化工进展

• 工业催化 • 上一篇    下一篇

Br?nsted-Lewis双酸性离子液体的合成与应用

王金龙,何志强,吴业帆,方 云   

  1. 江南大学化学与材料工程学院食品胶体与生物技术教育部重点实验室,江苏 无锡 214122
  • 出版日期:2012-11-05 发布日期:2012-11-07

Synthesis and application of Br?nsted-Lewis acidic ionic liquids

WANG Jinlong,HE Zhiqiang,WU Yefan,FANG Yun   

  1. MOE Key Laboratory of Food Colloids and Biotechnology,School of Chemical & Material Engineering,Jiangnan University,Wuxi 214122, Jiangsu, China
  • Online:2012-11-05 Published:2012-11-07

摘要: Br?nsted-Lewis双酸性离子液体同时具备B酸性和L酸性,是融合双酸性固体酸与离子液体的特征发展起来的一类新型催化剂。本文综述了近年来B-L双酸性离子液体的合成、表征及催化剂应用等方面的进展,在此基础上,总结出B-L双酸性离子液体的三个特征。其一,利用一种催化剂就可以催化分别需要B酸和L酸催化的分步反应,使反应一锅化,简洁可控。其二,B酸性和L酸性之间存在相互增强的协同作用,使其具有更好的催化性能,或可提高反应转化率或产物选择性。其三,液体催化剂在传质和扩散等方面均优于双酸性固体酸。上述特征使B-L双酸性离子液体替代并超越传统酸性催化剂成为可能,在工业应用中显示良好的发展前景。

关键词: 离子液体, Br?nsted-Lewis双酸性离子液体, 催化剂

Abstract: Br?nsted-Lewis acidic ionic liquids are a novel type of catalysts which combine the characters of the Br?nsted-Lewis solid acids and the ionic liquids. Three characteristics of the B-L acidic ionic liquids are summarized in this paper based on the advance of synthetic route, characterization methods and applications of them nowadays. First, the B-L acidic ionic liquids make it possible that a step-by-step reaction is completed in one pot, in which B acid and L acid were added separately in different steps. Furthermore, a synergetic effect of B and L acid sites enhances the catalytic performance, which makes the B-L acidic ionic liquids raise the substrate conversion or product selectivity. The last but not the least, the B-L acidic ionic liquids have better performance in mass transfer and diffusion than B-L solid acids. These above features make the B-L acidic ionic liquids become a competitor of traditional acid catalysts, which reveals that the B-L acidic ionic liquids have good development prospects in industrial catalysis field.

Key words: ionic liquid, Br?nsted-Lewis acidic ionic liquid, catalyst