金属有机框架光催化剂微环境调控研究进展

doi:10.11949/0438-1157.20190601

化工学报 ›› 2019, Vol. 70 ›› Issue (10): 3776-3790.DOI: 10.11949/0438-1157.20190601

金属有机框架光催化剂微环境调控研究进展

安珂^1,²(),杨冬^3,⁴,赵展烽^1,²,任汉杰^1,²,陈瑶^1,²,周致远³,姜忠义^1,²()

1. 天津大学化工学院绿色化学化工教育部重点实验室，天津 300072
2. 天津化学化工协同创新中心，天津 300072
3. 天津大学化工学院系统生物工程教育部重点实验室，天津 300072
4. 天津大学环境科学与工程学院，天津 300072

收稿日期:2019-05-31 修回日期:2019-08-11 出版日期:2019-10-05 发布日期:2019-10-05
通讯作者: 姜忠义
作者简介:安珂（1996—），男，硕士研究生，sonoflordkirk@tju.edu.cn
基金资助:
国家自然科学基金创新研究群体项目(21621004);天津市自然科学基金面上项目(18JCYBJC21000)

Research progress on microenvironment regulation of metal-organic framework photocatalyst

Ke AN^1,²(),Dong YANG^3,⁴,Zhanfeng ZHAO^1,²,Hanjie REN^1,²,Yao CHEN^1,²,Zhiyuan ZHOU³,Zhongyi JIANG^1,²()

1. Key Laboratory for Green Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
3. Key Laboratory of Systems Bioengineering of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
4. School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China

Received:2019-05-31 Revised:2019-08-11 Online:2019-10-05 Published:2019-10-05
Contact: Zhongyi JIANG

摘要/Abstract

摘要：

金属有机框架材料（MOFs）是一类无机金属中心和有机配体自组装形成的晶体多孔材料，既有无机材料高结晶度、高电子迁移率等特点，又兼具有机材料高比表面积、高孔隙率、强可修饰性等特点，在光催化领域显示出广阔的应用前景。围绕物理化学微环境调控，对近年来MOFs光催化材料的研究进行了详细综述。其中，物理微环境的调控重点介绍了微观形貌调控、贵金属沉积和异质结构建三个方面；化学微环境调控重点介绍了金属位点调控与有机配体调控两个方面。此外，对MOFs光催化材料的未来发展进行展望，以期为高性能MOFs光催化剂的理性设计和可控制备等方面的研究提供思路。

关键词: 金属有机框架材料, 微环境, 催化剂, 光化学, 太阳能

Abstract:

Metal organic framework materials (MOFs) are a class of inorganic metal centers and organic ligands formed by self-assembly of crystalline porous materials. MOFs combine high crystallinity and electron mobility of inorganic materials with high specific surface area, porosity and modifiability of organic materials, thus exhibiting broad application prospects in the field of photocatalysis. The research on MOFs photocatalytic materials in recent years is reviewed centering on the regulation of physical and chemical microenvironment. The regulation of physical microenvironment has been focused on micromorphology regulation, noble metal deposition and heterostructure construction, meanwhile the regulation of chemical microenvironment has been focused on metal site regulation and organic ligand regulation. In addition, in order to provide ideas for rational design and controllable preparation of high-performance MOF photocatalysts, the future development of MOF photocatalytic materials is also prospected.

Key words: metal-organic frameworks, microenvironment, catalyst, photochemistry, solar energy

中图分类号:

O 643

安珂, 杨冬, 赵展烽, 任汉杰, 陈瑶, 周致远, 姜忠义. 金属有机框架光催化剂微环境调控研究进展[J]. 化工学报, 2019, 70(10): 3776-3790.

Ke AN, Dong YANG, Zhanfeng ZHAO, Hanjie REN, Yao CHEN, Zhiyuan ZHOU, Zhongyi JIANG. Research progress on microenvironment regulation of metal-organic framework photocatalyst[J]. CIESC Journal, 2019, 70(10): 3776-3790.

图/表 16

参考文献 101

1	Grätzel M . Mesoscopic solar cells for electricity and hydrogen production from sunlight[J]. Chemistry Letters, 2004, 34(1): 8-13.
2	Ravelli D , Dondi D , Fagnoni M , et al . Photocatalysis. A multi-faceted concept for green chemistry[J]. Chemical Society Reviews, 2009, 38(7): 1999-2011.
3	Fujishima A , Honda K . Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238(5358): 37-38.
4	Yaghi O M , Li G , Li H . Selective binding and removal of guests in a microporous metal-organic framework[J]. Nature, 1995, 378(6558): 703-706.
5	Li J R , Kuppler R J , Zhou H C . Selective gas adsorption and separation in metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5): 1477-1504.
6	Wang T , Li X , Dai W , et al . Enhanced adsorption of dibenzothiophene with zinc/copper-based metal-organic frameworks[J]. Journal of Materials Chemistry A, 2015, 3(42): 21044-21050.
7	张所瀛, 刘红, 刘朋飞, 等 . 金属有机骨架材料在CO₂/CH₄吸附分离中的研究进展[J]. 化工学报, 2014, 65(5): 1563-1570.
	Zhang S Y , Liu H , Liu P F , et al . Progress of adsorption-based CO₂/CH₄ separation by metal organic frameworks[J]. CIESC Journal, 2014, 65(5):1563-1570.
8	Adil K , Belmabkhout Y , Pillai R S , et al . Gas/vapour separation using ultra-microporous metal-organic frameworks: insights into the structure/separation relationship[J]. Chemical Society Reviews, 2017, 46(11): 3402-3430.
9	Han L , Yu X Y , Lou X W . Formation of prussian-blue-analog nanocages via a direct etching method and their conversion into Ni-Co-mixed oxide for enhanced oxygen evolution[J]. Advanced Materials, 2016, 28(23): 4601-4605.
10	Palaniselvam T , Kashyap V , Bhange S N , et al . Nanoporous graphene enriched with Fe/Co-N active sites as a promising oxygen reduction electrocatalyst for anion exchange membrane fuel cells[J]. Advanced Functional Materials, 2016, 26(13): 2150-2162.
11	Farrusseng D , Aguado S , Pinel C . Metal-organic frameworks: opportunities for catalysis[J]. Angewandte Chemie International Edition, 2009, 48(41): 7502-7513.
12	Yin Z , Wang Q X , Zeng M H . Iodine release and recovery, influence of polyiodide anions on electrical conductivity and nonlinear optical activity in an interdigitated and interpenetrated bipillared-bilayer metal-organic framework[J]. Journal of the American Chemical Society, 2012, 134(10): 4857-4863.
13	Lustig W P , Mukherjee S , Rudd N D , et al . Metal-organic frameworks: functional luminescent and photonic materials for sensing applications[J]. Chemical Society Reviews, 2017, 46(11): 3242-3285.
14	Yao R X , Xu X , Zhang X M . Magnetic modulation and cation-exchange in a series of isostructural (4, 8)-connected metal-organic frameworks with butterfly-like [M₄(OH)₂(RCO₂)₈] building units[J]. Chemistry of Materials, 2012, 24(2): 303-310.
15	Grancha T , Ferrando-Soria J , Zhou H C , et al . Postsynthetic improvement of the physical properties in a metal-organic framework through a single crystal to single crystal transmetallation[J]. Angewandte Chemie International Edition, 2015, 54(22): 6521-6525.
16	He Y , Zhou W , Qian G , et al . Methane storage in metal-organic frameworks[J]. Chemical Society Reviews, 2014, 43(16): 5657-5678.
17	Evans J D , Jelfs K E , Day G M , et al . Application of computational methods to the design and characterisation of porous molecular materials[J]. Chemical Society Reviews, 2017, 46(11): 3286-3301.
18	Alvaro M , Carbonell E , Ferrer B , et al . Semiconductor behavior of a metal-organic framework (MOF)[J]. Chemistry-A European Journal, 2007, 13(18): 5106-5112.
19	Silva C G , Corma A , García H . Metal-organic frameworks as semiconductors[J]. Journal of Materials Chemistry, 2010, 20(16): 3141-3156.
20	Du J J , Yuan Y P , Sun J X , et al . New photocataslysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye[J]. Journal of Hazardous Materials, 2011, 190(1/2/3): 945-951.
21	Gomes S C , Luz I , Llabrési X F X , et al . Water stable Zr-benzenedicarboxylate metal-organic frameworks as photocatalysts for hydrogen generation[J]. Chemistry-A European Journal, 2010, 16(36): 11133-11138.
22	Li R , Zhang W , Zhou K . Metal-organic-framework-based catalysts for photoreduction of CO₂ [J]. Advanced Materials, 2018, 30(35): 1705512.
23	Assi H , Mouchaham G , Steunou N , et al . Titanium coordination compounds: from discrete metal complexes to metal-organic frameworks[J]. Chemical Society Reviews, 2017, 46(11): 3431-3452.
24	Bai Y , Dou Y , Xie L H , et al . Zr-based metal-organic frameworks: design, synthesis, structure, and applications[J]. Chemical Society Reviews, 2016, 45(8): 2327-2367.
25	Wang D , Li Z . Iron-based metal-organic frameworks (MOFs) for visible-light-induced photocatalysis[J]. Research on Chemical Intermediates, 2017, 43(9): 5169-5186.
26	Meyer K , Ranocchiari M , Bokhoven J A V . Metal organic frameworks for photo-catalytic water splitting[J]. Energy & Environmental Science, 2015, 8(7):1923-1937.
27	Chen Y , Wang D , Deng X , et al . Metal-organic frameworks (MOFs) for photocatalytic CO₂ reduction[J]. Catalysis Science & Technology, 2017, 7(21): 4893-4904.
28	Wang C C , Li J R , Lü X L , et al . Photocatalytic organic pollutants degradation in metal-organic frameworks[J]. Energy & Environmental Science, 2014, 7(9):2831-2867.
29	Deng X , Li Z , García H . Visible light induced organic transformations using metal‐organic‐frameworks (MOFs)[J]. Chemistry-A European Journal, 2017, 23(47): 11189-11209.
30	Wang D , Pan Y , Xu L , et al . PdAu@ MIL-100 (Fe) cooperatively catalyze tandem reactions between amines and alcohols for efficient n-alkyl amines syntheses under visible light[J]. Journal of Catalysis, 2018, 361: 248-254.
31	Wang D , Albero J , García H , et al . Visible-light-induced tandem reaction of o-aminothiophenols and alcohols to benzothiazoles over Fe-based MOFs: influence of the structure elucidated by transient absorption spectroscopy[J]. Journal of Catalysis, 2017, 349: 156-162.
32	Sun D , Li Z . Double-solvent method to Pd nanoclusters encapsulated inside the cavity of NH₂-Uio-66 (Zr) for efficient visible-light-promoted suzuki coupling reaction[J]. The Journal of Physical Chemistry C, 2016, 120(35): 19744-19750.
33	Wang D , Wang M , Li Z . Fe-based metal-organic frameworks for highly selective photocatalytic benzene hydroxylation to phenol[J]. ACS Catalysis, 2015, 5(11): 6852-6857.
34	Zeng L , Guo X , He C , et al . Metal-organic frameworks: versatile materials for heterogeneous photocatalysis[J]. ACS Catalysis, 2016, 6(11): 7935-7947.
35	刘芳, 樊丰涛, 吕玉翠, 等 . 石墨烯/TiO₂复合材料光催化降解有机污染物的研究进展[J]. 化工学报, 2016, 67(5): 1635-1643.
	Liu F , Fan F T , Lyu Y C , et al . Research progress on photocatalytic degradation of organic pollutants by graphene/TiO₂ composite materials[J]. CIESC Journal, 2016, 67(5): 1635-1643.
36	Deng X , Hao M , Li Z . Engineering metal-organic frameworks (MOFs) for efficient photocatalysis[J]. Current Organic Chemistry, 2018, 22(18): 1825-1835.
37	Li Y , Xu H , Ouyang S , et al . Metal-organic frameworks for photocatalysis[J]. Physical Chemistry Chemical Physics, 2016, 18(11): 7563-7572.
38	Zhang T , Jin Y , Shi Y , et al . Modulating photoelectronic performance of metal-organic frameworks for premium photocatalysis[J]. Coordination Chemistry Reviews, 2019, 380: 201-229.
39	Wen M , Mori K , Kuwahara Y , et al . Design of single-site photocatalysts by using metal-organic frameworks as a matrix[J]. Chemistry-An Asian Journal, 2018, 13(14): 1767-1779.
40	Subudhi S , Rath D , Parida K M . A mechanistic approach towards the photocatalytic organic transformations over functionalised metal organic frameworks: a review[J]. Catalysis Science & Technology, 2018, 8(3): 679-696.
41	Dhakshinamoorthy A , Li Z , Garcia H . Catalysis and photocatalysis by metal organic frameworks[J]. Chemical Society Reviews, 2018, 47(22): 8134-8172.
42	Nguyen H L . The chemistry of titanium-based metal-organic frameworks[J]. New Journal of Chemistry, 2017, 41(23): 14030-14043.
43	Tu T N , Nguyen M V , Nguyen H L , et al . Designing bipyridine-functionalized zirconium metal-organic frameworks as a platform for clean energy and other emerging applications[J]. Coordination Chemistry Reviews, 2018, 364: 33-50.
44	Sun D , Li Z . Robust Ti- and Zr-based metal-organic frameworks for photocatalysis[J]. Chinese Journal of Chemistry, 2017, 35(2): 135-147.
45	Wen M , Mori K , Kuwahara Y , et al . Design and architecture of metal organic frameworks for visible light enhanced hydrogen production[J]. Applied Catalysis B: Environmental, 2017, 218: 555-569.
46	Cui Y , Zhang J , He H , et al . Photonic functional metal-organic frameworks[J]. Chemical Society Reviews, 2018, 47(15): 5740-5785.
47	孙登荣, 李朝晖 . 金属有机框架材料 (MOFs) 在光催化有机合成中的应用[J]. 中国材料进展, 2017, 36(10): 756-764.
	Sun D R , Li Z H . Metal-organic frameworks (MOFs) in photocatalytic organic transformations[J]. Materials China, 2017, 36(10): 756-764.
48	Sun D , Liu W , Fu Y , et al . Noble metals can have different effects on photocatalysis over metal-organic frameworks (MOFs): a case study on M/NH₂-MIL-125(Ti)(M= Pt and Au)[J]. Chemistry-A European Journal, 2014, 20(16): 4780-4788.
49	Wen M , Mori K , Kuwahara Y , et al . Plasmonic Au@ Pd nanoparticles supported on a basic metal-organic framework: synergic boosting of H₂ production from formic acid[J]. ACS Energy Letters, 2016, 2(1): 1-7.
50	Chen M , Han L , Zhou J , et al . Photoreduction of carbon dioxide under visible light by ultra-small Ag nanoparticles doped into Co-ZIF-9[J]. Nanotechnology, 2018, 29(28): 284003.
51	Xiao J D , Han L , Luo J , et al . Integration of plasmonic effects and Schottky junctions into metal-organic framework composites: steering charge flow for enhanced visible-light photocatalysis[J]. Angewandte Chemie International Edition, 2018, 57(4): 1103-1107.
52	Wang R , Gu L , Zhou J , et al . Quasi-polymeric metal-organic framework UiO-66/g-C₃N₄ heterojunctions for enhanced photocatalytic hydrogen evolution under visible light irradiation[J]. Advanced Materials Interfaces, 2015, 2(10): 1500037.
53	Huang J , Zhang X , Song H , et al . Protonated graphitic carbon nitride coated metal-organic frameworks with enhanced visible-light photocatalytic activity for contaminants degradation[J]. Applied Surface Science, 2018, 441: 85-98.
54	Liu S , Chen F , Li S , et al . Enhanced photocatalytic conversion of greenhouse gas CO₂ into solar fuels over g-C₃N₄ nanotubes with decorated transparent ZIF-8 nanoclusters[J]. Applied Catalysis B: Environmental, 2017, 211: 1-10.
55	Zhang F M , Sheng J L , Yang Z D , et al . Rational design of MOF/COF hybrid materials for photocatalytic H₂ evolution in the presence of sacrificial electron donors[J]. Angewandte Chemie, 2018, 130(37): 12282-12286.
56	Li F , Wang D , Xing Q J , et al . Design and syntheses of MOF/COF hybrid materials via postsynthetic covalent modification: an efficient strategy to boost the visible-light-driven photocatalytic performance[J]. Applied Catalysis B: Environmental, 2019, 243: 621-628.
57	Peng Y , Zhao M , Chen B , et al . Hybridization of MOFs and COFs: a new strategy for construction of MOF@ COF core-shell hybrid materials[J]. Advanced Materials, 2018, 30(3): 1705454.
58	Sun D , Jang S , Yim S J , et al . Metal doped core-shell metal-organic frameworks@ covalent organic frameworks (MOFs@ COFs) hybrids as a novel photocatalytic platform[J]. Advanced Functional Materials, 2018, 28(13): 1707110.
59	He S , Rong Q , Niu H , et al . Platform for molecular-material dual regulation: a direct Z-scheme MOF/COF heterojunction with enhanced visible-light photocatalytic activity[J]. Applied Catalysis B: Environmental, 2019, 247: 49-56.
60	Zhang S , Li L , Zhao S , et al . Hierarchical metal-organic framework nanoflowers for effective CO₂ transformation driven by visible light[J]. Journal of Materials Chemistry A, 2015, 3(30): 15764-15768.
61	Xiao Y , Qi Y , Wang X , et al . Visible-light-responsive 2D cadmium-organic framework single crystals with dual functions of water reduction and oxidation[J]. Advanced Materials, 2018, 30(44): 1803401.
62	Ran J , Qu J , Zhang H , et al . 2D metal organic framework nanosheet: a universal platform promoting highly efficient visible-light-induced hydrogen production[J]. Advanced Energy Materials, 2019, 9(11): 1803402.
63	Wang M , Liu J , Guo C , et al . Metal-organic frameworks (ZIF-67) as efficient cocatalysts for photocatalytic reduction of CO₂: the role of the morphology effect[J]. Journal of Materials Chemistry A, 2018, 6(11): 4768-4775.
64	Niu K , Xu Y , Wang H , et al . A spongy nickel-organic CO₂ reduction photocatalyst for nearly 100% selective CO production[J]. Science Advances, 2017, 3(7): e1700921.
65	Li Z , Xiao J D , Jiang H L . Encapsulating a Co (Ⅱ) molecular photocatalyst in metal-organic framework for visible-light-driven H₂ production: boosting catalytic efficiency via spatial charge separation[J]. ACS Catalysis, 2016, 6(8): 5359-5365.
66	Chen L , Chen H , Li Y . One-pot synthesis of Pd@ MOF composites without the addition of stabilizing agents[J]. Chemical Communications, 2014, 50(94): 14752-14755.
67	Lajevardi A , Yaraki M T , Masjedi A , et al . Green synthesis of MOF@ Ag nanocomposites for catalytic reduction of methylene blue[J]. Journal of Molecular Liquids, 2019, 276: 371-378.
68	Abdelhameed R M , Simões M M Q , Silva A M S , et al . Enhanced photocatalytic activity of MIL-125 by post-synthetic modification with Cr^Ⅲ and Ag nanoparticles[J]. Chemistry-A European Journal, 2015, 21(31): 11072-11081.
69	Feng S , Wang R , Feng S , et al . Synthesis of Zr-based MOF nanocomposites for efficient visible-light photocatalytic degradation of contaminants[J]. Research on Chemical Intermediates, 2019, 45(3): 1263-1279.
70	Yang Z , Xu X , Liang X , et al . Construction of heterostructured MIL-125/Ag/g-C₃N₄ nanocomposite as an efficient bifunctional visible light photocatalyst for the organic oxidation and reduction reactions[J]. Applied Catalysis B: Environmental, 2017, 205: 42-54.
71	Bai S , Ge J , Wang L , et al . A unique semiconductor-metal-graphene stack design to harness charge flow for photocatalysis[J]. Advanced Materials, 2014, 26(32): 5689-5695.
72	Kudo A , Miseki Y . Heterogeneous photocatalyst materials for water splitting[J]. Chemical Society Reviews, 2009, 38(1): 253-278.
73	Wang H , Zhang L , Chen Z , et al . Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances[J]. Chemical Society Reviews, 2014, 43(15): 5234-5244.
74	Tong Z , Yang D , Li Z , et al . Thylakoid-inspired multishell g-C₃N₄ nanocapsules with enhanced visible-light harvesting and electron transfer properties for high-efficiency photocatalysis[J]. ACS Nano, 2017, 11(1): 1103-1112.
75	Tong Z , Yang D , Sun Y , et al . Tubular g-C₃N₄ isotype heterojunction: enhanced visible-light photocatalytic activity through cooperative manipulation of oriented electron and hole transfer[J]. Small, 2016, 12(30): 4093-4101.
76	Shi L , Wang T , Zhang H , et al . Electrostatic self-assembly of nanosized carbon nitride nanosheet onto a zirconium metal-organic framework for enhanced photocatalytic CO₂ reduction[J]. Advanced Functional Materials, 2015, 25(33): 5360-5367.
77	Zhang X , Yang Y , Huang W , et al . G-C₃N₄/UiO-66 nanohybrids with enhanced photocatalytic activities for the oxidation of dye under visible light irradiation[J]. Materials Research Bulletin, 2018, 99: 349-358.
78	Huang W , Liu N , Zhang X , et al . Metal organic framework g-C₃N₄/MIL-53 (Fe) heterojunctions with enhanced photocatalytic activity for Cr (Ⅵ) reduction under visible light[J]. Applied Surface Science, 2017, 425: 107-116.
79	Bai C , Bi J , Wu J , et al . Fabrication of noble-metal-free g-C₃N₄-MIL53 (Fe) composite for enhanced photocatalytic H₂-generation performance[J]. Applied Organometallic Chemistry, 2018, 32(12): e4597.
80	Guo D , Wen R , Liu M , et al . Facile fabrication of g-C₃N₄/MIL-53 (Al) composite with enhanced photocatalytic activities under visible-light irradiation[J]. Applied Organometallic Chemistry, 2015, 29(10): 690-697.
81	Hong J , Chen C , Bedoya F E , et al . Carbon nitride nanosheet/metal-organic framework nanocomposites with synergistic photocatalytic activities[J]. Catalysis Science & Technology, 2016, 6(13): 5042-5051.
82	Du X , Yi X , Wang P , et al . Enhanced photocatalytic Cr (Ⅵ) reduction and diclofenac sodium degradation under simulated sunlight irradiation over MIL-100 (Fe)/g-C₃N₄ heterojunctions[J]. Chinese Journal of Catalysis, 2019, 40(1): 70-79.
83	Tian L , Yang X , Liu Q , et al . Anchoring metal-organic framework nanoparticles on graphitic carbon nitrides for solar-driven photocatalytic hydrogen evolution[J]. Applied Surface Science, 2018, 455: 403-409.
84	Panneri S , Thomas M , Ganguly P , et al . C₃N₄ anchored ZIF 8 composites: photo-regenerable, high capacity sorbents as adsorptive photocatalysts for the effective removal of tetracycline from water[J]. Catalysis Science & Technology, 2017, 7(10): 2118-2128.
85	Zou L , Feng D , Liu T F , et al . A versatile synthetic route for the preparation of titanium metal-organic frameworks[J]. Chemical Science, 2016, 7(2): 1063-1069.
86	Lee Y , Kim S , Kang J K , et al . Photocatalytic CO₂ reduction by a mixed metal (Zr/Ti), mixed ligand metal-organic framework under visible light irradiation[J]. Chemical Communications, 2015, 51(26): 5735-5738.
87	Sun D , Liu W , Qiu M , et al . Introduction of a mediator for enhancing photocatalytic performance via post-synthetic metal exchange in metal-organic frameworks (MOFs)[J]. Chemical Communications, 2015, 51(11): 2056-2059.
88	Tu J , Zeng X , Xu F , et al . Microwave-induced fast incorporation of titanium into UiO-66 metal-organic frameworks for enhanced photocatalytic properties[J]. Chemical Communications, 2017, 53(23): 3361-3364.
89	Liu J , Xiao J , Wang D , et al . Construction and photocatalytic activities of a series of isostructural Co²⁺/Zn²⁺ metal-doped metal-organic frameworks[J]. Crystal Growth & Design, 2017, 17(3): 1096-1102.
90	Wen M , Kuwahara Y , Mori K , et al . Synthesis of Ce ions doped metal-organic framework for promoting catalytic H₂ production from ammonia borane under visible light irradiation[J]. Journal of Materials Chemistry A, 2015, 3(27): 14134-14141.
91	Lee Y , Kim S , Fei H , et al . Photocatalytic CO₂ reduction using visible light by metal-monocatecholato species in a metal-organic framework[J]. Chemical Communications, 2015, 51(92): 16549-16552.
92	Li Q Y , Ma Z , Zhang W Q , et al . AIE-active tetraphenylethene functionalized metal-organic framework for selective detection of nitroaromatic explosives and organic photocatalysis[J]. Chemical Communications, 2016, 52(75): 11284-11287.
93	Wu P , He C , Wang J , et al . Photoactive chiral metal-organic frameworks for light-driven asymmetric α-alkylation of aldehydes[J]. Journal of the American Chemical Society, 2012, 134(36): 14991-14999.
94	Fu Y , Sun D , Chen Y , et al . An amine-functionalized titanium metal-organic framework photocatalyst with visible-light-induced activity for CO₂ reduction[J]. Angewandte Chemie International Edition, 2012, 51(14): 3364-3367.
95	Sun D , Fu Y , Liu W , et al . Studies on photocatalytic CO₂ reduction over NH₂-UiO-66(Zr) and its derivatives: towards a better understanding of photocatalysis on metal-organic frameworks[J]. Chemistry-A European Journal, 2013, 19(42): 14279-14285.
96	Fei H , Sampson M D , Lee Y , et al . Photocatalytic CO₂ reduction to formate using a Mn (I) molecular catalyst in a robust metal-organic framework[J]. Inorganic Chemistry, 2015, 54(14): 6821-6828.
97	Wang D , Huang R , Liu W , et al . Fe-based MOFs for photocatalytic CO₂ reduction: role of coordination unsaturated sites and dual excitation pathways[J]. ACS Catalysis, 2014, 4(12): 4254-4260.
98	Bhattacharjee S , Lee Y R , Puthiaraj P , et al . Metal-organic frameworks for catalysis[J]. Catalysis Surveys from Asia, 2015, 19(4): 203-222.
99	Lei Z , Xue Y , Chen W , et al . MOFs-based heterogeneous catalysts: new opportunities for energy-related CO₂ conversion[J]. Advanced Energy Materials, 2018, 8(32): 1801587.
100	Zhang S , Han L , Li L , et al . A highly symmetric metal-organic framework based on a propeller-like Ru-organic metalloligand for photocatalysis and explosives detection[J]. Crystal Growth & Design, 2013, 13(12): 5466-5472.
101	Kim D , Whang D R , Park S Y . Self-healing of molecular catalyst and photosensitizer on metal-organic framework: robust molecular system for photocatalytic H₂ evolution from water[J]. Journal of the American Chemical Society, 2016, 138(28): 8698-8701.

催化剂种类	物理微环境调控	应用领域	光催化活性	参考文献
NH₂-MIL-125	沉积Pt	CO₂还原	587.5 μmol?h^–1?g^–1	Sun等^[48]
UiO-66	沉积Au@Pd	产氢	42000 ml?h^–1?g^–1	Wen等^[49]
Co-ZIF-9	沉积Ag	CO₂还原	56800 μmol?h^–1?g^–1	Chen等^[50]
MIL-125	沉积Pt和Au	产氢	1743.0 μmol?h^–1?g^–1	Xiao等^[51]
UiO-66	复合g-C₃N₄	产氢	比物理混合性能高17倍	Wang等^[52]
MIL-53	复合 g-C₃N₄	Cr(Ⅵ)还原	比MIL-53性能高2.0倍	Huang等^[53]
ZIF-8	复合 g-C₃N₄	CO₂还原	0.75 μmol?h^–1?g^–1	Liu等^[54]
NH₂-UiO-66	复合TpPa-1-COF	产氢	23.41 μmol?h^–1?g^–1	Zhang等^[55]
NH₂-MIL-125或NH₂-UiO-66	复合B-CTF-1	产氢	360 μmol?h^–1?g^–1	Li等^[56]
NH₂-MIL-68	复合TPA-COF	降解罗丹明B	降解率100%(40 min)	Peng等^[57]
NH₂-MIL-125	复合LZU1	苯乙烯加氢	转化率100%(15 min)	Sun等^[58]
NH₂-MIL-125	复合TTB-TTA	降解甲基橙	降解率100%(20 min)	He等^[59]
Ru-MOF	形貌调控	CO₂还原	77.2 μmol?h^–1?g^–1	Zhang等^[60]
Cd-TBAPy	形貌调控	全解水	产氧速率1634 μmol?h^–1?g^–1	Xiao等^[61]
Ni-MOF	形貌调控	产氢	45201 μmol?h^–1?g^–1	Qiao等^[62]
ZIF-67	形貌调控	CO₂还原	3890 μmol?h^–1?g^–1	Wang等^[63]
Ni-MOF	缺陷构造	CO₂还原	16000 μmol?h^–1?g^–1	Niu等^[64]
NH₂-MIL-125	孔道封装Co(Ⅱ)	产氢	比NH₂-MIL-125高32倍	Jiang等^[65]

催化剂种类	物理微环境调控	应用领域	光催化活性	参考文献
NH₂-MIL-125	沉积Pt	CO₂还原	587.5 μmol?h^–1?g^–1	Sun等^[48]
UiO-66	沉积Au@Pd	产氢	42000 ml?h^–1?g^–1	Wen等^[49]
Co-ZIF-9	沉积Ag	CO₂还原	56800 μmol?h^–1?g^–1	Chen等^[50]
MIL-125	沉积Pt和Au	产氢	1743.0 μmol?h^–1?g^–1	Xiao等^[51]
UiO-66	复合g-C₃N₄	产氢	比物理混合性能高17倍	Wang等^[52]
MIL-53	复合 g-C₃N₄	Cr(Ⅵ)还原	比MIL-53性能高2.0倍	Huang等^[53]
ZIF-8	复合 g-C₃N₄	CO₂还原	0.75 μmol?h^–1?g^–1	Liu等^[54]
NH₂-UiO-66	复合TpPa-1-COF	产氢	23.41 μmol?h^–1?g^–1	Zhang等^[55]
NH₂-MIL-125或NH₂-UiO-66	复合B-CTF-1	产氢	360 μmol?h^–1?g^–1	Li等^[56]
NH₂-MIL-68	复合TPA-COF	降解罗丹明B	降解率100%(40 min)	Peng等^[57]
NH₂-MIL-125	复合LZU1	苯乙烯加氢	转化率100%(15 min)	Sun等^[58]
NH₂-MIL-125	复合TTB-TTA	降解甲基橙	降解率100%(20 min)	He等^[59]
Ru-MOF	形貌调控	CO₂还原	77.2 μmol?h^–1?g^–1	Zhang等^[60]
Cd-TBAPy	形貌调控	全解水	产氧速率1634 μmol?h^–1?g^–1	Xiao等^[61]
Ni-MOF	形貌调控	产氢	45201 μmol?h^–1?g^–1	Qiao等^[62]
ZIF-67	形貌调控	CO₂还原	3890 μmol?h^–1?g^–1	Wang等^[63]
Ni-MOF	缺陷构造	CO₂还原	16000 μmol?h^–1?g^–1	Niu等^[64]
NH₂-MIL-125	孔道封装Co(Ⅱ)	产氢	比NH₂-MIL-125高32倍	Jiang等^[65]

催化剂种类	化学微环境调控	应用领域	光催化活性	参考文献
MIL100、MOF-74	Sc、Zn、Mg与Ti离子交换	降解亚甲基蓝	降解率＞98%(3 min)	Zou等^[85]
NH₂-UiO-66	Ti、Zr离子交换	CO₂还原	最高转换数为6.50	Lee等^[86]
NH₂-UiO-66	Ti、Zr离子交换	产氢	389 μmol?h^-1?mol^-1	Sun等^[87]
NH₂-UiO-66	Ti、Zr离子交换	还原Se(Ⅵ)	还原率100%	Tu等^[88]
M(tpbpc)_0.5(bdc)_0.5·H₂O	Co、Zn离子交换	降解甲基橙	降解率100%(1.5 h)	Liu等^[89]
Pd/MlL-101	Ce、Cr离子交换	产氢	495 μmol?h^-1?g^-1	Wen等^[90]
UiO-66	Zr、Ga离子交换	CO₂还原	9.06 μmol?h^-1	Lee等^[91]
UiO-68	配体H₂mtpdc引入H₂etpdc	CDC反应	产率93%	Li等^[92]
Zn-PYIs	配体BCIP转换PYIs	醛α-烷基化	转化率74%	Wu等^[93]
NH₂-MIL-125	配体ATA中引入氨基	CO₂还原	16.28 μmol?h^-1?g^-1	Fu等^[94]
NH₂-UiO-66	配体ATA中混合DTA	CO₂还原	41.4 μmol?h^-1?g^-1	Sun等^[95]
UiO-67	配体H₂bpdc引入Mn(bpy)(CO)₃Br	CO₂还原	量子产率13.8%	Fei等^[96]

催化剂种类	化学微环境调控	应用领域	光催化活性	参考文献
MIL100、MOF-74	Sc、Zn、Mg与Ti离子交换	降解亚甲基蓝	降解率＞98%(3 min)	Zou等^[85]
NH₂-UiO-66	Ti、Zr离子交换	CO₂还原	最高转换数为6.50	Lee等^[86]
NH₂-UiO-66	Ti、Zr离子交换	产氢	389 μmol?h^-1?mol^-1	Sun等^[87]
NH₂-UiO-66	Ti、Zr离子交换	还原Se(Ⅵ)	还原率100%	Tu等^[88]
M(tpbpc)_0.5(bdc)_0.5·H₂O	Co、Zn离子交换	降解甲基橙	降解率100%(1.5 h)	Liu等^[89]
Pd/MlL-101	Ce、Cr离子交换	产氢	495 μmol?h^-1?g^-1	Wen等^[90]
UiO-66	Zr、Ga离子交换	CO₂还原	9.06 μmol?h^-1	Lee等^[91]
UiO-68	配体H₂mtpdc引入H₂etpdc	CDC反应	产率93%	Li等^[92]
Zn-PYIs	配体BCIP转换PYIs	醛α-烷基化	转化率74%	Wu等^[93]
NH₂-MIL-125	配体ATA中引入氨基	CO₂还原	16.28 μmol?h^-1?g^-1	Fu等^[94]
NH₂-UiO-66	配体ATA中混合DTA	CO₂还原	41.4 μmol?h^-1?g^-1	Sun等^[95]
UiO-67	配体H₂bpdc引入Mn(bpy)(CO)₃Br	CO₂还原	量子产率13.8%	Fei等^[96]

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金属有机框架光催化剂微环境调控研究进展

Research progress on microenvironment regulation of metal-organic framework photocatalyst

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