 610065

收稿日期:2013-12-23 修回日期:2014-01-28 出版日期:2014-05-05 发布日期:2014-05-05
通讯作者: 褚良银
基金资助:
国家自然科学基金项目（21136006，21276162）；国家重点基础研究发展计划项目（2009CB623407）。

Progress of Pb²⁺-recognition-responsive smart polymeric functional materials

LIU Zhuang, JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin

School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

Received:2013-12-23 Revised:2014-01-28 Online:2014-05-05 Published:2014-05-05
Supported by:
supported by the National Natural Science Foundation of China (21136006,21276162) and the National Basic Research Program of China (2009CB623407).

摘要/Abstract

摘要： 发酵生物甲烷的菌群可以吸附Pb²⁺等重金属而在沼液和沼渣中富集；因此，在生物甲烷系统研究过程中，Pb²⁺等重金属离子的检测和处理是沼液和沼渣处理的关键问题之一。18-冠-6具有选择性络合Pb²⁺的能力，研究者们将18-冠-6的Pb²⁺识别特性与聚N-异丙基丙烯酰胺的相变行为特性相结合制备了一系列Pb²⁺识别响应型智能高分子功能材料。本文综述了基于18-冠-6和聚N-异丙基丙烯酰胺的离子识别响应型智能高分子材料在检测和去除Pb²⁺等方面的研究进展。

关键词: Pb²⁺识别, 吸附, 膜, 聚合物

Abstract: Some of the anaerobic bacterium fermented bio-methane can adsorb heavy metals, such as Pb²⁺, which are enriched in biogas slurry and residue. For this reason, the detection and removal of heavy metal ions, such as Pb²⁺ ion in biogas slurry and residue is one of the key problems in the study of bio-methane systems. 18-crown-6 has remarkable recognition ability towards Pb²⁺ ion. The Pb²⁺ ion-recognition-responsive smart materials composed of 18-crown-6 and poly(N-isopropylacrylamide) (PNIPAM) have been developed. In this paper, the progress of investigation on Pb²⁺ ion-recognition-responsive smart polymeric materials based on 18-crown-6 and poly(N-isopropylacrylamide) for detection and removal of Pb²⁺ is reviewed.

Key words: Pb²⁺-recognition, sorption, membranes, polymers

中图分类号:

TB381

刘壮, 巨晓洁, 谢锐, 汪伟, 褚良银. Pb²⁺识别响应型智能高分子功能材料的研究进展[J]. 化工学报, 2014, 65(5): 1571-1576.

LIU Zhuang, JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin. Progress of Pb²⁺-recognition-responsive smart polymeric functional materials[J]. CIESC Journal, 2014, 65(5): 1571-1576.

参考文献 32

[1]	Liu Chang(刘畅), Lu Xiaohua(陆小华). Carbon reduction pattern in China: comparison of CCS and biomethane route[J]. CIESC Journal(化工学报), 2013, 64(1): 7-10
[2]	Kratochvil D, Volesky B. Advances in the biosorption of heavy metals[J]. Trends Biotechnol., 1998, 16(7): 291-300
[3]	Ahluwalia S S, Goyal D. Microbial and plant derived biomass for removal of heavy metals from wastewater[J]. Bioresource Technol., 2007, 98(12): 2243-2257
[4]	Narin I, Soylak M, Elci L, Dogan M. Determination of trace metal ions by AAS in natural water samples after preconcentration of pyrocatechol violet complexes on an activated carbon column[J]. Talanta, 2000, 52(6): 1041-1046
[5]	Mahmoud M E, Kenawy I M M, Hafez MM A H, Lashein R R. Removal, preconcentration and determination of trace heavy metal ions in water samples by AAS via chemically modified silica gel N-(1-carboxy-6-hydroxy) benzylidenepropylamine ion exchanger[J]. Desalination, 2010, 250(1): 62-70
[6]	Caroli S, Forte G, Iamiceli A L, Galoppi B. Determination of essential and potentially toxic trace elements in honey by inductively coupled plasma-based techniques[J]. Talanta, 1999, 50(2): 327-336
[7]	Cesarino I, Cavalheiro E T G, Brett C M A. Simultaneous determination of cadmium, lead, copper and mercury ions using organofunctionalized SBA-15 nanostructured silica modified graphite- polyurethane composite electrode[J]. Electroanalysis, 2010, 22(1): 61-68
[8]	Tonle I K, Letaief S, Ngameni E, Walcarius A, Detellier C. Square wave voltammetric determination of lead(Ⅱ) ions using a carbon paste electrode modified by a thiol-functionalized kaolinite[J]. Electroanalysis, 2011, 23(1): 245-252
[9]	Matlock M M, Howerton B S, Atwood D A. Chemical precipitation of heavy metals from acid mine drainage[J]. Water Res., 2002, 36(19): 4757-4764
[10]	Babel S, Kurniawan T A. Low-cost adsorbents for heavy metals uptake from contaminated water: a review[J]. J. Hazard. Mater., 2003, 97(1/2/3): 219-243
[11]	Alkhudhiri A, Darwish N, Hilal N. Membrane distillation: a comprehensive review[J]. Desalination, 2012, 287(15): 2-18
[12]	Izatt R M, Pawlak K, Bradshaw J S, Bruening R L. Thermodynamic and kinetic data for macrocycle interactions with cations and anions[J]. Chem. Rev., 1991, 91(8): 1721-2085
[13]	Guo Xiaojing, Zhu Yudan, Wei Mingjie, Wu Ximing, Lü Linghong, Lu Xiaohua. Theoretical study of hydration effects on the selectivity of 18-crown-6 between K+ and Na+[J]. Chinese J. Chem. Eng., 2011, 19(2): 212-216
[14]	Ju Xiaojie(巨晓洁), Xie Rui(谢锐), Wang Wei(汪伟), Chu Liangyin(褚良银). Development of ion-recognition-responsive smart materials based on crown ethers[J]. CIESC Journal(化工学报), 2013, 64(1): 261-267
[15]	Irie M, Misumi Y, Tanaka T. Stimuli-responsive polymers: chemical induced reversible phase separation of an aqueous solution of poly(N-isopropylacrylamide) with pendent crown ether groups[J]. Polymer, 1993, 34(21): 4531-4535
[16]	Shannon R D, Prewitt C T. Effective ionic radii in oxides and fluorides[J]. Acta Crystallogr. B, 1969, 25(5): 925-946
[17]	Takeda Y, Kohno R, Kudo Y, Fukada N. Stabilities in water and transfer activity coefficients from water to nonaqueous solvents of benzo-18-crown-6-metal ion complexes[J]. B. Chem. Soc. Jpn., 1989, 62(4): 999-1003
[18]	Zhang B, Ju X J, Xie R, Liu Z, Pi S W, Chu L Y. Comprehensive effects of metal ions on responsive characteristics of P(NIPAM-co- B18C6Am)[J]. J. Phys. Chem. B, 2012, 116(18): 5527- 5536
[19]	Luo Q F, Guan Y, Zhang Y J, Siddiq M. Lead-sensitive PNIPAM microgels modified with crown ether groups[J]. J. Polym. Sci. Pol. Chem., 2010, 48(18): 4120-4127
[20]	Ju X J, Zhang S B, Zhou M Y, Xie R, Yang L, Chu L Y. Novel heavy-metal adsorption material: ion-recognition P(NIPAM-co- BCAm) hydrogels for removal of lead(Ⅱ) ions[J]. J. Hazard. Mater., 2009, 167(1/2/3): 114-118
[21]	Pi S W, Ju X J, Wu H G, Xie R, Chu L Y. Smart responsive microcapsules capable of recognizing heavy metal ions[J]. J. Colloid. Interf. Sci., 2010, 349(2): 512-518
[22]	Liu Y M, Wang W, Zheng W C, Ju X J, Xie R, Zerrouk D, Deng N N, Chu L Y. Hydrogel-based microactuators with remote-controlled locomotion and fast Pb2+-response for micromanipulation[J]. ACS Appl. Mater. Interfaces, 2013, 5(15): 7219-7226
[23]	Yamaguchi T, Ito T, Sato T, Shinbo T, Nakao S. Development of a fast response molecular recognition ion gating membrane[J]. J. Am. Chem. Soc., 1999, 121(16): 4078-4079
[24]	Ito T, Hioki T, Yamaguchi T, Shinbo T, Nakao S, Kimura S. Development of a molecular recognition ion gating membrane and estimation of its pore size control[J]. J. Am. Chem. Soc., 2002, 124(26): 7840-7846
[25]	Ito T, Yamaguchi T. Osmotic pressure control in response to a specific ion signal at physiological temperature using a molecular recognition ion gating membrane[J]. J. Am. Chem. Soc., 2004, 126(20): 6202- 6203
[26]	Okajima S, Sakai Y, Yamaguchi T. Development of a regenerable cell culture system that senses and releases dead cells[J]. Langmuir, 2005, 21(9): 4043-4049
[27]	Okajima S, Yamaguchi T, Sakai Y, Nakao S. Regulation of cell adhesion using a signal-responsive membrane substrate[J]. Biotechnol. Bioeng., 2005, 91(2): 237-243
[28]	Ito T, Yamaguchi T. Nonlinear self-excited oscillation of a synthetic ion-channel-inspired membrane[J]. Angew. Chem. Int. Edit., 2006, 45(34): 5630-5633
[29]	Ito T, Yamaguchi T. Controlled release of model drugs through a molecular recognition ion gating membrane in response to a specific ion signal[J]. Langmuir, 2006, 22(8): 3945-3949
[30]	Ito T, Oshiba Y, Ohashi H, Tamaki T, Yamaguchi T. Reentrant phase transition behavior and sensitivity enhancement of a molecular recognition ion gating membrane in an aqueous ethanol solution[J]. J. Membrane Sci., 2010, 348(1/2): 369-375
[31]	Ito T, Ohashi H, Tamaki T, Yamaguchi T. Mathematical modeling of molecular recognition by an ion-gating membrane oscillator[J]. J. Membrane Sci., 2013, 448(15): 231-239
[32]	Liu Z, Luo F, Ju X J, Xie R, Sun Y M, Wang W, Chu L Y. Gating membranes for water treatment: detection and removal of trace Pb2+ ions based on molecular recognition and polymer phase transition[J]. J. Mater. Chem. A, 2013, 1(34): 9659-9671

Pb²⁺识别响应型智能高分子功能材料的研究进展

Progress of Pb²⁺-recognition-responsive smart polymeric functional materials

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献 32

相关文章 15

编辑推荐

Metrics

本文评价

[1]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[2]	邵苛苛, 宋孟杰, 江正勇, 张旋, 张龙, 高润淼, 甄泽康. 水平方向上冰中受陷气泡形成和分布实验研究[J]. 化工学报, 2023, 74(S1): 161-164.
[3]	吴延鹏, 李晓宇, 钟乔洋. 静电纺丝纳米纤维双疏膜油性细颗粒物过滤性能实验分析[J]. 化工学报, 2023, 74(S1): 259-264.
[4]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[5]	杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH₃的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755.
[6]	胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765.
[7]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[8]	何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774.
[9]	高燕, 伍鹏, 尚超, 胡泽君, 陈晓东. 基于双流体喷嘴的磁性琼脂糖微球的制备及其蛋白吸附性能探究[J]. 化工学报, 2023, 74(8): 3457-3471.
[10]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[11]	张佳怡, 何佳莉, 谢江鹏, 王健, 赵鹬, 张栋强. 渗透汽化技术用于锂电池生产中N-甲基吡咯烷酮回收的研究进展[J]. 化工学报, 2023, 74(8): 3203-3215.
[12]	盛冰纯, 于建国, 林森. 铝基锂吸附剂分离高钠型地下卤水锂资源过程研究[J]. 化工学报, 2023, 74(8): 3375-3385.
[13]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[14]	张贲, 王松柏, 魏子亚, 郝婷婷, 马学虎, 温荣福. 超亲水多孔金属结构驱动的毛细液膜冷凝及传热强化[J]. 化工学报, 2023, 74(7): 2824-2835.
[15]	王杰, 丘晓琳, 赵烨, 刘鑫洋, 韩忠强, 许雍, 蒋文瀚. 聚电解质静电沉积改性PHBV抗氧化膜的制备与性能研究[J]. 化工学报, 2023, 74(7): 3068-3078.