丁二烯抽提工艺中离子液体添加剂的筛选及分离性能

doi:10.3969/j.issn.0438-1157.2014.06.024

化工学报 ›› 2014, Vol. 65 ›› Issue (6): 2120-2129.DOI: 10.3969/j.issn.0438-1157.2014.06.024

丁二烯抽提工艺中离子液体添加剂的筛选及分离性能

曾少娟^1,2, 田肖¹, 董海峰¹, 张香平¹, 张锁江¹

1. 中国科学院过程工程研究所, 多相复杂系统国家重点实验室, 离子液体清洁过程北京市重点实验室, 北京 100190;
2. 中国科学院大学, 北京 100049

收稿日期:2013-09-18 修回日期:2014-02-19 出版日期:2014-06-05 发布日期:2014-06-05
通讯作者: 张锁江，张香平
作者简介:曾少娟（1982- ），女，硕士，助理研究员。
基金资助:
国家自然科学基金项目（U1162105）；国家重点基础研究发展计划项目（2013CB733506）。

Selection and separation performance of ionic liquid as additive in butadiene extraction with ACN

ZENG Shaojuan^1,2, TIAN Xiao¹, DONG Haifeng¹, ZHANG Xiangping¹, ZHANG Suojiang¹

1. Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-09-18 Revised:2014-02-19 Online:2014-06-05 Published:2014-06-05
Supported by:
supported by the National Natural Science Foundation of China(U1162105) and the National Basic Research Program of China (2013CB733506).

摘要/Abstract

摘要： 提出以离子液体为第三组分的丁二烯抽提新工艺，通过考察不同结构的离子液体对C₄组分在复合萃取剂中相对挥发度的影响，并结合量化计算的方法，研究了该工艺中萃取剂和第三组分与C₄组分的相互作用机理，从而优选出适用于该工艺的离子液体添加剂[Emim][PF₆]。另外研究了该离子液体在工业条件下对C₄组分分离性能的影响，并对改进前后的工艺进行全流程模拟计算。结果表明：与现有乙腈法相比，离子液体的加入有利于提高C₄在新型萃取剂中的相对挥发度，具有很好的分离效果。含离子液体的新工艺可使能耗降低约6.62%，乙腈消耗量降低约24%，而且离子液体能够回收利用，回收率高达98%（质量分数）以上，因此基于离子液体的乙腈法抽提丁二烯新技术具有很好的工业应用前景。

关键词: 离子液体, C₄, 乙腈法, 相对挥发度, 分离, 丁二烯

Abstract: A new separation process of C₄ mixture with ionic liquid as additive was proposed. The influence of ionic liquid on the relative volatility of C₄ mixtures in acetonitrile (ACN) solvent system was investigated. The interaction mechanisms between ACN, ionic liquid and C₄ were analyzed by quantum chemistry calculations. In addition, two flowsheets of ACN butadiene extraction process with or without ionic liquid were simulated. Ionic liquids were proved to be effective additives for C₄ separation, and the appropriate ionic liquid [Emim][PF₆] for ACN butadiene extraction process was chosen and confirmed by the simulation results. In the practical process, the mixed solvent of ACN with ionic liquids showed better separation performance than that of ACN solvent, and the new technology could recover more than 98%(mass) ionic liquids after the distillation process. Moreover, separating C₄ with ionic liquid could decrease energy consumption by about 24%. Therefore, the proposed new process technology with ionic liquid as additive is a perspective C₄ mixture separation process.

Key words: ionic liquid, C₄, acetonitrile, relative volatility, separation, butadiene

中图分类号:

TQ028

曾少娟, 田肖, 董海峰, 张香平, 张锁江. 丁二烯抽提工艺中离子液体添加剂的筛选及分离性能[J]. 化工学报, 2014, 65(6): 2120-2129.

ZENG Shaojuan, TIAN Xiao, DONG Haifeng, ZHANG Xiangping, ZHANG Suojiang. Selection and separation performance of ionic liquid as additive in butadiene extraction with ACN[J]. CIESC Journal, 2014, 65(6): 2120-2129.

参考文献 28

[1]	Ammenheuser M M, Bechtold W E, Abdel-Rahman S Z, Rosenblatt J I, Hastings-Smith D A, Ward J B. Assessment of 1,3-butadiene exposure in polymer production workers using HPRT mutations in lymphocytes as a biomarker [J]. Environmental Health Perspectives, 2001, 109(12): 1249-1255
[2]	Barshteyn N, Krause R J, Elfarra A A. Mass spectral analyses of hemoglobin adducts formed after in vitro exposure of erythrocytes to hydroxymethylvinyl ketone [J]. Chemico-Biological Interactions, 2007, 166(1/2/3): 176-181
[3]	Zhang X Y, Elfarra A A. Reaction of 1,2,3,4-diepoxybutane with 2'-deoxyguanosine: initial products and their stabilities and decomposition patterns under physiological conditions [J]. Chemical Research in Toxicology, 2005, 18(8): 1316-1323
[4]	Yang X J, Yin X, Ouyang P K. Simulation of 1,3-butadiene production process by dimethylfomamide extractive distillation [J]. Chin. J. Chem. Eng., 2009, 17(1): 27-35
[5]	Asano Y, Fujishiro K, Tani Y, Yamada H. Aliphatic nitrile hydratase from Arthrobacter sp. J-l purification and characterization [J]. Agric. Biol. Chem., 1982, 46(5): 1165-1174
[6]	Asano Y, Tachibana M, Tani Y, Yamada H. Purification and characterization of amidase which participates in nitrile degradation [J]. Agric. Biol. Chem., 1982, 46(5): 1175-1181
[7]	Digeronimo M J, Antoine A D. Metabolism of acetonitrile and propionitrile by Nocardia rhodochrous L100-21 [J]. Appl. Environ. Microbiol., 1976, 31(6): 900-906
[8]	Lei Z G, Wang H Y, Zhou R Q, Duan Z T. Solvent improvement for separating C4 with ACN [J]. Comput. Chem. Eng., 2002, 26:1213-1221
[9]	Japan Synthetic Rubber Co. Ltd. Separation of mixture of hydrocarbons [P]:JP, 60052686
[10]	Hong X D, Jian L, Jian P. Research advances in extractive distillation with salt [J]. Chemical Industry Time, 2004, 18(5): 16-19
[11]	Lei Zhigang(雷志刚), Xu Zheng(许峥), Zhou Rongqi(周荣琪), Duan Zhanting(段占庭). Influence of addition of salt to solvent on separating non-polar systems by extractive distillation [J]. Petrochemical Technology(石油化工),2001, 30(3):200-204
[12]	Lei Zhigang(雷志刚), Zhou Rongqi(周荣琪), Duan Zhanting(段占庭). Separation C4 by extractive distillation with added DMF [J]. Journal of Chemical Industry and Engineering (China)(化工学报), 1999, 15(3): 407-410
[13]	Lei Zhigang(雷志刚), Xu Zheng(许峥), Zhou Rongqi(周荣琪), Duan Zhanting(段占庭). Solvent optimization for separating C4 by extractive distillation [J]. Journal of Chemical Engineering of Chinese Universities (高校化学工程学报), 2001, 15(1): 17-22
[14]	Pan Xiaomei(潘晓梅), Xiao Guomin(肖国民), Yang Zhicai(杨志才). The separation process of distillation coupled with salt extraction [J]. Journal of Chemical Engineering of Chinese Universities (高校化学工程学报), 2005, 19(5): 598-602
[15]	Meindersma G W, Dehaan A B. Cyano-containing ionic liquids for the extraction of aromatic hydrocarbons from an aromatic/aliphatic mixture [J]. Sci. China Chem., 2012, 55(8): 1488-1499
[16]	Zhu Jiqin(朱吉钦), Chen Jian(陈健), Fei Weiyang(费维扬). Separation of aromatic hydrocarbons or olefins from paraffins using new ionic liquids [J]. Journal of Chemical Industry and Engineering (China) (化工学报),2004, 55(12): 2091-2094
[17]	Huddleaton J G,Willauer H D,Swatloski R P, Visser A E, Rogers R D. Room temperature ionic liquids as novel mediafor“clean”liquid-liquid extraction [J]. Chem. Commun.,1998(16): 1765-1766
[18]	Chen Y H, Zhang S J, Yuan X L, Zhang Y Q, Zhang X P, Dai W B, Mori R. Solubility of CO2 in imidazolium-based tetrafluoroborate ionic liquids [J]. Thermochim. Acta, 2006, 441(1): 42-44
[19]	Wang J J, Pei Y C, Zhao Y, Zhang S J. Selective extraction of bioproducts by ionic liquids [J]. Chin. J. Chem., 2005, 23(6): 662-664
[20]	He X Z, Zhang X P, Zhang S J, Liu J D, Li C S. Prediction of phase equilibrium properties for complicated macromolecular systems by HGALM neural networks [J].Fluid Phase Equilib.,2005, 238(1): 52-57
[21]	Yuan X L, Zhang S J,Lu X M. Hydroxyl ammonium ionic liquids: synthesis, properties, and solubility of SO2 [J]. Journal of Chemical and Engineering Data, 2007, 52(2): 596-599
[22]	Gao H S, Luo M F, Xing J M, Wu Y, Li Y, Li W L, Liu Q F, Liu H Z. Desulfurization of fuel by extraction with pyridinium-based ionic liquids [J]. Ind. Eng. Chem. Res., 2008, 47(21): 8384-8388
[23]	Wang C M, Luo X Y, Luo H M, Jiang D E, Li H R, Dai S. Tuning the basicity of ionic liquids for equimolar CO2 Capture [J]. Angew. Chem. Int. Ed.,2011, 50, 4918-4922
[24]	Wang Yuantao(王渊涛), Fang Chenggang(方诚刚), Zhang Feng(张锋), Wu Youting(吴有庭), Geng Jiao(耿皎), Zhang Zhibing(张志炳). Performance of CO2 absorption in mixed aqueous solution of MDEA and amino acid ionic liquids [J]. CIESC Journal (化工学报),2009, 60(11): 2781-2786
[25]	Venkat V,Raghunathan R, et al. A review of process fault detection and diagnosis (Ⅲ): Process history based methods [J]. Computers and Chemical Engineering, 2003, 27: 327-346
[26]	Prausnitz J M, Anderson R. Thermodynamics of solvent selectivity in extractive distillation of hydrocarbons [J]. AIChE Journal, 1961, 7(1): 96-10
[27]	Lei Z G, Arlt W, Wasserschield P. Separation of 1-hexene and n-hexane with ionic liquids [J]. Fluid Phase Equilibria, 2006, 241(1/2): 290-299
[28]	Bondi A. Physical Properties of Molecular Crystans, Liquids and Glasses[M]. New York: John Wiley & Sons, 1968:502

丁二烯抽提工艺中离子液体添加剂的筛选及分离性能

Selection and separation performance of ionic liquid as additive in butadiene extraction with ACN

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