Effect of bio-oil on properties of bio-oil starch adhesive

doi:10.11949/j.issn.0438-1157.20180244

Abstract

Abstract:

Biomass is abundant and widely distributed in China. Fast pyrolysis of this renewable resource for bio-oil, a high quality starting material for chemical industry, is considered to be one of the most promising approaches for the achievement of its high value and efficient application. The basic performance of environment-friendly bio-oil starch adhesive (BOS adhesive) prepared from bio-oil was investigated. The results showed that the wet bonding strength of BOS adhesive reached the ClassⅡ of Chinese Standard GB/T 17657 and the viscosity of this adhesive met well with the production demands of plywood industry. The rheological behavior of this BOS adhesive showed obvious shear-thinning characteristic, which meant that the BOS adhesive was typical pseudoplastic fluid. The low △E_η value of BOS adhesive (9.67 kJ·mol^-1) indicated that this adhesive has good liquidity, making it a great potential for industrial application and promotion. Comparative investigation on the strength, rheological property and thermal stability of BOS adhesive with different bio-oil content demonstrated that the bio-oil could improve the water resistance and thermal stability of BOS adhesive, and had a positive impact on the curing characteristics of BOS adhesive.

Key words: biomass, pyrolysis, bio-oil, bio-based adhesive, rheology, thermostability

摘要：

我国的生物质资源丰富，将其快速热解成生物油，作为优质化工原料应用，可实现其高值高效应用。本文对以生物油制备的环境友好型生物油淀粉胶黏剂基本性能进行研究，结果表明，其湿胶合强度可达到国标Ⅱ类胶合板标准，其黏度可以满足胶合板工业化生产需求；生物油淀粉胶黏剂流变行为呈现出明显的剪切变稀特征，是典型的假塑性流体，流动活化能△E_η为9.67 kJ·mol^-1，表明其具有良好的流动性和应用潜力；通过对比不同生物油加入量的BOS胶黏剂湿胶合强度、流变性和热稳定性的研究发现，生物油的加入可改善BOS胶黏剂的耐水性，促进其固化，并增强其热稳定性。

关键词: 生物质, 热解, 生物油, 生物基胶黏剂, 流变学, 热稳定性

CLC Number:

TQ431

ZHANG Jizong, CHANG Houchun, CHANG Jianmin, LONG Jinxing, LI Xuehui. Effect of bio-oil on properties of bio-oil starch adhesive[J]. CIESC Journal, 2018, 69(S1): 123-128.

张继宗, 常厚春, 常建民, 龙金星, 李雪辉. 生物油对生物油基淀粉胶黏剂性能的影响[J]. 化工学报, 2018, 69(S1): 123-128.

References 32

[1]	石元春. 中国生物质原料资源[J]. 中国工程科学, 2011, 13(2):16-23. SHI Y C. China's resources of biomass feedstock[J]. Eng. Sci., 2011, 13(2):16-23.
[2]	隋海清, 李攀, 王贤华, 等. 生物质热解气分级冷凝对生物油特性的影响[J]. 化工学报, 2015, 66(10):4138-4144. SUI H Q, LI P, WANG X H, et al. Influence on bio-oil by fractional condensation of biomass pyrolysis vapor[J]. CIESC Journal, 2015, 66(10):4138-4144.
[3]	BRIDGWATER A V. Review of fast pyrolysis of biomass and product upgrading[J]. Biomass. Bioenerg., 2012, 38(2):68-94.
[4]	GARCIAPEREZ M, CHAALA A, PAKDEL H, et al. Characterization of bio-oils in chemical families[J]. Biomass. Bioenerg., 2007, 31(4):222-242.
[5]	NAIK D K, MONIKA K, PRABHAKAR S, et al. Pyrolysis of sorghum bagasse biomass into bio-char and bio-oil products[J]. J. Therm. Anal. Calorim., 2017, 127(2):1277-1289.
[6]	SMITH E A, LEE Y J. Petroleomic analysis of bio-oils from the fast pyrolysis of biomass:laser desorption ionization-linear ion trap-orbitrap mass spectrometry approach[J]. Energ. Fuel., 2010, 24(3):5190-5198.
[7]	ELKASABI Y, MULLEN C A, JACKSON M A, et al. Characterization of fast-pyrolysis bio-oil distillation residues and their potential applications[J]. J. Anal. Appl. Pyrol., 2015, 114:179-186.
[8]	JOSEPH J, RASMUSSEN M J, FECTEAU J P, et al. Compositional changes to low water content bio-oils during aging:an NMR, GC/MS, and LC/MS study[J]. Energ. Fuel., 2016, 30(6):4825-4840.
[9]	MARSMAN J H, WILDSCHUT J, MAHFUD F, et al. Identification of components in fast pyrolysis oil and upgraded products by comprehensive two-dimensional gas chromatography and flame ionisation detection[J]. J. Chromatogr. A, 2007, 1150(1/2):21.
[10]	KIM S J, JUNG S H, KIM J S. Fast pyrolysis of palm kernel shells:influence of operation parameters on the bio-oil yield and the yield of phenol and phenolic compounds[J]. Bioresource. Technol., 2010, 101(23):9294.
[11]	GARCIA-PEREZ M, SHEN J, WANG X S, et al. Production and fuel properties of fast pyrolysis oil/bio-diesel blends[J]. Fuel Process. Technol., 2010, 91(3):296-305.
[12]	LEHTO J, OASMAA A, SOLANTAUSTA Y, et al. Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass[J]. Appl. Energ., 2014, 116(3):178-190.
[13]	OASMAA A, BELD B V D, SAARI P, et al. Norms, standards, and legislation for fast pyrolysis bio-oils from lignocellulosic biomass[J]. Energ. Fuel., 2015, 29(4):2471-2484.
[14]	PEREIRA J, AGBLEVOR F A, BEIS S H. The influence of process conditions on the chemical composition of pine wood catalytic pyrolysis oils[J]. ISRN Renew. Energ., 2012, 2012(1/2). doi:10.5402/2012/167629.
[15]	KOIKE N, HOSOKAI S, TAKAGAKI A, et al. Upgrading of pyrolysis bio-oil using nickel phosphide catalysts[J]. J. Catal., 2016, 333:115-126.
[16]	OASMAA A, ELLIOTT D C, MÜLLER S. Quality control in fast pyrolysis bio-oil production and use[J]. Environ. Prog. Sustain. Energ., 2009, 28(3):404-409.
[17]	AMEN-CHEN C, PAKDEL H, ROY C. Production of monomeric phenols by thermochemical conversion of biomass:a review[J]. Bioresour. Technol., 2001, 79:277-299.
[18]	FAN D, CHANG J, GOU J, et al. On the cure acceleration of oil-phenol-formaldehyde resins with different catalysts[J]. J. Adhesion, 2010, 86(8):836-845.
[19]	CUI Y, HOU X, WANG W, et al. Synthesis and characterization of bio-oil phenol formaldehyde resin used to fabricate phenolic based materials[J]. Materials, 2017, 10(6):668.
[20]	ELKASABI Y, MULLEN C A, JACKSON M A, et al. Characterization of fast-pyrolysis bio-oil distillation residues and their potential applications[J]. J. Anal. Appl. Pyrol., 2015, 114:179-186.
[21]	ZHANG Z B, QIANG L, YE X N, et al. Production of phenolic-rich bio-oil from catalytic fast pyrolysis of biomass using magnetic solid base catalyst[J]. Energ. Convers. Manage., 2015, 106:1309-1317.
[22]	GYUNGGOO C, SEUNGJIN O, SOONJANG L, et al. Production of bio-based phenolic resin and activated carbon from bio-oil and biochar derived from fast pyrolysis of palm kernel shells[J]. Bioresource. Technol., 2015, 178:99-107.
[23]	张继宗, 张琪, 常建民. 生物油淀粉胶黏剂制备工艺研究[J]. 现代化工, 2013, 33(6):62-65. ZHANG J Z, ZHANG Q, CHANG J M. Preparation process of bio-oil starch adhesive[J]. Mod. Chem. Ind., 2013, 33(6):62-65.
[24]	尚小琴, 赖雅平, 陈展云,等. 淀粉丙烯酰胺表面控制反应机理及接枝产物结构表征[J]. 化工学报, 2007, 58(8):2110-2114. SHI X Q, LAI Y P, CHEN Z Y, et al. Mechanism of surface control reaction and characterization of graft copolymers of acrylamide onto starch[J]. J. Chem. Ind. Eng.(China), 2007, 58(8):2110-2114.
[25]	WANG Z J, GU Z, HONG Y, et al. Bonding strength and water resistance of starch-based wood adhesive improved by silica nanoparticles[J]. Carbohyd. Polym., 2011, 86(1):72-76.
[26]	WANG S M, SHI J Y, XU W. Synthesis and characterization of starch-based aqueous polymer isocyanate wood adhesive[J]. BioResources, 2015, 10(4):7653-7666.
[27]	RAMIRES E C, MEGIATTO J D, GARDRAT C, et al. Biobased composites from glyoxal-phenolic resins and sisal fibers[J]. Bioresour. Technol., 2010, 101(6):1998-2006.
[28]	顾继友. 胶黏剂与涂料[M].2版. 北京:中国林业出版社, 2012. GU J Y. Adhesives and Coatings[M]. 2nd ed. Beijing:China Forestry Publishing House, 2012.
[29]	顾蓉, 张佳, 郭康权, 等. 葡甘聚糖-壳聚糖-聚乙烯醇复合胶黏剂的流变特性[J]. 复合材料学报, 2011, 28(1):37-42. GU R, ZHANG J, GUO K Q, et al. Rheological properties of konjac glucomannan-chitosan-PVA blending adhesive[J]. Acta Mater. Compos. Sin., 2011, 28(1):37-42.
[30]	WU Q, OGASAWARA T, YOSHIKAWA N, et al. Modeling the viscoelasticity of polyetherimide[J]. J. Appl. Polym. Sci., 2018, 135(15):46102.
[31]	JAHANDIDEH A, MUTHUKUMARAPPAN K. Synthesis, characterization and curing optimization of a biobased thermosetting resin from xylitol and lactic acid[J]. Eur. Polym. J., 2016, 83:344-358.
[32]	LÓPEZ D, CENDOYA I, TORRES F, et al. Preparation and characterization of poly(vinyl alcohol)-based magnetic nanocomposites (1):Thermal and mechanical properties[J]. J. Appl. Polym. Sci., 2001, 82(13):3215-3222.