化工学报 ›› 2018, Vol. 69 ›› Issue (1): 141-155.DOI: 10.11949/j.issn.0438-1157.20171164
刘东帆, 孙淑英, 于建国
收稿日期:
2017-08-23
修回日期:
2017-11-29
出版日期:
2018-01-05
发布日期:
2018-01-05
通讯作者:
于建国
基金资助:
国家自然科学基金项目(U1407120)。
LIU Dongfan, SUN Shuying, YU Jianguo
Received:
2017-08-23
Revised:
2017-11-29
Online:
2018-01-05
Published:
2018-01-05
Contact:
10.11949/j.issn.0438-1157.20171164
Supported by:
supported by the National Natural Science Foundation of China (U1407120).
摘要:
近年来,随着核电、航空航天、锂电动汽车等行业的快速发展,全球对锂产品的需求逐年增加。鉴于卤水锂资源约占世界锂资源的65%及世界锂产品产量的58%来自于卤水工艺,过去十余年卤水提锂材料、技术与装备研究方兴未艾,吸引越来越多的科技工作者关注。根据全球特别是中国卤水锂资源赋存特征与状态,归纳分析了沉淀法、膜法、萃取法和吸附法等卤水提锂关键技术,综述了各种方法的适应性及发展方向。
中图分类号:
刘东帆, 孙淑英, 于建国. 盐湖卤水提锂技术研究与发展[J]. 化工学报, 2018, 69(1): 141-155.
LIU Dongfan, SUN Shuying, YU Jianguo. Research and development on technique of lithium recovery from salt lake brine[J]. CIESC Journal, 2018, 69(1): 141-155.
[1] | KIM H, HONG J, PARK K Y, et al. Aqueous rechargeable Li and Na ion batteries[J]. Chem. Rev., 2014, 114(23):11788. |
[2] | HANNA VIKSTR M S D, MIKAEL H. Lithium availability and future production outlooks[J]. Appl. Energy, 2013, 110(110):252-266. |
[3] | SPEIRS J, CONTESTABILE M, HOUARI Y, et al. The future of lithium availability for electric vehicle batteries[J]. Renew. Sust. Energ. Rev., 2014, 35:183-193. |
[4] | KEMPTHORNE D, MYERS M D. Mineral Commodity Summaries 2007[R]. Washington:United States Government Printing Office, 2007. |
[5] | KEMPTHORNE D, MYERS M D. Mineral Commodity Summaries 2008[R]. Washington:United States Government Printing Office, 2008. |
[6] | SALAZAR K, KIMBALL S M. Mineral Commodity Summaries 2009[R]. Washington:United States Government Printing Office, 2009. |
[7] | SALAZAR K, MCNUTT M K. Mineral Commodity Summaries 2010[R]. Washington:United States Government Printing Office, 2010. |
[8] | SALAZAR K, MCNUTT M K. Mineral Commodity Summaries 2011[R]. Reston:U.S. Geological Survey, 2011. |
[9] | SALAZAR K, MCNUTT M K. Mineral Commodity Summaries 2012[R]. Reston:U.S. Geological Survey, 2012. |
[10] | SALAZAR K, MCNUTT M K. Mineral Commodity Summaries 2013[R]. Reston:U.S. Geological Survey, 2013. |
[11] | JEWELL S, KIMBALL S M. Mineral Commodity Summaries 2014[R]. Reston:U.S. Geological Survey, 2014. |
[12] | JEWELL S, KIMBALL S M. Mineral Commodity Summaries 2015[R]. Reston:U.S. Geological Survey, 2015. |
[13] | JEWELL S, KIMBALL S M. Mineral Commodity Summaries 2016[R]. Reston:U.S. Geological Survey, 2016. |
[14] | JEWELL S, KIMBALL S M. Mineral Commodity Summaries 2017[R]. Reston:U.S. Geological Survey, 2017. |
[15] | CABEZA L F, GUTIERREZ A, BARRENECHE C, et al. Lithium in thermal energy storage:a state-of-the-art review[J]. Renew. Sust. Energ. Rev., 2015, 42:1106-1112. |
[16] | 生意社. 中国碳酸锂风向标——碳酸锂生产者价格指数[EB/OL].[2017-08-09]. http://www.100ppi.com/vane/detail-733.html,Business club. Sign of lithium carbonate of China-price index of lithium carbonate producers[EB/OL].[2017-08-09]. http://www.100ppi.com/vane/detail-733.html. |
[17] | SWAIN B. Recovery and recycling of lithium:a review[J]. Sep. Purif. Technol., 2017, 172:388-403. |
[18] | 刘博, 施毅. 行业研究·锂行业[R]. 上海:海通证券研究所, 2013. LIU B, SHI Y. Industry research·lithium[R]. Shanghai:Institute of Haitong Securities, 2013. |
[19] | AN J W, KANG D J, TRAN K T, et al. Recovery of lithium from Uyuni salar brine[J]. Hydrometallurgy, 2012, 117/118(4):64-70. |
[20] | BORYTA D A, KULLBERG T F, THURSTON A M. Production of lithium compounds directly from lithium containing brines:US7390466[P]. 2008-06-24. |
[21] | HAMZAOUI A H, M'NIF A, HAMMI H, et al. Contribution to the lithium recovery from brine[J]. Desalination, 2003, 158:221-224. |
[22] | UM N, HIRATO T. Precipitation behavior of Ca(OH)2, Mg(OH)2, and Mn(OH)2 from CaCl2, MgCl2, and MnCl2 in NaOH-H2O solutions and study of lithium recovery from seawater via two-stage precipitation process[J]. Hydrometallurgy, 2014, 146(3):142-148. |
[23] | 陆增, 胡士文, 袁建军. 从高镁锂比盐湖水中提取碳酸锂的方法:1398785A[P]. 2003-03-26. LU Z, HU S W, YUAN J J. Method for lithium recovery from the brine with high Mg/Li ratio:1398785A[P]. 2003-03-26. |
[24] | 徐徽, 李新海, 石西昌, 等. 一种从盐湖卤水中联合提取镁、锂的方法:1618997A[P]. 2005-05-25. XU H, LI X H, SHI X C, et al. A method for magesium and lithium recovery from the salt lake brine:1618997A[P]. 2005-05-25. |
[25] | BUKOWSKY H, UHLEMANN E, STEINBORN D. The recovery of pure lithium chloride from "brines" containing higher contents of calcium chloride and magnesium chloride[J]. Hydrometallurgy, 1991, 27(3):317-325. |
[26] | 钟辉, 杨建元, 张芃. 高镁锂比盐湖卤水中制取碳酸锂的方法:1335262A[P]. 2002-02-13. ZHONG H, YANG J Y, ZHANG P. A method for lithium carbonate synthesis from salt lake brine with high Mg/Li ratio:1335262A[P]. 2002-02-13. |
[27] | KAPLAN D. Process for the extraction of lithium from dead sea solutions[J]. Isr. J. Chem., 1963, 1(2):115-120. |
[28] | EPSTEIN J A, FEIST E M, ZMORA J, et al. Extraction of lithium from the dead sea[J]. Hydrometallurgy, 1981, 6(3):269-275. |
[29] | HAMZAOUI A H, HAMMI H, M'NIF A. Operating conditions for lithium recovery from natural brines[J]. Russ. J. Inorg. Chem., 2007, 52(12):1859-1863. |
[30] | YANAGASE K, YOSHINAGA T, KAWANO K, et al. The recovery of lithium from geothermal water in the Hatchobaru area of Kyushu, Japan[J]. Bull. Chem. Soc. Jpn., 2006, 56(8):2490-2498. |
[31] | YOSHINAGA T, KAWANO K, IMOTO H. ChemInform abstract:basic study on lithium recovery from lithium containing solution[J]. Bull. Chem. Soc. Jpn., 1986, 59(4):1207-1213. |
[32] | 魏新俊, 王永浩, 保守君. 自卤水中同时沉淀硼锂的方法:1249272A[P]. 2000-04-05. WEI X J, WANG Y H, BAO S J. A method for precipitating boron and lithium simultaneously from brine:1249272A[P]. 2000-04-05. |
[33] | 钟辉, 许惠. 一种硫酸镁亚型盐湖卤水镁锂分离方法:1454843A[P]. 2003-11-12. ZHONG H, XU H. A method for Mg/Li separation from magnesium sulfate subtype brine:1454843A[P]. 2003-11-12. |
[34] | 王日公, 王军, 王晓燕, 等. 从高镁锂比盐湖卤水中一步提取碳酸锂的方法:1502557A[P]. 2004-06-09. WANG R G, WANG J, WANG X Y, et al. A method for one-step lithium carbonate extraction fromsalt lake brine of high Mg/Li ratio:1502557A[P]. 2004-06-09. |
[35] | 姚红娟, 王晓琳. 压力驱动膜分离过程的操作模式及其优化[J]. 膜科学与技术, 2003, 23(6):38-43. YAO H J, WANG X L. Operation mode and optimization of the pressure-driven membrane separation process[J]. Membrane Sci. Technol., 2003, 23(6):38-43. |
[36] | 高从堦, 陈益棠. 纳滤膜及其应用[J]. 中国有色金属学报, 2004, 14(s1):310-316. GAO C J, CHEN Y T. Nanofiltration membrane and its application[J]. Chinese J. Nonferr. Metal, 2004, 14(s1):310-316. |
[37] | WEN X, MA P, ZHU C, et al. Preliminary study on recovering lithium chloride from lithium-containing waters by nanofiltration[J]. Sep. Purif. Technol., 2006, 49(3):230-236. |
[38] | 康为清, 时历杰, 赵有璟, 等. 纳滤法用于盐湖卤水镁锂分离的初步实验[J]. 无机盐工业, 2014, 46(12):22-24. KANG W Q, SHI L J, ZHAO Y J, et al. Preliminary test of separation of Mg2+/Li+ in salt lake brine by nanofiltration[J]. Inorg. Chem. Ind., 2014, 46(12):22-24. |
[39] | 计超, 张杰, 张志君, 等. DK纳滤膜对高镁锂比卤水的分离性能研究[J]. 膜科学与技术, 2014, 34(3):79-85. JI C, ZHANG J, ZHANG Z J, et al. Separation performance of DK nanofiltration membrane for the brine with high Mg/Li ratio[J]. Membrane Sci. Technol., 2014, 34(3):79-85. |
[40] | SUN S Y, CAI L J, NIE X Y, et al. Separation of magnesium and lithium from brine using a Desal nanofiltration membrane[J]. J. Water Process Eng., 2015, 7:210-217. |
[41] | JI Z Y, CHEN Q B, YUAN J S, et al. Preliminary study on recovering lithium from high Mg2+/Li+ ratio brines by electrodialysis[J]. Sep. Purif. Technol., 2017, 172:168-177. |
[42] | SOMRANI A, HAMZAOUI A H, PONTIE M. Study on lithium separation from salt lake brines by nanofiltration (NF) and low pressure reverse osmosis (LPRO)[J]. Desalination, 2013, 317(7):184-192. |
[43] | LI X, ZHANG C, ZHANG S, et al. Preparation and characterization of positively charged polyamide composite nanofiltration hollow fiber membrane for lithium and magnesium separation[J]. Desalination, 2015, 369:26-36. |
[44] | BRUGGEN B V D, KONINCKX A, VANDECASTEELE C. Separation of monovalent and divalent ions from aqueous solution by electrodialysis and nanofiltration[J]. Water Res., 2004, 38(5):1347-1353. |
[45] | 马培华, 邓小川, 温现民. 从盐湖卤水中分离镁和浓缩锂的方法:1626443A[P]. 2005-06-15. MA P H, DENG X C, WEN X M. Methods for magnesium separation and lithium concentration from salt lake brine:1626443A[P]. 2005-06-15. |
[46] | NIE X Y, SUN S Y, SONG X, et al. Further investigation into lithium recovery from salt lake brines with different feed characteristics by electrodialysis[J]. J. Membr. Sci., 2017, 530:185-191. |
[47] | NIE X Y, SUN S Y, SUN Z, et al. Ion-fractionation of lithium ions from magnesium ions by electrodialysis using monovalent selective ion-exchange membranes[J]. Desalination, 2017, 403:128-135. |
[48] | HOSHINO T. Development of technology for recovering lithium from seawater by electrodialysis using ionic liquid membrane[J]. Fusion. Eng. Des., 2013, 88(11):2956-2959. |
[49] | HOSHINO T. Preliminary studies of lithium recovery technology from seawater by electrodialysis using ionic liquid membrane[J]. Desalination, 2013, 317(11):11-16. |
[50] | SEELEY F G, BALDWIN W H. Extraction of lithium from neutral salt solutions with fluorinated β-diketones[J]. J. Inorg. Ncl. Chem., 1976, 38(5):1049-1052. |
[51] | SEELEY F, BALDWIN W. Extraction of lithium from neutral brines using a beta diketone and trioctylphosphine oxide:US3793443[P]. 1974-02-19. |
[52] | ZHOU Z, QIN W, FEI W, et al. A study on stoichiometry of complexes of tributyl phosphate and methyl isobutyl ketone with lithium in the presence of FeCl3[J]. Chinese J. Chem. Eng., 2012, 20(1):36-39. |
[53] | XIANG W, LIANG S, ZHOU Z, et al. Lithium recovery from salt lake brine by counter-current extraction using tributyl phosphate/FeCl3 in methyl isobutyl ketone[J]. Hydrometallurgy, 2017, 171:27-32. |
[54] | XIANG W, LIANG S, ZHOU Z, et al. Extraction of lithium from salt lake brine containing borate anion and high concentration of magnesium[J]. Hydrometallurgy, 2016, 166:9-15. |
[55] | ZHOU Z, WEI Q, FEI W. Extraction equilibria of lithium with tributyl phosphate in three diluents[J]. J. Chem. Eng. Data, 2011, 56(9):3518-3522. |
[56] | ZHOU Z, WEI Q, YANG L, et al. Extraction equilibria of lithium with tributyl phosphate in kerosene and FeCl3[J]. J. Chem. Eng. Data, 2012, 57(1):82-86. |
[57] | ZHOU Z, LIANG S, QIN W, et al. Extraction equilibria of lithium with tributyl phosphate, diisobutyl ketone, acetophenone, methyl isobutyl ketone, and 2-heptanone in kerosene and FeCl3[J]. Ind. Eng. Chem. Res., 2013, 52(23):7912-7917. |
[58] | ZHOU Z, LIANG F, WEI Q, et al. Coupled reaction and solvent extraction process to form Li2CO3:mechanism and product characterization[J]. AIChE J., 2013, 60(1):282-288. |
[59] | YI H, WANG Y, SMITH K H, et al. Axial dispersion and mass transfer of a pulsed solvent extraction column with novel ceramic internals[J]. Ind. Eng. Chem. Res., 2017, 56:3049-3058. |
[60] | ZHOU Z, QIN W, CHU Y, et al. Elucidation of the structures of tributyl phosphate/Li complexes in the presence of FeCl3 via UV-visible, Raman and IR spectroscopy and the method of continuous variation[J]. Chem. Eng. Sci., 2013, 101(20):577-585. |
[61] | YI H, WANG Y, SMITH K H, et al. Hydrodynamic performance of a pulsed solvent extraction column with novel ceramic internals:holdup and drop size[J]. Ind. Eng. Chem. Res., 2016, 56:999-1007. |
[62] | 秦炜, 周智勇, 谭元忠, 等. 一种从高镁锂比盐湖卤水中提取碳酸锂的方法:102275956A[P]. 2011-12-14. QIN W, ZHOU Z Y, TAN Y Z, et al. A method for lithium carbonate extraction from salt lake brine with high Mg/Li ratio brine:102275956A[P]. 2011-12-14. |
[63] | ZHOU Z, WEI Q, LIANG S, et al. Recovery of lithium using tributyl phosphate in methyl isobutyl ketone and FeCl3[J]. Ind. Eng. Chem. Res., 2012, 51(39):12926-12932. |
[64] | PRANOLO Y, ZHU Z, CHENG C Y. Separation of lithium from sodium in chloride solutions using SSX systems with LIX 54 and Cyanex 923[J]. Hydrometallurgy, 2015, 154:33-39. |
[65] | MA P, CHEN X D, HOSSAIN M M. Lithium extraction from a multicomponent mixture using supported liquid membranes[J]. Sep. Sci. Technol., 2000, 35(15):2513-2533. |
[66] | KINUGASA T, NISHIBARA H, MURAO Y, et al. Equilibrium and kinetics of lithium extraction by a mixture of LIX54 and TOPO[J]. J. Chem. Eng. Jpn., 1993, 27(6):815-818. |
[67] | MUKAI H, MIYAZAKI S, UMETANI S, et al. Synergic liquid/liquid extraction of lithium and sodium with 4-acyl-5-pyrazolones with bulky substituents and tri-n-octylphosphine oxide[J]. Anal. Chim. Acta, 1988, 220(1):111-117. |
[68] | LI H F, LI L J, SHI D, et al. Extraction kinetics of lithium ions by N,N-bis(2-ethylhexyl)acetamide from simulated brine using rising single drop method[J]. Hydrometallurgy, 2016, 160:1-5. |
[69] | HANO T, MATSUMOTO M, OHTAKE T, et al. Recovery of lithium from geothermal water by solvent extraction technique[J]. Solvent Extr. Ion Exch., 1992, 10(2):195-206. |
[70] | GREGORIUS, RIONUGROHO, HARVIANTO, et al. Solvent extraction and stripping of lithium ion from aqueous solution and its application to seawater[J]. Rare Metals, 2016, 35(12):948-953. |
[71] | TSUKUBE H, HORI K, INOUE T. Amine-armed aza-12-crown-4 as a new Li+ ion-specific ionophore[J]. Tetrahedron Letters, 1993, 34(42):6749-6752. |
[72] | TORREJOS R E C, NISOLA G M, SONG H S, et al. Liquid-liquid extraction of lithium using lipophilic dibenzo-14-crown-4 ether carboxylic acid in hydrophobic room temperature ionic liquid[J]. Hydrometallurgy, 2016, 164:362-371. |
[73] | KATAYAMA Y, FUKUDA R, IWASAKI T, et al. Synthesis of chromogenic crown ethers and liquid-liquid extraction of alkaline earth metal ions[J]. Anal. Chim. Acta, 1988, 173:193-209. |
[74] | ITOH T, BILLAH M, HONJO T, et al. Separation and determination of a trace amount of lithium as its thenoyltrifluoroacetone complex with 12-crown-4 by means of synergic extraction and flame photometry[J]. Anal. Sci., 1991, 7:47-50. |
[75] | HABATA Y, IKEDA M, AKABORI S. Lithium ion selective dibenzo-14-crown-4 possessing a phosphoric acid functional group as a pendant[J]. Cheminform, 1992, 23(47):3157-3160. |
[76] | CZECH B P, BABB D A, SON B, et al. Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds:synthesis and lithium ion complexation[J]. Cheminform, 1984, 49(19):4805-4810. |
[77] | BOULATOV R, DU B, MEYERS E A, et al. Two novel lithium-15-crown-5 complexes:an extended LiCl chain stabilized by crown ether and a dimeric complex stabilized by hydrogen bonding with water[J]. Inorg. Chem., 1999, 38(20):4554. |
[78] | BARTSCH R A, GOO M J, CHRISTIAN G D, et al. Influence of ring substituents and matrix on lithium/sodium selectivity of 14-crown-4 and benzo-13-crown-4-compounds[J]. Anal. Chim. Acta, 1993, 272(2):285-292. |
[79] | BARTSCH R A, CZECH B P, KANG S I, et al. ChemInform abstract:high lithium selectivity in competitive alkali metal solvent extraction by lipophilic crown carboxylic acids[J]. Chem. Inf., 1985, 16(49):4997-4998. |
[80] | JI L, LI L, SHI D, et al. Extraction equilibria of lithium with N, N-bis(2-ethylhexyl)-3-oxobutanamide and tributyl phosphate in kerosene and FeCl3[J]. Hydrometallurgy, 2016, 164:304-312. |
[81] | JI L, HU Y, LI L, et al. Lithium extraction with a synergistic system of dioctyl phthalate and tributyl phosphate in kerosene and FeCl3[J]. Hydrometallurgy, 2016, 162:71-78. |
[82] | SHI C, JING Y, JIA Y. Solvent extraction of lithium ions by tri-n-butyl phosphate using a room temperature ionic liquid[J]. J. Mol. Liq., 2016, 215:640-646. |
[83] | SHI C, JIA Y, ZHANG C, et al. Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate[J]. Fusion. Eng. Des., 2015, 90:1-6. |
[84] | SHI C, DUAN D, JIA Y, et al. A highly efficient solvent system containing ionic liquid in tributyl phosphate for lithium ion extraction[J]. J. Mol. Liq., 2014, 200:191-195. |
[85] | XING L, SONG J, LI Z, et al. Solvent stable nanoporous poly (ethylene-co-vinyl alcohol) barrier membranes for liquid-liquid extraction of lithium from a salt lake brine[J]. J. Membr. Sci., 2016, 520:596-606. |
[86] | SONG J, LI X M, ZHANG Y, et al. Hydrophilic nanoporous ion-exchange membranes as a stabilizing barrier for liquid-liquid membrane extraction of lithium ions[J]. J. Membr. Sci., 2014, 471(23):372-380. |
[87] | GAO D, YU X P, GUO Y, et al. Extraction of lithium from salt lake brine with triisobutyl phosphate in ionic liquid and kerosene[J]. Chem. Res. Chinese U., 2015, 31(4):621-626. |
[88] | SHI C, JING Y, XIAO J, et al. Solvent extraction of lithium from aqueous solution using non-fluorinated functionalized ionic liquids as extraction agents[J]. Sep. Purif. Technol., 2017, 172:473-479. |
[89] | 张绍成. 吸附法盐湖卤水提锂工艺试验[J]. 盐湖研究, 1997, 5(1):59-68. ZHANG S C. Experiment of lithium recovery from salt lake brine by adsorption[J]. J. Salt Lake Sci., 1997, 5(1):59-68. |
[90] | KOTSUPALO N P, RYABTSEV A D, POROSHINA I A, et al. Effect of structure on the sorption properties of chlorine-containing form of double aluminum lithium hydroxide[J]. Russ. J. Appl. Chem., 2013, 86(4):482-487. |
[91] | 张绍成, 马培华, 邓小川. 吸附法从盐湖卤水中提取锂的方法:1511964A[P]. 2004-07-14. ZHANG S C, MA P H, DENG X C. Methods for lithium recovery from salt lake brine:1511964A[P]. 2004-07-14. |
[92] | LEE J M, BAUMAN W C. Alumina compounds in ion exchange resins:US4381349[P]. 1983-04-26. |
[93] | BURBA J L. Crystalline 2-layer lithium-hydroxy aluminates:US4477367[P]. 1984-10-16. |
[94] | BAUMAN W C, LEE J M, BURBA Ⅲ J L. Crystalline lithium aluminates:US4348295[P]. 1982-09-07. |
[95] | BURBA J L, BAUMAN W C. Intercalations of crystalline lithium aluminates:US4812245[P]. 1989-03-14. |
[96] | LEE J M, BAUMAN W C. A method of leaching lithium values from a brine-contaminated resin/aluminate composite:EP0117316[P]. 1984-09-05. |
[97] | REPSHER W J, RAPSTEIN K T. Recovery of lithium from brine:US4291001[P]. 1981-09-22. |
[98] | LEE J M, BAUMAN W C. Recovery of lithium from brine:US4116856s[P]. 1978-09-26. |
[99] | LEE J M, BAUMAN W C. Recovery of lithium from brines:US4221767[P]. 1980-09-09. |
[100] | BAUMAN W C, BURBA Ⅲ J L. Recovery of lithium values from brines:US5389349[P]. 1995-02-14. |
[101] | FENG Q, KANOH H, OOI K. Manganese oxide porous crystals[J]. J. Mater. Chem., 1999, 9(2):319-333. |
[102] | OOI K, KATOH Y M, SHUNSAKU. Lithium-ion sieve property of λ-type manganese oxide[J]. Solvent Extr. Ion Exch., 1987, 5(3):561-572. |
[103] | ZHANG Q H, LI S P, SUN S Y, et al. LiMn2O4 spinel direct synthesis and lithium ion selective adsorption[J]. Chem. Eng. Sci., 2010, 65(1):169-173. |
[104] | 孙淑英, 张钦辉, 于建国. 尖晶石型LiMn2O4的水热合成及其锂吸附性能[J]. 过程工程学报, 2010, 1:185-189. SUN S Y, ZHANG Q H, YU J G. Hydrothermal synthesis and lithium adsorption properties of LiMn2O4 spinel[J]. J. Process Eng., 2010, 1:185-189. |
[105] | ÖZG R C. Preparation and characterization of LiMn2O4 ion-sieve with high Li+ adsorption rate by ultrasonic spray pyrolysis[J]. Solid State Ionics, 2010, 181(31/32):1425-1428. |
[106] | WU H M, TU J P, YUAN Y F, et al. One-step synthesis LiMn2O4 cathode by a hydrothermal method[J]. J. Power Sources, 2006, 161(2):1260-1263. |
[107] | JIANG C H, DOU S X, LIU H K, et al. Synthesis of spinel LiMn2O4 nanoparticles through one-step hydrothermal reaction[J]. J. Power Sources, 2007, 172(1):410-415. |
[108] | CHITRAKAR R, KANOH H, MIYAI Y, et al. A new type of manganese oxide (MnO2·0.5H2O) derived from Li1.6Mn1.6O4 and its lithium ion-sieve properties[J]. Chem. Mat., 2000, 12(10):3151-3157. |
[109] | CHITRAKAR R, KANOH H, MIYAI Y, et al. Recovery of lithium from seawater using manganese oxide adsorbent (H1.6Mn1.6O4) derived from Li1.6Mn1.6O4[J]. Ind. Eng. Chem. Res., 2001, 40:2054-2058. |
[110] | CHITRAKAR R, MAKITA Y, OOI K, et al. Selective uptake of lithium ion from brine by H1.33Mn1.67O4 and H1.6Mn1.6O4[J]. Chem. Lett., 2012, 41(12):1647-1649. |
[111] | CHITRAKAR R, SAKANE K, UMENO A, et al. Synthesis of orthorhombic LiMnO2 by solid-phase reaction under steam atmosphere and a study of its heat and acid[J]. J. Solid State Chem., 2002, 169(1):66-74. |
[112] | CHITRAKAR R, KANOH H, MIYAI Y, et al. Synthesis of o-LiMnO2 by microwave irradiation and study its heat treatment and lithium exchange[J]. J. Solid State Chem., 2002, 163(1):1-4. |
[113] | RYU T, SHIN J, LEE D H, et al. Development of multi-stage column for lithium recovery from an aqueous solution[J]. Hydrometallurgy, 2015, 157:39-43. |
[114] | YU Q Q, MORIOKA E, SASAKI K. Characterization of lithium ion sieve derived from biogenic Mn oxide[J]. Microporous Mesoporous Mat., 2013, 179(10):122-127. |
[115] | YU Q Q, SASAKI K. In situ X-ray diffraction investigation of the evolution of a nanocrystalline lithium-ion sieve from biogenic manganese oxide[J]. Hydrometallurgy, 2014, 150:253-258. |
[116] | SUN S, XIAO J, WANG J, et al. Synthesis and adsorption properties of Li1.6Mn1.6O4 by a combination of redox precipitation and solid-phase reaction[J]. Ind. Eng. Chem. Res., 2014, 53(40):15517-15521. |
[117] | XIAO J L, SUN S Y, WANG J, et al. Synthesis and adsorption properties of Li1.6Mn1.6O4 spinel[J]. Ind. Eng. Chem. Res., 2013, 52(34):11967-11973. |
[118] | ZHANG Q H, LI S P, SUN S Y, et al. Lithium selective adsorption on 1-D MnO2 nanostructure ion-sieve[J]. Adv. Powder Technol., 2009, 20(5):432-437. |
[119] | XIAO J L, NIE X Y, SUN S Y, et al. Lithium ion adsorption-desorption properties on spinel Li4Mn5O12 and pH-dependent ion-exchange model[J]. Adv. Powder Technol., 2015, 26(2):589-594. |
[120] | XIAO J L, SUN S Y, SONG X F, et al. Lithium ion recovery from brine using granulated polyacrylamide-MnO2 ion-sieve[J]. Chem. Eng. J., 2015, 279:659-666. |
[121] | SHI X, ZHOU D, ZHANG Z, et al. Synthesis and properties of Li1.6Mn1.6O4 and its adsorption application[J]. Hydrometallurgy, 2011, 110:99-106. |
[122] | 石西昌, 张志兵, 周喜诚, 等. MnO2·0.5H2O的固相法制备及其对Li的吸附动力学[J]. 中国有色金属学报, 2013, 11(22):3135-3143. SHI X C, ZHANG Z B, ZHOU X C, et al. Synthesis of MnO2·0.5H2O by solid method and its adsorption dynamics for Li+[J]. Chinese J. Nonferr. Metal, 2013, 11(22):3135-3143. |
[123] | 王禄, 马伟, 韩梅, 等. 高效锂离子筛吸附剂MnO2·0.5H2O的软化学合成及吸附性能研究[J]. 化学学报, 2007, 65(12):1135-1139. WANG L, MA W, HAN M, et al. Soft chemical synthesis and adsorption properties of MnO2·0.5H2O, a high performance ion sieve for lithium[J]. Acta Chim.Sinica, 2007, 65(12):1135-1139. |
[124] | 纪志永, 郭文娟, 袁俊生, 等. 基于Li1.6Mn1.6O4的锂离子筛分步合成及其吸附性能研究[J]. 河北工业大学学报, 2014, 1(43):45-49. JI Z Y, GUO W J, YUAN J S, et al. Study on preparation of lithium ion-sieve basing on Li1.6Mn1.6O4 with fractional steps and its adsorption properties[J]. J. Hebei U.Technol., 2014, 1(43):45-49. |
[125] | ZHANG Q H, LI S P, SUN S Y, et al. Lithium selective adsorption on low-dimensional titania nanoribbons[J]. Chem. Eng. Sci., 2010, 65(1):165-168. |
[126] | 钟辉. 偏钛酸型锂离子交换剂的交换性质及从气田卤水中提锂[J]. 应用化学, 2000, 17(3):307-309. ZHONG H. Property of H2TiO3 type ion-exchangers and extraction of lithium from brine of natural gas wells[J]. Chinese J. Appl. Chem., 2000, 17(3):307-309. |
[127] | 颜辉, 钟辉, 陈念. 新型锂吸附剂的制备研究[J]. 无机盐工业, 2014, 46(2):38-40. YAN H, ZHONG H, CHEN N. Preparation of new lithium adsorbents[J]. Inorg. Chem. Ind., 2014, 46(2):38-40. |
[128] | 董殿权, 张凤宝, 张国亮, 等. Li4Ti5O12的合成及对Li+的离子交换动力学[J]. 物理化学学报, 2007, 23(6):950-954. DONG D Q, ZHANG F B, ZHANG G L, et al. Synthesis of Li4Ti5O12 and its exchange kinetics with Li+[J]. Acta Phys. Chim. Sin., 2007, 23(6):950-954. |
[129] | JI Z Y, YANG F J, ZHAO Y Y, et al. Preparation of titanium-base lithium ionic sieve with sodium persulfate as eluent and its performance[J]. Chem. Eng. J., 2017, 328:768-775. |
[130] | CHITRAKAR R, MAKITA Y, OOI K. Magnesium-doped manganese oxide with lithium ion-sieve property:lithium adsorption from salt lake brine[J]. Bull. Chem. Soc. Jpn., 2013, 86(7):850-855. |
[131] | CHITRAKAR R, MAKITA Y, OOI K, et al. Synthesis of iron-doped manganese oxides with an ion-sieve property:lithium adsorption from bolivian brine[J]. Ind. Eng. Chem. Res., 2014, 53(9):3682-3688. |
[132] | 董殿权, 刘维娜, 刘亦凡. LiNi0.05Mn1.95O4的合成及其对Li+的离子交换热力学[J]. 物理化学学报, 2009, 25(7):1279-1284. DONG D Q, LIU W N, LIU Y F. Synthesis of LiNi0.05Mn1.95O4 and its ion-exchange thermodynamics for Li+[J]. Acta Phys. Chim. Sin., 2009, 25(7):1279-1284. |
[133] | 冯林永, 蒋训雄, 汪胜东, 等. 掺杂对锂离子筛吸附性能的影响[J]. 有色金属:冶炼部分, 2009, 6:31-33. FENG L Y, JIANG X X, WANG S D, et al. The adsorption performance of doped lithium ion sieve[J]. Nonferr. Metal, 2009, 6:31-33. |
[134] | 石西昌, 尹世豪, 唐天罡, 等. 锰钛系复合锂离子筛的制备及其吸附性能研究[J]. 材料导报, 2014, 8:13-16. SHI X C, YIN S H, TANG T G, et al. Preparation of manganese titanium composite lithium ion-sieve and research on absorptive property[J]. Mater. Rev., 2014, 8:13-16. |
[135] | ÖZMAL F, ERDO?AN Y. Li+ adsorption/desorption properties of lithium ion-sieves in aqueous solution and recovery of lithium from borogypsum[J]. J. Environ. Chem. Eng., 2015, 3(4):2670-2683. |
[136] | OOI K, MIYAI Y, KATOH S, et al. Lithium-ion insertion/extraction reaction with λ-MnO2 in the aqueous phase[J]. Chem. Lett., 1988, 1:989-992. |
[137] | YUAN J S, YIN H B, JI Z Y, et al. Effective recycling performance of Li+ extraction from spinel-type LiMn2O4 with persulfate[J]. Ind. Eng. Chem. Res., 2014, 53(23):9889-9896. |
[138] | JI Z Y, ZHAO M Y, YUAN J S, et al. Li+ Extraction from spinel-type LiMn2O4 in different eluents and Li+ insertion in the aqueous phase[J]. Solvent Extr. Ion Exch., 2016, 34(6):549-557. |
[139] | JI Z Y, ZHAO M Y, ZHAO Y Y, et al. Lithium extraction process on spinel-type LiMn2O4 and characterization based on the hydrolysis of sodium persulfate[J]. Solid State Ionics, 2017, 301:116-124. |
[140] | 杨建元, 程温莹, 邓天龙, 等. 东台吉乃尔湖晶间卤水综合利用研究(煅烧法提锂工艺)[J]. 无机盐工业, 1996, 2:29-32. YANG J Y, CHENG W Y, DENG T L, et al. Study on the comprehensive utilization of intercrystalline brine of East Taijinar salt lake (calcination method)[J]. Inorg. Chem. Ind., 1996, 2:29-32. |
[141] | 杨建元, 程温莹, 张勇, 等. 东台吉乃尔湖晶间卤水综合利用途径研究[J]. 矿物岩石, 1995, 15(2):81-85. YANG J Y, CHENG W Y, ZHANG Y, et al. Study on the comprehensive utilization of intercrystalline brine of East Taijinar salt lake[J]. J. Mineral. Petr., 1995, 15(2):81-85. |
[142] | 郑绵平, 卜令忠, 邓月金, 等. 利用太阳池从碳酸盐型卤水中结晶析出碳酸锂的方法:1398786[P]. 2003-02-26. ZHENG M P, PU L Z, DENG Y J, et al. Methods for lithium carbonate crystallization from sulfate type brine using solar pond:1398786[P]. 2003-02-26. |
[143] | 赵元艺, 郑绵平, 卜令忠, 等. 西藏碳酸盐型盐湖卤水锂盐提取盐田工艺研究[J]. 盐业与化工, 2005, 34(2):1-6. ZHAO Y Z, ZHENG M P, PU L Z, et al. Study on salt pan technology of lithium salt extracting from carbonate-type saline lakes, Tibet[J]. Sea-lake Salt Chem. Ind., 2005, 34(2):1-6. |
[144] | 郝勇, 张启海, 李广汉, 等. 西藏结则茶卡和龙木错盐湖卤水协同提锂研究[J]. 无机盐工业, 2013, 45(6):27-29. HAO Y, ZHANG Q H, LI G H, et al. Study on salt pan technology of lithium salt extracting from carbonate-type saline lakes Tibet[J]. Inorg. Chem. Ind., 2013, 45(6):27-29.Hydrometallurgy. 2016, 164:362-371. |
[73] | KATAYAMA Y, FUKUDA R, IWASAKI T, et al. Synthesis of chromogenic crown ethers and liquid-liquid extraction of alkaline earth metal ions[J]. Anal. Chim. Acta. 1988, 204(JUL):113-125. |
[74] | ITOH T, BILLAH M, HONJO T, et al. Separation and determination of a trace amount of lithium as its thenoyltrifluoroacetone complex with 12crown4 by means of synergic extraction and flame photometry[J]. Anal. Sci. 1991, 7(Supple):47-50. |
[75] | HABATA Y, IKEDA M, AKABORI S. Lithium ion selective dibenzo-14-crown-4 possessing a phosphoric acid functional group as a pendant[J]. Cheminform. 1992, 23(47):3157-3160. |
[76] | CZECH B P, BABB D A, SON B, et al. Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds:synthesis and lithium ion complexation[J]. Cheminform. 1984, 49:25(19):4805-4810. |
[77] | BOULATOV R, DU B, MEYERS E A, et al. Two Novel Lithium-15-Crown-5 Complexes:An Extended LiCl Chain Stabilized by Crown Ether and a Dimeric Complex Stabilized by Hydrogen Bonding with Water[J]. Inorg. Chem. 1999, 38(20):4554. |
[78] | BARTSCH R A, GOO M J, CHRISTIAN G D, et al. Influence of ring substituents and matrix on lithium/sodium selectivity of 14-crown-4 and benzo-13-crown-4-compounds[J]. Anal. Chim. Acta. 1993, 272(2):285-292. |
[79] | BARTSCH R A, CZECH B P, KANG S I, et al. ChemInform Abstract:High lithium selectivity in competitive alkali metal solvent extraction by lipophilic crown carboxylic acids[J]. Chem. Inf. 1985, 16(49):4997-4998. |
[80] | JI L, LI L, SHI D, et al. Extraction equilibria of lithium with N, N-bis(2-ethylhexyl)-3-oxobutanamide and tributyl phosphate in kerosene and FeCl3[J]. Hydrometallurgy. 2016, 164:304-312. |
[81] | JI L, HU Y, LI L, et al. Lithium Extraction with a Synergistic System of Dioctyl Phthalate and Tributyl Phosphate in Kerosene and FeCl3[J]. Hydrometallurgy. 2016, 162:71-78. |
[82] | SHI C, JING Y, JIA Y. Solvent extraction of lithium ions by tri-n-butyl phosphate using a room temperature ionic liquid[J]. J. Mol. Liq. 2016, 215:640-646. |
[83] | SHI C, JIA Y, ZHANG C, et al. Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate[J]. Fusion. Eng. Des. 2015, 90:1-6. |
[84] | SHI C, DUAN D, JIA Y, et al. A highly efficient solvent system containing ionic liquid in tributyl phosphate for lithium ion extraction[J]. J. Mol. Liq. 2014, 200:191-195. |
[85] | XING L, SONG J, LI Z, et al. Solvent stable nanoporous poly (ethylene-co-vinyl alcohol) barrier membranes for liquid-liquid extraction of lithium from a salt lake brine[J]. J. Membr. Sci. 2016, 520:596-606. |
[86] | SONG J, LI X M, ZHANG Y, et al. Hydrophilic nanoporous ion-exchange membranes as a stabilizing barrier for liquid-liquid membrane extraction of lithium ions[J]. J. Membr. Sci. 2014, 471(23):372-380. |
[87] | GAO D, XIAOPING Y U, GUO Y, et al. Extraction of Lithium from Salt Lake Brine with Triisobutyl Phosphate in Ionic Liquid and Kerosene[J]. Chem. Res. Chinese U. 2015, 31(4):621-626. |
[88] | SHI C, JING Y, XIAO J, et al. Solvent extraction of lithium from aqueous solution using non-fluorinated functionalized ionic liquids as extraction agents[J]. Sep. Purif. Technol. 2017, 172:473-479. |
[89] | 张绍成. 吸附法盐湖卤水提锂工艺试验[J]. 盐湖研究. 1997, 5(1):59-68. ZHANG S C. Experiment of lithium recovery from salt lake brine by adsorption[J]. J. Salt Lake Sci. 1997, 5(1):59-68. |
[90] | KOTSUPALO N P, RYABTSEV A D, POROSHINA I A, et al. Effect of structure on the sorption properties of chlorine-containing form of double aluminum lithium hydroxide[J]. Russ. J. Appl. Chem. 2013, 86(4):482-487. |
[91] | 张绍成, 马培华, 邓小川. 吸附法从盐湖卤水中提取锂的方法[P]. CN1511964A. 2006. ZHANG S C, MA P H, DENG X C. Methods for lithium recovery from salt lake brine[P]. CN1511964A. 2006. |
[92] | LEE J M, BAUMAN W C. Alumina compounds in ion exchange resins[P]. US4381349, 1983. |
[93] | BURBA J L. Crystalline 2-layer lithium-hydroxy aluminates[P]. U4477367, 1984. |
[94] | BAUMAN W C, LEE J M, BURBA Ⅲ J L. Crystalline lithium aluminates[P]. US4348295, 1982. |
[95] | BURBA J L, BAUMAN W C. Intercalations of crystalline lithium aluminates[P]. US4812245, 1989. |
[96] | LEE J M, BAUMAN W C. A method of leaching lithium values from a brine-contaminated resin/aluminate composite[P]. EP0117316, 1984. |
[97] | REPSHER W J, RAPSTEIN K T. Recovery of lithium from brine[P]. US4291001, 1981. |
[98] | LEE J M, BAUMAN W C. Recovery of lithium from brines[P]. US4116856, 1978. |
[99] | LEE J M, BAUMAN W C. Recovery of lithium from brines[P]. US4221767, 1980. |
[100] | BAUMAN W C, BURBA Ⅲ J L. Recovery of lithium values from brines[P]. US5389349, 1995. |
[101] | FENG Q, KANOH H, OOI K. Manganese oxide porous crystals[J]. J, Mater, Chem,. 1999, 9(2):319-333. |
[102] | OOI K, KATOH Y M, SHUNSAKU. Lithium-ion sieve property of λ-type manganese oxide[J]. Solvent Extr. Ion Exch. 1987, 5(3):561-572. |
[103] | ZHANG Q H, LI S P, SUN S Y, et al. LiMn2O4 spinel direct synthesis and lithium ion selective adsorption[J]. Chem. Eng. Sci. 2010, 65(1):169-173. |
[104] | 孙淑英, 张钦辉, 于建国. 尖晶石型LiMn2O4的水热合成及其锂吸附性能[J]. 过程工程学报. 2010, (01):185-189. SUN S Y, ZHANG Q H, YU J G. Hydrothermal Synthesis and Lithium Adsorption Properties of LiMn2O4 Spinel[J]. J. Process Eng. 2010, (01):185-189. |
[105] | ÖZG R C. Preparation and characterization of LiMn2O4 ion-sieve with high Li+ adsorption rate by ultrasonic spray pyrolysis[J]. Solid State Ionics. 2010, 181(31-32):1425-1428. |
[106] | WU H M, TU J P, YUAN Y F, et al. One-step synthesis LiMn2O4 cathode by a hydrothermal method[J]. J. Power Sources. 2006, 161(2):1260-1263. |
[107] | JIANG C H, DOU S X, LIU H K, et al. Synthesis of spinel LiMn2O4 nanoparticles through one-step hydrothermal reaction[J]. J. Power Sources. 2007, 172(1):410-415. |
[108] | CHITRAKAR R, KANOH H, MIYAI Y, et al. A New Type of Manganese Oxide MnO2·0.5H2O) Derived from Li1.6Mn1.6O4 and Its Lithium Ion-sieve Properties[J]. Chem. Mat. 2000, 12(10):3151-3157. |
[109] | CHITRAKAR R, KANOH H, MIYAI Y, et al. Recovery of lithium from seawater using manganese oxide adsorbent (H1.6Mn1.6O4) derived from Li1.6Mn1.6O4[J]. Ind. Eng. Chem. Res. 2001, 40:2054-2058. |
[110] | CHITRAKAR R, MAKITA Y, OOI K, et al. Selective Uptake of Lithium Ion from Brine by H1.33Mn1.67O4 and H1.6Mn1.6O4[J]. Chem. Lett. 2012, 41(12):1647-1649. |
[111] | CHITRAKAR R, SAKANE K, UMENO A, et al. Synthesis of orthorhombic LiMnO2 by solid-phase reaction under steam atmosphere and a study of its heat and acid[J]. J. Solid State Chem. 2002, 169(1):66-74. |
[112] | CHITRAKAR R, KANOH H, MIYAI Y, et al. Synthesis of o-LiMnO2 by Microwave Irradiation and StudyIts Heat Treatment and Lithium Exchange[J]. J. Solid State Chem. 2002, 163(1):1-4. |
[113] | RYU T, SHIN J, LEE D H, et al. Development of multi-stage column for lithium recovery from an aqueous solution[J]. Hydrometallurgy. 2015, 157:39-43. |
[114] | YU Q Q, MORIOKA E, SASAKI K. Characterization of lithium ion sieve derived from biogenic Mn oxide[J]. Microporous Mesoporous Mat. 2013, 179(10):122-127. |
[115] | YU Q Q, SASAKI K. In situ X-ray diffraction investigation of the evolution of a nanocrystalline lithium-ion sieve from biogenic manganese oxide[J]. Hydrometallurgy. 2014, 150:253-258. |
[116] | SUN S, XIAO J, WANG J, et al. Synthesis and Adsorption Properties of Li1.6Mn1.6O4 by a Combination of Redox Precipitation and Solid-Phase Reaction[J]. Ind. Eng. Chem. Res. 2014, 53(40):15517-15521. |
[117] | XIAO J L, SUN S Y, WANG J, et al. Synthesis and Adsorption Properties of Li1.6Mn1.6O4 Spinel[J]. Ind. Eng. Chem. Res. 2013, 52(34):11967-11973. |
[118] | ZHANG Q H, LI S P, SUN S Y, et al. Lithium selective adsorption on 1-D MnO2 nanostructure ion-sieve[J]. Adv. Powder Technol. 2009, 20(5):432-437. |
[119] | XIAO J L, NIE X Y, SUN S Y, et al. Lithium ion adsorption-desorption properties on spinel Li4Mn5O12 and pH-dependent ion-exchange model[J]. Adv. Powder Technol. 2015, 26(2):589-594. |
[120] | XIAO J L, SUN S Y, SONG X F, et al. Lithium ion recovery from brine using granulated polyacrylamide-MnO2 ion-sieve[J]. Chem. Eng. J. 2015, 279:659-666. |
[121] | SHI X, ZHOU D, ZHANG Z, et al. Synthesis and properties of Li1.6Mn1.6O4 and its adsorption application[J]. Hydrometallurgy. 2011, 110(1-4):99-106. |
[122] | 石西昌, 张志兵, 周喜诚, 等. MnO2·0.5H2O的固相法制备及其对Li的吸附动力学[J]. 中国有色金属学报. 2013, 11(11):3135-3143. SHI X C, ZHANG Z B, ZHOU X C, et al. Synthesis of MnO2·0.5H2O by solid method and its adsorption dynamics for Li+[J]. Chinese J. Nonferr. Metal. 2013, 11(11):3135-3143. |
[123] | 王禄, 马伟, 韩梅, 等. 高效锂离子筛吸附剂MnO2·0.5H2O的软化学合成及吸附性能研究[J]. 化学学报. 2007, 12(12):1135-1139. WANG L, MA W, HAN M, et al. Soft Chemical Synthesis and Adsorption Properties of MnO2·0.5H2O, a High Performance Ion Sieve for Lithium[J]. Acta Chim.Sinica. 2007, 12(12):1135-1139. |
[124] | 纪志永, 郭文娟, 袁俊生, 等. 基于Li1.6Mn1.6O4的锂离子筛分步合成及其吸附性能研究[J]. 河北工业大学学报. 2014, 1(1):45-49. JI Z Y, GUO W J, YUAN J S, et al. Study on preparation of lithium ion-sieve basing on Li1.6Mn1.6O4 with fractional steps and its adsorption properties[J]. J. Hebei U.Technol. 2014, 1(1):45-49. |
[125] | ZHANG Q H, LI S P, SUN S Y, et al. Lithium selective adsorption on low-dimensional titania nanoribbons[J]. Chem. Eng. Sci. 2010, 65(1):165-168. |
[126] | JI Z Y, YANG F J, ZHAO Y Y, et al. Preparation of titanium-base lithium ionic sieve with sodium persulfate as eluent and its performance[J]. Chem. Eng. J. 2017, 328:768-775. |
[127] | CHITRAKAR R, MAKITA Y, OOI K. Magnesium-Doped Manganese Oxide with Lithium Ion-Sieve Property:Lithium Adsorption from Salt Lake Brine[J]. Bull. Chem. Soc. Jpn. 2013, 86(7):850-855. |
[128] | CHITRAKAR R, MAKITA Y, OOI K, et al. Synthesis of Iron-Doped Manganese Oxides with an Ion-Sieve Property:Lithium Adsorption from Bolivian Brine[J]. Ind. Eng. Chem. Res. 2014, 53(9):3682-3688. |
[129] | 董殿权, 刘维娜, 刘亦凡. LiNi0.05Mn1.95O4的合成及其对Li+的离子交换热力学[J]. 物理化学学报. 2009, 7(7):1279-1284. DONG D Q, LIU W N, LIU Y F. Synthesis of LiNi0.05Mn1.95O4 and its ion-exchange thermodynamics for Li+[J]. Acta Phys. -Chim. Sin. 2009, 7(7):1279-1284. |
[130] | 冯林永, 蒋训雄, 汪胜东, 等. 掺杂对锂离子筛吸附性能的影响[J]. 有色金属:冶炼部分. 2009, 0(06):31-33. FENG L Y, JIANG X X, WANG S D, et al. The Adsorption Performance of Doped Lithium Ion Sieve[J]. Nonferr. metal. 2009, 0(06):31-33. |
[131] | 石西昌, 尹世豪, 唐天罡, 等. 锰钛系复合锂离子筛的制备及其吸附性能研究[J]. 材料导报. 2014, 8:13-16. SHI X C, YIN S H, TANG T G, et al. Preparation of manganese titanium composite lithium ion-sieve and research on absorptive property[J]. Mater. Rev. 2014, 8:13-16. |
[132] | ÖZMAL F, ERDO?AN Y. Li+ adsorption/desorption properties of lithium ion-sieves in aqueous solution and recovery of lithium from borogypsum[J]. J. Environ. Chem. Eng. 2015, 3(4):2670-2683. |
[133] | OOI K, MIYAI Y, KATOH S, et al. Lithium-ion insertion/extraction reaction with λ-MnO2 in the aqueous phase[J]. Chem. Lett. 1988:989-992. |
[134] | YUAN J S, YIN H B, JI Z Y, et al. Effective Recycling Performance of Li+ Extraction from Spinel-Type LiMn2O4 with Persulfate[J]. Ind. Eng. Chem. Res. 2014, 53(23):9889-9896. |
[135] | JI Z Y, ZHAO M Y, YUAN J S, et al. Li+ Extraction from Spinel-Type LiMn2O4 in Different Eluents and Li+ Insertion in the Aqueous Phase[J]. Solvent Extr. Ion Exch. 2016, 34(6):549-557. |
[136] | JI Z Y, ZHAO M Y, ZHAO Y Y, et al. Lithium extraction process on spinel-type LiMn2O4 and characterization based on the hydrolysis of sodium persulfate[J]. Solid State Ionics. 2017, 301:116-124. |
[137] | 杨建元, 程温莹, 邓天龙, 等. 东台吉乃尔湖晶间卤水综合利用研究(煅烧法提锂工艺)[J]. 无机盐工业. 1996, (2):29-32. YANG J Y, CHENG W Y, DENG T L, et al. Study on the comprehensive utilization of intercrystalline brine of East Taijinar salt lake (Calcination method)[J]. Inorg. Chem. Ind. 1996, (2):29-32. |
[138] | 杨建元, 程温莹, 张勇, 等. 东台吉乃尔湖晶间卤水综合利用途径研究[J]. 矿物岩石. 1995, 15(2):81-85. YANG J Y, CHENG W Y, ZHANG Y, et al. Study on the comprehensive utilization of intercrystalline brine of East Taijinar salt lake[J]. J. Mineral. Petr. 1995, 15(2):81-85. |
[139] | 郑绵平, 卜令忠, 邓月金, 等. 利用太阳池从碳酸盐型卤水中结晶析出碳酸锂的方法[P]. CN1398786. 2003. ZHENG M P, PU L Z, DENG Y J, et al. Methods for lithium carbonate crystallization from sulfate type brine using solar pond[P]. CN1398786. 2003. |
[140] | 赵元艺, 郑绵平, 卜令忠, 等. 西藏碳酸盐型盐湖卤水锂盐提取盐田工艺研究[J]. 盐业与化工. 2005, 34(02):1-6. ZHAO Y Z, ZHENG M P, PU L Z, et al. Study on salt pan technology of lithium salt extracting from carbonate-type saline lakes, Tibet[J]. Sea-lake Salt Chem. Ind. 2005, 34(02):1-6. |
[141] | 郝勇, 张启海, 李广汉, 等. 西藏结则茶卡和龙木错盐湖卤水协同提锂研究[J]. 无机盐工业. 2013, 45(06):27-29. HAO Y, ZHANG Q H, LI G H, et al. Study on Salt Pan Technology of Lithium Salt Extracting from Carbonate-type Saline Lakes Tibet[J]. Inorg. Chem. Ind. 2013, 45(06):27-29. |
[1] | 邵苛苛, 宋孟杰, 江正勇, 张旋, 张龙, 高润淼, 甄泽康. 水平方向上冰中受陷气泡形成和分布实验研究[J]. 化工学报, 2023, 74(S1): 161-164. |
[2] | 吴延鹏, 李晓宇, 钟乔洋. 静电纺丝纳米纤维双疏膜油性细颗粒物过滤性能实验分析[J]. 化工学报, 2023, 74(S1): 259-264. |
[3] | 晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310. |
[4] | 李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840. |
[5] | 王俐智, 杭钱程, 郑叶玲, 丁延, 陈家继, 叶青, 李进龙. 离子液体萃取剂萃取精馏分离丙酸甲酯+甲醇共沸物[J]. 化工学报, 2023, 74(9): 3731-3741. |
[6] | 宋明昊, 赵霏, 刘淑晴, 李国选, 杨声, 雷志刚. 离子液体脱除模拟油中挥发酚的多尺度模拟与研究[J]. 化工学报, 2023, 74(9): 3654-3664. |
[7] | 杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH3的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755. |
[8] | 胡建波, 刘洪超, 胡齐, 黄美英, 宋先雨, 赵双良. 有机笼跨细胞膜易位行为的分子动力学模拟研究[J]. 化工学报, 2023, 74(9): 3756-3765. |
[9] | 齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930. |
[10] | 何松, 刘乔迈, 谢广烁, 王斯民, 肖娟. 高浓度水煤浆管道气膜减阻两相流模拟及代理辅助优化[J]. 化工学报, 2023, 74(9): 3766-3774. |
[11] | 胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521. |
[12] | 张佳怡, 何佳莉, 谢江鹏, 王健, 赵鹬, 张栋强. 渗透汽化技术用于锂电池生产中N-甲基吡咯烷酮回收的研究进展[J]. 化工学报, 2023, 74(8): 3203-3215. |
[13] | 盛冰纯, 于建国, 林森. 铝基锂吸附剂分离高钠型地下卤水锂资源过程研究[J]. 化工学报, 2023, 74(8): 3375-3385. |
[14] | 张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393. |
[15] | 高燕, 伍鹏, 尚超, 胡泽君, 陈晓东. 基于双流体喷嘴的磁性琼脂糖微球的制备及其蛋白吸附性能探究[J]. 化工学报, 2023, 74(8): 3457-3471. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||