R1233zd(E)在[HMIM][PF6]中的溶解度和扩散系数的实验测量和理论计算

doi:10.11949/0438-1157.20190544

摘要/Abstract

摘要：

R1233zd(E)具有无毒、环保、不可燃等优点，而离子液体具有较宽的液体温度范围和良好的物理化学性质。R1233zd(E)和离子液体相结合可以成为一种优良的吸收式制冷工质对。测量了R1233zd(E)在[HMIM][PF₆]离子液体中的溶解度和扩散系数，温度测量范围为303.2~343.2 K，压力测量范围为23~140 kPa。为了方便工业化应用，采用NRTL方程和Arrhenius方程对实验结果进行了关联，计算结果和实验数据之间的平均偏差和最大偏差分别为2.45%和6.13%。

关键词: 扩散系数, 溶解度, 离子液体, 压力衰减法

Abstract:

R1233zd (E) has the advantages of non-toxic, environmentally friendly, non-flammable, and the ionic liquid has a wide liquid temperature range and good physicochemical properties. The combination of R1233zd(E) and ionic liquids can be an excellent pair of absorption refrigeration. In this paper, the solubility and diffusion coefficient of R1233zd (E) in [HMIM][PF₆] ionic liquid were measured. The temperature measurement range was 303.2—343.2 K, and the pressure measurement range was 23—140 kPa. In order to facilitate industrial application, the experimental results were correlated by NRTL equation and Arrhenius equation. The average deviation and maximum deviation between the calculated results and experimental data were 2.45% and 6.13%, respectively.

Key words: diffusion coefficient, solubility, ionic liquid, pressure decay method

中图分类号:

TQ 021.2

刘向阳,何茂刚. R1233zd(E)在[HMIM][PF₆]中的溶解度和扩散系数的实验测量和理论计算[J]. 化工学报, 2019, 70(S2): 44-49.

Manh Quang NGUYEN. Experimental measurement and theoretical calculation of solubility and diffusion coefficient of R1233zd(E) in [HMIM][PF₆][J]. CIESC Journal, 2019, 70(S2): 44-49.

图/表 7

图1 实验系统

Fig.1 Schematic diagram of experimental system

表1 R1233zd(E)在离子液体[HMIM][PF6]中溶解度的实验结果

Table 1 Experimental results of solubility of R1233zd(E) in ionic liquid [HMIM][PF6]

T/K	p/ kPa	x	T/K	p/kPa	x
303.2	23.02	0.016	323.2	81.92	0.05
303.2	37.44	0.03	323.2	108.3	0.069
303.2	50.26	0.043	333.2	36.48	0.01
303.2	63.34	0.057	333.2	55.82	0.021
303.2	81.58	0.079	333.2	74.18	0.033
313.2	27.21	0.014	333.2	94.31	0.045
313.2	41.67	0.027	333.2	123.8	0.063
313.2	57.32	0.04	343.2	40.93	0.008
313.2	72.47	0.054	343.2	64.48	0.018
313.2	93.88	0.074	343.2	85.33	0.029
323.2	31.37	0.013	343.2	106.4	0.04
323.2	47.93	0.025	343.2	142.3	0.057
323.2	65.24	0.037

图2 R1233zd(E)在离子液体[HMIM][PF6]中的溶解度

Fig.2 Solubility of R1233zd(E) in ionic liquid [HMIM][PF6]

表2 R1233zd(E)在离子液体[HMIM][PF6]中的扩散系数和亨利常数实验结果

Table 2 Experimental results of diffusion coefficient and Henry’s constant of R1233zd(E) in ionic liquid [HMIM][PF6]

T/K	H/MPa	D×10¹⁰/(m²·s^-1)
303.2	1.4604	0.9724
313.2	1.9248	1.4506
323.2	2.3614	2.0671
333.2	3.486	3.1289
343.2	4.8601	4.4513

图3 R1233zd(E)在离子液体[HMIM][PF6]中亨利常数和扩散系数

Fig.3 Henry’s constant and diffusion coefficient of R1233zd(E) in ionic liquid [HMIM][PF6]

表3 NRTL方程的拟合参数和误差

Table 3 Fitting parameters and errors of NRTL equation

α	$τ_{12}^{0}$	$τ_{12}^{1}$	$τ_{21}^{0}$	$τ_{21}^{1}$	AARD/%	MD/%
0.013	-0.60982	869.04	626.12	3066.11	2.45	6.13

表3 NRTL方程的拟合参数和误差

Table 3 Fitting parameters and errors of NRTL equation

α	$τ_{12}^{0}$	$τ_{12}^{1}$	$τ_{21}^{0}$	$τ_{21}^{1}$	AARD/%	MD/%
0.013	-0.60982	869.04	626.12	3066.11	2.45	6.13

表4 Arrhenius 方程的拟合参数和误差

Table 4 Fitting parameters and errors of Arrhenius equation

A	-B	AARD/%	MD/%
612117.9	-33758.8	1.91	4.12

参考文献 30

1	ZhangH, XuanG, YangD, et al. Emergy analysis of organic Rankine cycle (ORC) for waste heat power generation[J]. Journal of Cleaner Production, 2018, 183: 1207-1215.
2	ManzelaA A, HanriotS M, Cabezas-GómezL, et al. Using engine exhaust gas as energy source for an absorption refrigeration system[J]. Applied Energy, 2010, 87(4): 1141-1148.
3	LiQ, SunZ, WangH, et al. Insight into the enhanced CO₂ photocatalytic reduction performance over hollow-structured bi-decorated g-C₃N₄nanohybrid under visible-light irradiation[J]. Journal of CO₂ Utilization, 2018, 28: 126-136.
4	SalmiW, VanttolaJ, ElgM, et al. Using waste heat of ship as energy source for an absorption refrigeration system[J]. Applied Thermal Engineering, 2017, 115(Complete): 501-516.
5	EbrahimiK, JonesG F, FleischerA S. Thermo-economic analysis of steady state waste heat recovery in data centers using absorption refrigeration[J]. Applied Energy, 2015, 139: 384-397.
6	李星, 徐士鸣, 李见波. 基于R124-DMAC为工质对的余热吸收式制冷[J]. 化工学报, 2015, 66(5): 1883-1890.
	LiX, XuS M, LiJ B. Absorption refrigeration cycle driven by waste heat using R124-DMAC as working fluids[J]. CIESC Journal, 2015, 66(5): 1883-1890.
7	王刚, 解国珍, 王亮亮. 溴化锂吸收式循环的内外热物理参数与机组制冷特性耦合[J]. 化工学报, 2012, 63(S2): 1-7.
	WangG, XieG Z, WangL L. Coupling of lithium bromide absorption cycle inside and outside thermal physical parameters and refrigeration unit characteristics[J]. CIESC Journal, 2012, 63(S2): 1-7.
8	FarshiL G, FerreiraC A I, MahmoudiS M S, et al. First and second law analysis of ammonia/salt absorption refrigeration systems[J]. International Journal of Refrigeration, 2014, 40(4): 111-121.
9	刘向阳, 潘培, 彭三国, 等. 氢氟烃在离子液体[HMIM][PF₆]中的扩散系数和亨利常数[J]. 化工学报, 2017, 68(12): 4486-4493.
	LiuX Y, PanP, PengS G, et al. Diffusion coefficients and Henry’s constants of six hydrofluorocarbons in ionic liquid [HMIM][PF₆][J]. CIESC Journal, 2017, 68(12): 4486-4493.
10	RenW, ScurtoA M. Phase equilibria of imidazolium ionic liquids and the refrigerant gas, 1, 1, 1, 2-tetrafluoroethane (R-134a)[J]. Fluid Phase Equilibria, 2009, 286(1): 1-7.
11	WuW, WangB, ShiW, et al. Absorption heating technologies: a review and perspective[J]. Applied Energy, 2014, 130(Complete): 51-71.
12	WangK, AbdelazizO, KisariP, et al. State-of-the-art review on crystallization control technologies for water/LiBr absorption heat pumps[J]. International Journal of Refrigeration, 2011, 34(6): 1325-1337.
13	AndersonJ L, DixonJ K, BrenneckeJ F. Solubility of CO₂, CH₄, C₂H₆, C₂H₄, O₂, and N₂ in 1-hexyl-3 -methylpyridinium bis (trifluoromethylsulfonyl)imide: comparison to other ionic liquids[J]. Accounts of Chemical Research, 2007, 40 (11): 1208-1216.
14	ZhangS, SunN, HeX, et al. Physical properties of ionic liquids: database and evaluation[J]. Journal of Physical & Chemical Reference Data, 2006, 35(4): 1475-1517.
15	KimS, KohlP A . Theoretical and experimental investigation of an absorption refrigeration system using R134/[bmim][PF₆] working fluid[J]. Industrial & Engineering Chemistry Research, 2013, 52(37): 13459–13465.
16	FallanzaM, OrtizA, GorriD, et al. Propylene and propane solubility in imidazolium, pyridinium, and tetralkylammonium based ionic liquids containing a silver salt[J]. Journal of Chemical & Engineering Data, 2013, 58(8): 2147-2153.
17	LiuX, HeM, LvN, et al. Solubilities of R-161 and R-143a in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide[J]. Fluid Phase Equilibria, 2015, 388: 37-42.
18	ShiflettM B, YokozekiA. Gaseous absorption of fluoromethane, fluoroethane, and 1, 1, 2, 2-tetrafluoroethane in 1-butyl-3- methylimidazolium hexafluorophosphate[J]. Industrial & Engineering Chemistry Research, 2006, 45(18): 6375-6382.
19	MondéjarM E, McLindenM D, LemmonE W. Thermodynamic properties of trans-1-chloro-3, 3, 3- trifluoropropene (R1233zd(E)): vapor pressure, (p, ρ, T) behavior, and speed of sound measurements, and equation of state[J]. Journal of Chemical & Engineering Data, 2015, 60(8): 2477-2489.
20	HulseR J, BasuR S, SinghR R, et al. Physical properties of HCFO-1233zd (E)[J]. Journal of Chemical & Engineering Data, 2012, 57(12): 3581-3586.
21	SánchezD, CabelloR, LlopisR, et al. Energy performance evaluation of R1234yf, R1234ze (E), R600a, R290 and R152a as low-GWP R134a alternatives[J]. International Journal of Refrigeration, 2017, 74: 269-282.
22	CamperD, BeckerC, KovalC, et al. Diffusion and solubility measurements in room temperature ionic liquids[J]. Industrial & Engineering Chemistry Research, 2006, 45(1): 445-450.
23	ShokouhiM, AdibiM, JaliliA H, et al. Solubility and diffusion of H₂S and CO₂ in the ionic liquid 1-(2-hydroxyethyl) -3-methylimidazolium tetrafluoroborate[J]. Journal of Chemical & Engineering Data, 2010, 55(4): 1663-1668.
24	LiuX, PanP, YangF, et al. Solubilities and diffusivities of R227ea, R236fa and R245fa in 1-hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide[J]. The Journal of Chemical Thermodynamics, 2018, 123: 158-164.
25	ShokouhiM, AdibiM, JaliliA H, et al. Solubility and diffusion of H₂S and CO₂ in the ionic liquid 1-(2-hydroxyethyl) -3-methylimidazolium tetrafluoroborate[J]. Journal of Chemical & Engineering Data, 2010, 55(4): 1663-1668.
26	MaogangH, PeiP, FengY, et al. Gaseous absorption of trans-1-chloro-3,3,3-trifluoropropene in three immidazolium-based ionic liquids[J]. Journal of Chemical and Engineering Data, 2018, 63: 1780-1788.
27	RenonH, PrausnitzJ M. Local compositions in thermodynamic excess functions for liquid mixtures[J]. AIChE Journal, 1968, 14(1): 135-144.
28	ShiflettM B, YokozekiA. Solubility and diffusivity of hydrofluorocarbons in room‐temperature ionic liquids[J]. AIChE Journal, 2006, 52(3): 1205-1219.
29	KrynickiK, GreenC D, SawyerD W. Pressure and temperature dependence of self-diffusion in water[J]. Faraday Discussions of the Chemical Society, 1978, 66: 199-208.
30	RichterJ, LeuchterA, GroßerN. Digital image holography for diffusion measurements in molten salts and ionic liquids—method and first results[J]. Journal of Molecular Liquids, 2003, 103: 359-370.

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R1233zd(E)在[HMIM][PF₆]中的溶解度和扩散系数的实验测量和理论计算

Experimental measurement and theoretical calculation of solubility and diffusion coefficient of R1233zd(E) in [HMIM][PF₆]

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