热再生电池氨再生过程强化

doi:10.11949/0438-1157.20200487

化工学报 ›› 2020, Vol. 71 ›› Issue (S2): 253-258.DOI: 10.11949/0438-1157.20200487

热再生电池氨再生过程强化

石雨^1,²(),张亮^1,²(),李俊^1,²,付乾^1,²,朱恂^1,²,廖强^1,²,陈鹏宇^1,²

^1.重庆大学能源与动力工程学院，重庆 400030
^2.重庆大学工程热物理研究所，重庆 400030

收稿日期:2020-05-06 修回日期:2020-05-08 出版日期:2020-11-06 发布日期:2020-11-06
通讯作者: 张亮
作者简介:石雨（1996—），男，硕士研究生，cquietp2018shiyu@hotmail.com
基金资助:
国家自然科学基金面上项目(51976018);国家自然科学基金青年项目(51606022);重庆市基础科学与前沿技术项目(cstc2017jcyjAX0203);重庆市留学人员创业创新支持计划创新资助重点项目(cx2017020);中央高校基本科研业务费(10611 2016CDJXY 145504);低品位能源利用技术及系统教育部重点实验室固定人员科研基金项目(LLEUTS-2018005)

Enhanced ammonia regeneration of thermal regenerated batteries

Yu SHI^1,²(),Liang ZHANG^1,²(),Jun LI^1,²,Qian FU^1,²,Xun ZHU^1,²,Qiang LIAO^1,²,Pengyu CHEN^1,²

^1.School of Energy and Power Engineering, Chongqing University, Chongqing 400030, China
^2.Institute of Engineering Thermophysics, Chongqing University, Chongqing 400030, China

Received:2020-05-06 Revised:2020-05-08 Online:2020-11-06 Published:2020-11-06
Contact: Liang ZHANG

摘要/Abstract

摘要：

利用低温热能的热再生过程是热再生电池（thermally regenerative battery，TRB）系统的重要组成之一，针对TRB的产电和热再生过程，研究了使用再生电解液的TRB产电性能以及温度和强化传热传质措施对热再生过程的影响。研究结果表明，产电过程中，使用再生电解液的TRB最大功率为5.7 mW，比初始电解液的TRB（最大功率为6.5 mW）低14%；热再生过程中，提高温度可以明显强化热再生过程，采用玻璃球床和搅拌措施也可以有效提高热再生过程的性能。

关键词: 热再生氨电池, 电化学, 最大功率, 传质, 传热

Abstract:

Regeneration using low-grade thermal energy is one of the most important components of the thermal regenerative battery (TRB) system. In this study, the effects of the regenerative electrolyte on the performance of TRB and the effects of temperature and mass transfer on the thermal regeneration are studied. The experimental results showed that the maximum power of TRB using regenerated electrolyte was 5.7 mW, which was 14% lower than that of TRB using initial electrolyte (6.5 mW). In the process of thermal regeneration, the increasing of temperature can obviously strengthen the process of thermal regeneration, and the performance of thermal regeneration can also be effectively improved by using glass balls bed and stirring.

Key words: thermal regenerative ammonia-based battery, electrochemistry, maximum power, mass transfer, heat transfer

中图分类号:

X 703.1

石雨, 张亮, 李俊, 付乾, 朱恂, 廖强, 陈鹏宇. 热再生电池氨再生过程强化[J]. 化工学报, 2020, 71(S2): 253-258.

Yu SHI, Liang ZHANG, Jun LI, Qian FU, Xun ZHU, Qiang LIAO, Pengyu CHEN. Enhanced ammonia regeneration of thermal regenerated batteries[J]. CIESC Journal, 2020, 71(S2): 253-258.

图/表 4

图1 阳极液pH与氨浓度关系

Fig.1 Relationship between pH value of anode solution and ammonia concentration

图2 再生电极液pH变化(a)；功率曲线和极化曲线(b)；阴极电势和阳极电势(c)

Fig.2 pH variation of regenerated electrode solution (a); power generation and polarization curve (b); cathode and anode potential (c)

图3 温度对再生阴极液pH的影响

Fig.3 Effect of temperature on pH of regenerated cathode solution

图4 强化传热传质措施对再生阴极液pH的影响

Fig.4 Effect of enhanced heat and mass transfer measures on pH of regenerated cathode liquid

参考文献 31

1	Yang Y, Lee S W, Ghasemi H, et al. Charging-free electrochemical system for harvesting low-grade thermal energy [J]. Proc. Natl. Acad. Sci. U. S. A., 2014, 111(48): 17011-17016.
2	Brogioli D, La Mantia F, Yip N Y. Energy efficiency analysis of distillation for thermally regenerative salinity gradient power technologies [J]. Renew. Energy, 2019, 133: 1034-1045.
3	Fu J, Cano Z P, Park M G, et al. Electrically rechargeable zinc-air batteries: progress, challenges, and perspectives [J]. Adv. Mater., 2017, 29(7): 1604685.
4	Lu H Y, Price L, Zhang Q. Capturing the invisible resource: analysis of waste heat potential in Chinese industry [J]. Appl. Energ., 2016, 161: 497-511.
5	Chu S, Najumdar A. Opportunities and challenges for a sustainable energy future [J]. Nature, 2012, 488(7411): 294-303.
6	Garone S, Toppi T, Guerra M, et al. A water-ammonia heat transformer to upgrade low-temperature waste heat [J]. Appl. Therm. Eng., 2017, 127: 748-757.
7	Olkis C, Santori G, Brandani S. An adsorption reverse electrodialysis system for the generation of electricity from low-grade heat [J]. Appl. Energ., 2018, 231: 222-234.
8	Bell L E. Cooling, heating, generating power, and recovering waste heat with thermoelectric systems [J]. Science, 2008, 321(5895): 1457-1461.
9	Xu W C, Zhang J Y, Zhao L, et al. Novel experimental research on the compression process in organic Rankine cycle (ORC) [J]. Energy Convers. Manage., 2017, 137: 1-11.
10	Sanchez D, Munoz de Escalona J M, Monje B, et al. Preliminary analysis of compound systems based on high temperature fuel cell, gas turbine and organic Rankine cycle [J]. J. Power Sources, 2011, 196(9): 4355-4363.
11	MacLeod B A, Stanton N J, Gould I E, et al. Large n- and p-type thermoelectric power factors from doped semiconducting single-walled carbon nanotube thin films [J]. Energy Environ. Sci., 2017, 10(10): 2168-2179.
12	Karalis G, Tzounis L, Lambrou E, et al. A carbon fiber thermoelectric generator integrated as a lamina within an 8-ply laminate epoxy composite: efficient thermal energy harvesting by advanced structural materials [J]. Appl. Energ., 2019, 253: 113512.
13	Hu R C, Cola B A, Haram H, et al. Harvesting waste thermal energy using carbon-nanotube-based thermo-electrochemical cell [J]. Nano Lett., 2010, 10(3): 838-846.
14	Rahimi M, Straub A P, Zhang F, et al. Emerging electrochemical and membrane-based systems to convert low-grade heat to electricity [J]. Energy Environ. Sci., 2018, 11(2): 276-285.
15	Luo Y, Andresen J, Clarke H, et al. A decision support system for waste heat recovery and energy efficiency improvement in data centres [J]. Appl. Energ., 2019, 250: 1217-1224.
16	Rahimi M, Schoener Z, Zhu X P, et al. Removal of copper from water using a thermally regenerative electrodeposition battery [J]. Journal of Hazardous Materials, 2016, 322: 551-556.
17	Zhang F, Liu J, Yang W L, et al. A thermally regenerative ammonia-based battery for efficient harvesting of low-grade thermal energy as electrical power [J]. Energy & Environmental Science, 2015, 8(1): 343-349.
18	Rahimi M, D'Angelo A, Gorski C A, et al. Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery [J]. J. Power Sources, 2017, 351: 45-50.
19	唐志强, 张亮, 朱恂, 等. 不同Cu²⁺浓度下热再生氨电池产电及Cu²⁺去除特性[J]. 化工学报, 2019, 70(12): 4804-4810.
	Tang Z Q, Zhang L, Zhu X, et al. Effect of Cu²⁺ concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery [J]. CIESC Journal, 2019, 70(12): 4804-4810.
20	Zhang F, LaBarge N, Yang W L, et al. Enhancing low-grade thermal energy recovery in a thermally regenerative ammonia battery using elevated temperatures [J]. ChemSusChem, 2015, 8(6): 1043-1048.
21	Zhu X P, Rahimi M, Gorski C, al et, A thermally-regenerative ammonia-based flow battery for electrical energy recovery from waste heat [J]. ChemSusChem, 2016, 9(8): 873-879.
22	Rahimi M, Zhu L, Kowalski K, et al. Improved electrical power production of thermally regenerative batteries using a poly (phenylene oxide) based anion exchange membrane [J]. Journal of Power Sources, 2017, 342: 956-963.
23	Rahimi M, Kim T, Gorski C A, et al. A thermally regenerative ammonia battery with carbon-silver electrodes for converting low-grade waste heat to electricity [J]. J. Power Sources, 2018, 373: 95-102.
24	Wang W G, Shu G Q, Tian H, et al. A bimetallic thermally-regenerative ammonia-based flow battery for low-grade waste heat recovery [J]. J. Power Sources, 2019, 424: 184-192.
25	Wang W G, Tian H, Shu G Q, et al. A bimetallic thermally regenerative ammonia-based battery for high power density and efficiently harvesting low-grade thermal energy [J]. J. Mater. Chem. A, 2019, 7(11): 5991-6000.
26	Zhang L, Li Y X, Zhu X, et al. Copper foam electrodes for increased power generation in thermally regenerative ammonia-based batteries for low-grade waste heat recovery [J]. Industrial & Engineering Chemistry Research, 2019, 58(17): 7408-7415.
27	Zhang Y S, Zhang L, Li J, et al. Performance of a thermally regenerative ammonia-based flow battery with 3D porous electrodes: effect of reactor and electrode design [J]. Electrochim. Acta, 2020, 331: 135442.
28	Vicari F, D􀆳Angelo A, Kouko Y,et al. On the regeneration of thermally regenerative ammonia batteries [J]. Journal of Applied Electrochemistry,2018, 48(12): 1381-1388.
29	李彦翔, 张亮, 朱恂, 等. 传质对热可再生氨电池性能的影响[J]. 工程热物理学报, 2019, 40(3): 668-671.
	Li Y X, Zhang L, Zhu X, et al. Effect of mass transfer on the performance of membrane electrode assembly typed thermally regenerative ammonia-based battery [J]. Journal of Engineering Thermophysics, 2019, 40(3): 668-671.
30	EL-Bourawi M S, Khayet M, Ma R, et al. Application of vacuum membrane distillation for ammonia removal [J]. Journal of Membrane Science, 2007, 301(1/2): 200-209.
31	Chang Y H, Ferng Y M. Experimental investigation on bubble dynamics and boiling heat transfer for saturated pool boiling and comparison data with previous works [J]. Applied Thermal Engineering, 2019, 154: 284.

[1]	张双星, 刘舫辰, 张义飞, 杜文静. R-134a脉动热管相变蓄放热实验研究[J]. 化工学报, 2023, 74(S1): 165-171.
[2]	张义飞, 刘舫辰, 张双星, 杜文静. 超临界二氧化碳用印刷电路板式换热器性能分析[J]. 化工学报, 2023, 74(S1): 183-190.
[3]	陈爱强, 代艳奇, 刘悦, 刘斌, 吴翰铭. 基板温度对HFE7100液滴蒸发过程的影响研究[J]. 化工学报, 2023, 74(S1): 191-197.
[4]	刘明栖, 吴延鹏. 导光管直径和长度对传热影响的模拟分析[J]. 化工学报, 2023, 74(S1): 206-212.
[5]	王志国, 薛孟, 董芋双, 张田震, 秦晓凯, 韩强. 基于裂隙粗糙性表征方法的地热岩体热流耦合数值模拟与分析[J]. 化工学报, 2023, 74(S1): 223-234.
[6]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[7]	程成, 段钟弟, 孙浩然, 胡海涛, 薛鸿祥. 表面微结构对析晶沉积特性影响的格子Boltzmann模拟[J]. 化工学报, 2023, 74(S1): 74-86.
[8]	李艺彤, 郭航, 陈浩, 叶芳. 催化剂非均匀分布的质子交换膜燃料电池操作条件研究[J]. 化工学报, 2023, 74(9): 3831-3840.
[9]	王玉兵, 李杰, 詹宏波, 朱光亚, 张大林. R134a在菱形离散肋微小通道内的流动沸腾换热实验研究[J]. 化工学报, 2023, 74(9): 3797-3806.
[10]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[11]	齐聪, 丁子, 余杰, 汤茂清, 梁林. 基于选择吸收纳米薄膜的太阳能温差发电特性研究[J]. 化工学报, 2023, 74(9): 3921-3930.
[12]	李科, 文键, 忻碧平. 耦合蒸气冷却屏的真空多层绝热结构对液氢储罐自增压过程的影响机制研究[J]. 化工学报, 2023, 74(9): 3786-3796.
[13]	陈天华, 刘兆轩, 韩群, 张程宾, 李文明. 喷雾冷却换热强化研究进展及影响因素[J]. 化工学报, 2023, 74(8): 3149-3170.
[14]	胡亚丽, 胡军勇, 马素霞, 孙禹坤, 谭学诣, 黄佳欣, 杨奉源. 逆电渗析热机新型工质开发及电化学特性研究[J]. 化工学报, 2023, 74(8): 3513-3521.
[15]	杨越, 张丹, 郑巨淦, 涂茂萍, 杨庆忠. NaCl水溶液喷射闪蒸-掺混蒸发的实验研究[J]. 化工学报, 2023, 74(8): 3279-3291.

热再生电池氨再生过程强化

Enhanced ammonia regeneration of thermal regenerated batteries

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 4

参考文献 31

相关文章 15

编辑推荐

Metrics

本文评价