抗污染芳香聚酰胺反渗透膜研究进展

doi:10.11949/0438-1157.20190815

化工学报 ›› 2020, Vol. 71 ›› Issue (2): 475-486.DOI: 10.11949/0438-1157.20190815

抗污染芳香聚酰胺反渗透膜研究进展

任六一^1,^2,^3,⁴(),赵颂^1,^2,^3,⁴,王志^1,^2,^3,⁴(),燕方正^1,^2,^3,⁴,刘莹莹^1,^2,^3,⁴,韩向磊^1,^2,^3,⁴,王纪孝^1,^2,^3,⁴

^1.天津大学化工学院化学工程研究所，天津 300350
^2.天津市膜科学与海水淡化技术重点实验室，天津 300350
^3.化学工程联合国家重点实验室（天津大学），天津 300350
^4.天津化学化工协同创新中心，天津 300350

收稿日期:2019-07-15 修回日期:2019-10-08 出版日期:2020-02-05 发布日期:2020-02-05
通讯作者: 王志
作者简介:任六一（1995—），男，硕士研究生， hgxyrly@tju.edu.cn
基金资助:
海洋公益性行业科研专项(201405009)

Research progress of antifouling aromatic polyamide reverse osmosis membrane

Liuyi REN^1,^2,^3,⁴(),Song ZHAO^1,^2,^3,⁴,Zhi WANG^1,^2,^3,⁴(),Fangzheng YAN^1,^2,^3,⁴,Yingying LIU^1,^2,^3,⁴,Xianglei HAN^1,^2,^3,⁴,Jixiao WANG^1,^2,^3,⁴

^1.Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University
^2.Tianjin Key Laboratory of Membrane Science and Desalination Technology
^3.State Key Laboratory of Chemical Engineering(Tianjin University)
^4.Tianjin Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300350, China

Received:2019-07-15 Revised:2019-10-08 Online:2020-02-05 Published:2020-02-05
Contact: Zhi WANG

摘要/Abstract

摘要：

聚酰胺反渗透膜具有选择透过性高、化学稳定性好等优点，在水处理领域应用广泛。但膜污染导致的通量下降、寿命降低等问题严重制约了其发展与应用，开发抗污染反渗透膜是缓解膜污染的重要手段。本文根据抗污染膜作用机理将抗污染反渗透膜分为抗黏附型、污染驱除型和杀菌型，综述了近年来相关方面的研究成果，并对合理组合多种机制制备抗污染反渗透膜的进展进行简要概括，最后对抗污染反渗透膜的发展前景进行了展望。

关键词: 反渗透, 膜, 抗黏附, 污染驱除, 杀菌, 表面, 聚合物

Abstract:

Polyamide reverse osmosis membrane has the aduantages of high seleetive permeability and good chemical stability, and is widely used in the field of water treatment. However, the problems caused by membrane fouling, such as decreased flux and reduced membrane life, have severely restricted its development and application. The development of antifouling reverse osmosis membrane is an important solution to alleviate membrane fouling. In this review, the mechanisms of antifouling reverse osmosis membrane are divided into fouling resistance, fouling release and antibacterial. The progress in inhibiting the membrane fouling by using single antifouling mechanism and integrating multi-mechanisms is introduced briefly. Finally, the prospects of antifouling reverse osmosis membranes are proposed.

Key words: reverse osmosis, membrane, fouling resistance, fouling release, antibacterial, surface, polymers

中图分类号:

TQ 028.8

任六一, 赵颂, 王志, 燕方正, 刘莹莹, 韩向磊, 王纪孝. 抗污染芳香聚酰胺反渗透膜研究进展[J]. 化工学报, 2020, 71(2): 475-486.

Liuyi REN, Song ZHAO, Zhi WANG, Fangzheng YAN, Yingying LIU, Xianglei HAN, Jixiao WANG. Research progress of antifouling aromatic polyamide reverse osmosis membrane[J]. CIESC Journal, 2020, 71(2): 475-486.

图/表 7

图1 反渗透膜表面接枝两性离子聚合物 [ 22]

Fig.1 Surface modification of RO membrane by grafting with zwitterionic polymer [ 22]

图2 木质素在RO膜上沉积的示意图 [ 28]

Fig.2 Schematic representation for deposition of lignin onto RO membranes [ 28]

图3 反渗透膜聚酰胺层上聚合物刷防污涂层的示意图 [ 34]

Fig.3 Schematic representation of antifouling dendrimer-based coating on polyamide layer [ 34]

图4 HEMA和PFDA单体结构 [ 42]

Fig.4 Molecular structure of monomers PFDA and HEMA [ 42]

图5 刺激响应性聚合物刷机理 [ 44]

Fig.5 Mechanism of stimuli-responsive polymer brushes [ 44]

图6 在PA TFC膜上固定AgNP @ SiO 2颗粒的示意图 [ 55]

Fig.6 Schematic illustration of immobilization of AgNP@SiO 2 particles on PA TFC membrane [ 55]

图7 三重抗污染功能反渗透膜及其抗污染性能 [ 82] (H + T-modified: HFBM和TOB改性的反渗透膜)

Fig.7 Triple antifouling features RO membrane and the corresponding antibiofouling property [ 82]

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抗污染芳香聚酰胺反渗透膜研究进展

Research progress of antifouling aromatic polyamide reverse osmosis membrane

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