钙钛矿催化剂在生物质热化学利用领域的研究进展

doi:10.11949/0438-1157.20211000

摘要/Abstract

摘要：

钙钛矿催化剂优异的氧化还原性能、离子迁移率、热稳定性和较低的生产成本，使得其在生物质热化学利用领域具有广阔的应用前景。基于生物质热解/气化、生物质重整制氢和生物质下游产物化学合成等应用场景，重点阐述并总结了钙钛矿催化剂的催化性能和机制。聚焦于金属阳离子的催化作用和晶格氧的氧化还原作用，从A/B位离子取代、空间结构改变等方面总结了钙钛矿催化剂的优化设计方法。为钙钛矿催化剂在生物质热化学利用领域的应用与优化指明了方向。

关键词: 生物质, 钙钛矿, 催化, 晶格氧, 离子取代, 优化

Abstract:

Perovskites have good application prospects in biomass thermochemical utilization due to their excellent redox performance, ion mobility, thermal stability and low cost. Perovskite catalysts are mainly used in biomass pyrolysis/gasification, biomass reforming and chemical synthesis of biomass downstream products. This paper focused on the catalytic performance and the catalytic mechanism of the perovskite catalysts. Furthermore, based on the catalysis of metal cations and the redox of lattice oxygen, the optimization design of perovskite catalysts were summarized from the aspects of ion substitution at A/B sites and space structure change. It points out the direction for the application and optimization of the perovskite catalyst in the field of biomass thermochemical utilization.

Key words: biomass, perovskites, catalysis, lattice oxygen, ion substitution, optimization

中图分类号:

TK 6

董晓珊, 李健, 颜蓓蓓, 陈冠益. 钙钛矿催化剂在生物质热化学利用领域的研究进展[J]. 化工学报, 2022, 73(2): 504-520.

Xiaoshan DONG, Jian LI, Beibei YAN, Guanyi CHEN. Research progress of perovskite catalysts in thermochemical utilization of biomass[J]. CIESC Journal, 2022, 73(2): 504-520.

图/表 5

参考文献 80

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