化工学报 ›› 2011, Vol. 62 ›› Issue (S1): 66-71.

• 流体力学与传递现象 • 上一篇    下一篇

空气自呼吸式直接甲醇燃料电池传输特性数值研究

苗政,邹金强,何雅玲,刘增   

  1. 西安交通大学能源与动力工程学院,动力工程多相流国家重点实验室,热流科学与工程教育部重点实验室(筹),陕西 西安 710049
  • 出版日期:2011-07-03 发布日期:2011-07-03

  • Online:2011-07-03 Published:2011-07-03

摘要:

针对空气自呼吸式直接甲醇燃料电池(DMFC)建立了二维两相非等温的传质模型,通过自编程序模拟了电池内的传热、传质和电化学反应过程。并基于此模型研究了主要的操作参数,包括甲醇进口温度、环境中空气的温度、甲醇进口浓度,及对电池性能的影响。研究表明甲醇溶液的进口温度和环境温度上升都会使电池的性能得到提高,其中甲醇溶液的进口温度对电池性能的影响更大;当甲醇进口浓度提高后,在大电流密度下电池的性能得到了显著的提高。

关键词: 燃料电池, 两相模拟, 热传递, 甲醇串流

Abstract:

A two-dimensional two-phase non-isothermal mass transport model is developed in this paper for the air breathing direct methanol fuel cellDMFC.The self-made computer code is used to simulate the heat and mass transport characteristic which is coupled with electro-chemical reactions.The effects of temperature of the inlet methanol solutiontemperature of the airand the feeding concentration of methanol on the performance of the fuel cell are investigated.The numerical results show that the cell performance can be enhanced at a higher temperature of the inlet methanol solution and the air.Cell performance at the higher cell current densities can be improved with a higher feeding concentration of methanol.

Key words: 燃料电池, 两相模拟, 热传递, 甲醇串流