化工学报 ›› 2021, Vol. 72 ›› Issue (S1): 421-429.DOI: 10.11949/0438-1157.20201315

• 分离工程 • 上一篇    下一篇

聚偏氟乙烯膜亲水改性及其乳液分离与重金属吸附应用

吴中杰1(),刘则艳2,谢连科1,崔美2,黄仁亮2()   

  1. 1.国网山东省电力公司电力科学研究院,山东 济南 250002
    2.天津大学海洋科学与技术学院,天津 300072
  • 收稿日期:2020-09-17 修回日期:2020-10-10 出版日期:2021-06-20 发布日期:2021-06-20
  • 通讯作者: 黄仁亮
  • 作者简介:吴中杰(1987—),男,博士研究生,414699594@qq.com
  • 基金资助:
    国家电网公司科学技术项目(520626190015);国家自然科学基金项目(21976132)

Preparation of hydrophilic poly(vinylidene fluoride) membrane for oil/water emulsion separation and heavy metal ions adsorption

WU Zhongjie1(),LIU Zeyan2,XIE Lianke1,CUI Mei2,HUANG Renliang2()   

  1. 1.Shandong Electric Power Research Institute of Chinese Power Company, Jinan 250002, Shandong, China
    2.School of Marine Science and Technology, Tianjin University, Tianjin 300072, China
  • Received:2020-09-17 Revised:2020-10-10 Online:2021-06-20 Published:2021-06-20
  • Contact: HUANG Renliang

摘要:

聚偏氟乙烯(PVDF)膜因其优异的化学和力学稳定性而被广泛应用于水处理领域,但PVDF膜本身的疏水性,容易使其在处理含油废水的过程中被油滴污染,造成膜孔堵塞。以PVDF微滤膜为基底,通过单宁酸(TA)和聚乙烯亚胺(PEI)共沉积形成了TA/PEI黏附层,经戊二醛共价交联和接枝半胱氨酸(Cys),制备了一种PVDF改性膜(PVDF@TA/PEI-Cys)。改性后的PVDF膜具有良好的亲水性和水下超疏油性,水接触角和水下油接触角分别为22.2°和150.2°。在0.09 MPa下,PVDF@TA/PEI-Cys膜的纯水通量达6328 L/(m2·h),水包油型乳液分离效率高达99.9%。此外,该改性膜还可同时吸附水中的汞离子,最大吸附量为24.7 mg/g。

关键词: 膜分离, 重金属, 吸附, 乳液, 亲水性

Abstract:

Polyvinylidene fluoride (PVDF) membrane is widely used in the field of wastewater treatment due to its excellent chemical and mechanical stability. However, the hydrophobicity of the PVDF membrane makes it easy to be contaminated by oil droplets during the treatment of oily wastewater, which causes the pores of the membrane to be blocked and the decrease in permeation flux. In this study, we developed an approach for preparing a hydrophilic PVDF membrane. Specially, the co-deposition of tannic acid (TA) and polyethyleneimine (PEI) on the PVDF membrane was conducted for the formation of TA/PEI adhesive layer, which was covalently grafted with cysteine via glutaraldehyde to fabricate a modified PVDF membrane (PVDF@TA/PEI-Cys). The PVDF@TA/PEI-Cys membrane has good hydrophilicity and underwater superoleophobicity. The water contact angle and underwater oil contact angle were 22.2° and 150.2°, respectively. The pure water flux of the PVDF@TA/PEI-Cys membrane reached 6328 L/(m2·h) under 0.09 MPa and the separation efficiency of the oil-in-water emulsions was as high as 99.9%. In addition, the modified PVDF membrane can also be used for the adsorption of mercury ions with the maximum adsorption capacity of 24.7 mg/g.

Key words: membrane separation, heavy metal ions, adsorption, emulsion, hydrophilicity

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