金属有机骨架材料在CO2/CH4吸附分离中的研究进展

doi:10.3969/j.issn.0438-1157.2014.05.002

化工学报

金属有机骨架材料在CO₂/CH₄吸附分离中的研究进展

张所瀛¹, 刘红¹, 刘朋飞¹, 吴培培¹, 杨祝红¹, 阳庆元², 陆小华¹

1 南京工业大学化学化工学院, 材料化学工程国家重点实验室, 江苏南京 210009;
2 北京化工大学有机无机复合材料国家重点实验室, 北京 100029

收稿日期:2013-12-31 修回日期:2014-02-17 出版日期:2014-05-05 发布日期:2014-05-05
通讯作者: 陆小华
基金资助:
国家重点基础研究发展计划项目（2013CB733503）；国家自然科学基金重点项目（21136001，21206070）；江苏省博士创新基金项目（CXZZ13_0448）。

Progress of adsorption-based CO₂/CH₄ separation by metal organic frameworks

ZHANG Suoying¹, LIU Hong¹, LIU Pengfei¹, WU Peipei¹, YANG Zhuhong¹, YANG Qingyuan², LU Xiaohua¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, School of Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China;
2 State Key Laboratory of Organic-Inorganic Composites, School of Chemistry and Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2013-12-31 Revised:2014-02-17 Online:2014-05-05 Published:2014-05-05
Supported by:
supported by the National Basic Research Program of China (2013CB733503), the National Natural Science Foundation of China (21136001, 21206070) and the Innovation Foundation for Graduate Students of Jiangsu Province(CXZZ13_0448).

摘要/Abstract

摘要： CO₂/CH₄分离能耗高是生物甲烷过程核心难题之一。金属有机骨架材料（metal organic frameworks，MOFs）由于其优异的CO₂吸附分离性能，被视为最具潜力的CO₂分离捕集材料，近年来引起了广泛的关注。本文结合沼气的特点和MOFs研究的最新进展，对MOFs材料在CO₂/CH₄吸附分离过程的相关实验研究工作进行了综述。

关键词: 金属有机骨架材料, CO₂, CH₄, 吸附, 分离

Abstract: The high energy penalty of CO₂ separation from biogas is a core problem in the biomethane process. Metal organic frameworks (MOFs) have recently attracted intense research interest because of their ultra-high CO₂ adsorption capacity and potential applications as novel adsorbents to reduce energy cost. The recent progress of experimental researches on adsorption-based CO₂/CH₄ separation by MOFs is reviewed.

Key words: metal organic frameworks, CO₂, CH₄, adsorption, separation

中图分类号:

O6-1

张所瀛, 刘红, 刘朋飞, 吴培培, 杨祝红, 阳庆元, 陆小华. 金属有机骨架材料在CO₂/CH₄吸附分离中的研究进展[J]. 化工学报, DOI: 10.3969/j.issn.0438-1157.2014.05.002.

ZHANG Suoying, LIU Hong, LIU Pengfei, WU Peipei, YANG Zhuhong, YANG Qingyuan, LU Xiaohua. Progress of adsorption-based CO₂/CH₄ separation by metal organic frameworks[J]. CIESC Journal, DOI: 10.3969/j.issn.0438-1157.2014.05.002.

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金属有机骨架材料在CO₂/CH₄吸附分离中的研究进展

Progress of adsorption-based CO₂/CH₄ separation by metal organic frameworks

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