负载型离子液体吸附分离CO2的研究现状及展望

doi:10.11949/0438-1157.20220600

化工学报 ›› 2022, Vol. 73 ›› Issue (10): 4268-4284.DOI: 10.11949/0438-1157.20220600

负载型离子液体吸附分离CO₂的研究现状及展望

吴建猛¹^,²^,³(), 郑爽³, 曾少娟¹^,³(), 张香平¹^,³, 杨灿²^,³, 董海峰¹^,³

^1.先进能源科学与技术广东省实验室，广东惠州 516227
^2.郑州大学化工学院，先进功能材料制造教育部工程研究中心，河南郑州 450001
^3.中国科学院过程工程研究所，多相复杂系统国家重点实验室，离子液体清洁过程北京市重点实验室，北京 100190

收稿日期:2022-04-05 修回日期:2022-06-23 出版日期:2022-10-05 发布日期:2022-11-02
通讯作者: 曾少娟
作者简介:吴建猛（1998—），男，硕士研究生，wujianmeng2021@ipe.ac.cn
基金资助:
国家重点研发计划项目(2020YFA0710200);国家自然科学基金项目(21890764);山西省科技重大专项项目(20201102005);中国科学院青年创新促进会项目(2018064)

Status and prospect on CO₂adsorption and separation by supported ionic liquids

Jianmeng WU¹^,²^,³(), Shuang ZHENG³, Shaojuan ZENG¹^,³(), Xiangping ZHANG¹^,³, Can YANG²^,³, Haifeng DONG¹^,³

^1.Advanced Energy Science and Technology Guangdong Laboratory, Huizhou 516227, Guangdong, China
^2.Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China
^3.Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2022-04-05 Revised:2022-06-23 Online:2022-10-05 Published:2022-11-02
Contact: Shaojuan ZENG

摘要/Abstract

摘要：

人口增长与全球工业化的加速发展促使化石能源需求量逐年递增，由此导致大气中二氧化碳（CO₂）含量快速上升并引发了全球系列气候问题，“碳达峰·碳中和”背景下的CO₂减排刻不容缓。传统工业捕集CO₂方法由于能耗高、选择性较差、溶剂损耗大等问题限制了其大规模推广应用，离子液体因其极低挥发性、强的气体亲和性、可调的结构性质等特点在CO₂捕集分离领域逐渐显示出独特优势，但离子液体特别是功能化后通常黏度较高或室温呈固态，导致气液传质效果差或无法直接应用于吸收分离过程。负载型离子液体兼具离子液体和多孔材料的共同优势，不仅能提升选择性分离效果，有效避免离子液体直接吸收造成的高黏度，还可拓展离子液体应用范围，具有广阔的发展前景。重点总结了近些年物理和化学负载型离子液体在CO₂吸附分离方面的研究现状和进展，并对负载型离子液体捕集分离CO₂研究的发展趋势进行了展望。

关键词: 离子液体, 二氧化碳, 吸附, 负载型离子液体, 机理

Abstract:

Population growth and accelerated global industrialization have led to a yearly increase in fossil energy demand, resulting in a rapid increase of carbon dioxide (CO₂) emission in the atmosphere, which has led to a series of global climate problems, and CO₂ reduction in the context of “carbon peak and carbon neutralization” is imperative. Traditional industrial technologies for CO₂ separation are limited by high energy consumption, low selectivity and large solvent loss. Ionic liquids (ILs) have showed unique advantages in the field of CO₂ capture and separation due to their extremely low volatility, strong gas affinity and tunable structures. However, ILs, especially after functionalization, usually are highly viscous or solid at room temperature, resulting in poor gas-liquid mass transfer limiting their applications on CO₂ absorption and separation. Supported ionic liquids combine the advantages of ILs and porous materials, not only can enhance selective separation and effectively avoid high viscosity caused by direct absorption of ILs, but also can expand the application range of ILs, which have broad development prospect. This work comprehensively summarized the status and progress on physically and chemically supported ILs for CO₂ adsorption and separation in recent years, and provided an outlook on the development trend in future.

Key words: ionic liquids, carbon dioxide, adsorption, supported ionic liquids, mechanism

中图分类号:

TQ 530.11

吴建猛, 郑爽, 曾少娟, 张香平, 杨灿, 董海峰. 负载型离子液体吸附分离CO₂的研究现状及展望[J]. 化工学报, 2022, 73(10): 4268-4284.

Jianmeng WU, Shuang ZHENG, Shaojuan ZENG, Xiangping ZHANG, Can YANG, Haifeng DONG. Status and prospect on CO₂adsorption and separation by supported ionic liquids[J]. CIESC Journal, 2022, 73(10): 4268-4284.

图/表 14

图1 负载型离子液体的常见载体种类

Fig.1 Common carrier types of supported ionic liquids

图2 [P4444][2-Op]@介孔SiO2吸附分离CO2机理（PMS-w中的w为离子液体质量分数）[35]

Fig.2 Mechanism of CO2 separation by adsorption of [P4444][2-Op]@ mesoporous SiO2 (w in PMS-w is the mass fraction of ionic liquid) [35]

图3 离子液体[N4444][Ac]（a）、纤维素（b）、[N4444][Ac]@75%纤维素（c）、[N4444][Ac]@90%纤维素（d）的SEM图[42]

Fig.3 SEM images of ionic liquid [N4444][Ac] (a)， cellulose (b)， [N4444][Ac]@75% cellulose (c)，[N4444][Ac]@90% cellulose (d)[42]

图4 具有壳-夹层-核结构的IL-ZIF-IL复合材料的制备方法[53]

Fig.4 Preparation of IL-ZIF-IL composites with shell-interlayer-core structure [53]

图5 四种不同聚合物壳的化学结构[58]

Fig.5 Chemical structure of four different polymer shells[58]

图6 （a）使用模板法包裹离子液体的原理图；（b）离子液体胶囊的SEM和光学显微镜（OM）图像[59]

Fig.6 (a) Schematic of ionic liquid wrapped by template method; (b) SEM and optical microscope (OM) images of ionic liquid capsules [59]

表1 物理负载型离子液体对CO2的吸附量

Table 1 CO2 adsorption capacity of physically supported ionic liquids

吸附剂(离子液体@载体)	IL负载量/%(mass)	温度/℃	压力/MPa	吸附量/(mmol CO₂/g sorbent)	文献
[Bmim][NO₃]@SiO₂	50	25	0.1	0.35	[30]
[Bmim][PF₆]@硅胶	20	0	0.1	0.84	[31]
[Emim][Ac]@气相SiO₂	40	40	0.1	0.82	[32]
[Apmim][Br]@硅胶	40	35	0.1	0.67	[33]
[N₁₁₁₁][Gly]@硅胶	22.4	30	0.1	0.93	[34]
[P₄₄₄₄][2-Op]@MS	10	50	0.1	1.68	[35]
[N₂₂₂₂][Gly]@PDVB	51	30	0.1	1.63	[37]
[AEmim][Lys]@PMMA	50	30	0.1	1.50	[38]
[EOEOEmim][Gly]@D101	38	25	0.1	0.99	[39]
[Bmim][NTf₂]@PSF	32	45	0.4	1.30	[40]
[N₄₄₄₄][Ac]@纤维素	25	25	3.0	0.72	[42]
[dmedah][PR]@AC	10	25	0.1	1.21	[45]
[vbtma][Gly]@AC	20	25	0.1	1.51	[45]
[Emim][Gly]@F600-900	—	30	0.015	0.50	[47]
[Bmim][Ac]@SBA-15	48.5	25	0.1	2.11	[50]
[Apmim][Lys]@PE-SBA-15	50	30	0.1	0.88	[51]
[Teta]L@ZIF-8	25	25	0.1	1.53	[53]
[C₄(Vim)₂]Br₂@CuBTC	5	20	0.1	4.30	[54]
P[VCIm]Cl@MA	50	40	0.1	0.56	[55]
[Bmim][Gly]@HCM	60	30	0.1	0.52	[57]
[Bmim][PF₆]@HMDA-HDI	70	20	0.1	0.07	[58]
[Emim][2-CNpyr]@C₁₈-GO/PU	60	25	0.1	0.82	[59]

图7 Si-[P8883][Tf2N]-SiO2的合成过程[63]

Fig.7 Synthesis process of Si-[P8883][Tf2N]-SiO2[63]

图8 季铵基聚离子液体水分摆动吸收（MSA）CO2的机理[69]

Fig.8 Mechanism of quaternary ammonium-based poly ionic liquid moisture swing absorption (MSA) of CO2[69]

图9 化学接枝法合成活性炭负载型离子液体过程[72]

Fig.9 Synthesis of activated carbon loaded ionic liquids by chemical grafting[72]

图10 MIL-IL（A）与MIL-IL（B）的结合方式及CO2捕集转化示意图[77]

Fig.10 MIL-IL (A) and MIL-IL (B) combination method and CO2 capture and conversion diagram[77]

图11 GO-P[MATMA][BF4]的合成过程[80]

Fig.11 Synthesis process of GO-P[MATMA][BF4] [80]

图12 （a）单体结构式；（b）用于CO2捕获和固定的OPICs合成[81]

Fig.12 (a) Structural formula of monomer; (b) Synthesis of OPICs for CO2 capture and immobilization[81]

表2 化学负载型离子液体对CO2的吸附量

Table 2 CO2 adsorption capacity of chemically supported ionic liquids

吸附剂(离子液体-载体)	IL负载量/%(mass)	温度/℃	压力/MPa	吸附量/(mmol CO₂/g sorbent)	文献
[i-C₅TPIm][Tf₂N]-MS	5	45	0.4	1.81	[62]
Si-[P₈₈₈₃][Tf₂N]-SiO₂	—	40	0.1	0.99	[63]
P[VYIM][Bu₂PO₄]-SiO₂	8.2	0	0.1	1.03	[65]
P[Amim][BF₄]-SiO₂	5.0	0	0.1	0.87	[65]
[Bmim][Lys]-OMS	11.7	25	0.1	0.61	[66]
P[(META)⁺CF₃ $S O 3 -$ ]-cellulose	—	25	0.078	2.00	[68]
Si-P(C₈H₁₇)₃[Tf₂N]-AC	9.9	0	0.1	2.40	[72]
Si-P(C₈H₁₇)₃[Tf₂N]-AC	9.9	25	0.2	1.11	[73]
[(MeO)₃Sipmim][Cl]-MCM-41	25	25	0.1	1.49	[74]
[(MeO)₃Sipmim][Cl]-MCM-41	25	25	1	2.50	[74]
[Spmim][PF₆]-MCM-41 (2.3nm)	—	35	1	0.90	[75]
[Spmim][PF₆]-MCM-41 (3.3nm)	—	35	1	0.55	[75]
[C₂NH₂mim][Br]-MIL(A)	9.4	0	0.1	1.93	[77]
[C₂NH₂mim][Br]-MIL(B)	8.1	0	0.1	2.77	[77]
[C _m MOEim][Br]-MA	8	25	0.1	2.02	[78]
P[ViEtIm]Br-TiNTs	46	25	0.02	2.43	[79]
GO-P[MATMA][BF₄]	—	0	0.12	0.96	[80]
DB_10%-Pa-TP	—	0	0.1	4.83	[81]

表2 化学负载型离子液体对CO2的吸附量

Table 2 CO2 adsorption capacity of chemically supported ionic liquids

吸附剂(离子液体-载体)	IL负载量/%(mass)	温度/℃	压力/MPa	吸附量/(mmol CO₂/g sorbent)	文献
[i-C₅TPIm][Tf₂N]-MS	5	45	0.4	1.81	[62]
Si-[P₈₈₈₃][Tf₂N]-SiO₂	—	40	0.1	0.99	[63]
P[VYIM][Bu₂PO₄]-SiO₂	8.2	0	0.1	1.03	[65]
P[Amim][BF₄]-SiO₂	5.0	0	0.1	0.87	[65]
[Bmim][Lys]-OMS	11.7	25	0.1	0.61	[66]
P[(META)⁺CF₃ $S O 3 -$ ]-cellulose	—	25	0.078	2.00	[68]
Si-P(C₈H₁₇)₃[Tf₂N]-AC	9.9	0	0.1	2.40	[72]
Si-P(C₈H₁₇)₃[Tf₂N]-AC	9.9	25	0.2	1.11	[73]
[(MeO)₃Sipmim][Cl]-MCM-41	25	25	0.1	1.49	[74]
[(MeO)₃Sipmim][Cl]-MCM-41	25	25	1	2.50	[74]
[Spmim][PF₆]-MCM-41 (2.3nm)	—	35	1	0.90	[75]
[Spmim][PF₆]-MCM-41 (3.3nm)	—	35	1	0.55	[75]
[C₂NH₂mim][Br]-MIL(A)	9.4	0	0.1	1.93	[77]
[C₂NH₂mim][Br]-MIL(B)	8.1	0	0.1	2.77	[77]
[C _m MOEim][Br]-MA	8	25	0.1	2.02	[78]
P[ViEtIm]Br-TiNTs	46	25	0.02	2.43	[79]
GO-P[MATMA][BF₄]	—	0	0.12	0.96	[80]
DB_10%-Pa-TP	—	0	0.1	4.83	[81]

参考文献 81

1	Monastersky R. Global carbon dioxide levels near worrisome milestone[J]. Nature, 2013, 497(7447): 13-14.
2	邓旭, 谢俊, 滕飞. 何谓“碳中和”?[J]. 气候变化研究进展, 2021, 17(1): 107-113.
	Deng X, Xie J, Teng F. What is “carbon neutrality”?[J]. Climate Change Research, 2021, 17(1): 107-113.
3	叶亨利, 余兴光, 张继伟, 等. 我国二氧化碳捕集利用与封存项目环境影响评价对策[J]. 环境与可持续发展, 2017, 42(5): 43-46.
	Ye H L, Yu X G, Zhang J W, et al. Countermeasures on the environmental impact assessment of carbon dioxide capture and storage project in China[J]. Environment and Sustainable Development, 2017, 42(5): 43-46.
4	张中正. 二氧化碳的吸附分离[D]. 天津:天津大学, 2012.
	Zhang Z Z. Adsorptive separation of carbon dioxide[D]. Tianjin: Tianjin University, 2012.
5	Zhang K, Hou Y C, Wang Y M, et al. Efficient and reversible absorption of CO₂ by functional deep eutectic solvents[J]. Energy & Fuels, 2018, 32(7): 7727-7733.
6	Glasscock D A, Critchfield J E, Rochelle G T. CO₂ absorption/desorption in mixtures of methyldiethanolamine with monoethanolamine or diethanolamine[J]. Chemical Engineering Science, 1991, 46(11): 2829-2845.
7	Li X S, Liu J, Jiang W F, et al. Low energy-consuming CO₂ capture by phase change absorbents of amine/alcohol/H₂O[J]. Separation and Purification Technology, 2021, 275: 119181.
8	Heldebrant D J, Yonker C R, Jessop P G, et al. Organic liquid CO₂capture agents with high gravimetric CO₂ capacity[J]. Energy & Environmental Science, 2008, 1(4): 487-493.
9	Cognigni A, Kampichler S, Bica K. Surface-active ionic liquids in catalysis: impact of structure and concentration on the aerobic oxidation of octanol in water[J]. Journal of Colloid and Interface Science, 2017, 492: 136-145.
10	Wang T T, Hu Z Y, Zhang L, et al. Hydrodynamic characteristics of N₂-[Bmim][NO₃] two-phase Taylor flow in microchannels[J]. Industrial & Engineering Chemistry Research, 2021, 60(47): 17248-17258.
11	Li X, Ma N, Zhang L, et al. Applications of choline-based ionic liquids in drug delivery[J]. International Journal of Pharmaceutics, 2022, 612: 121366.
12	Lin H C, De Oliveira P W, Veith M. Application of ionic liquids in photopolymerizable holographic materials[J]. Optical Materials, 2011, 33(6): 759-762.
13	Blanchard L A, Dan H C, Beckman E J, et al. Green processing using ionic liquids and CO₂ [J]. Nature, 1999, 399(6731): 28-29.
14	夏裴文, 丁保宏, 张鹏军, 等. 离子液体及其吸收机理的研究进展[J]. 应用化工, 2019, 48(6): 1469-1473.
	Xia P W, Ding B H, Zhang P J, et al. Research progress on ionic liquids and their absorption mechanism[J]. Applied Chemical Industry, 2019, 48(6): 1469-1473.
15	Wang C M, Luo X Y, Zhu X, et al. The strategies for improving carbon dioxide chemisorption by functionalized ionic liquids[J]. RSC Advances, 2013, 3(36): 15518-15527.
16	Huang Y J, Cui G K, Zhao Y L, et al. Preorganization and cooperation for highly efficient and reversible capture of low-concentration CO₂ by ionic liquids[J]. Angewandte Chemie (International Ed. in English), 2017, 56(43): 13293-13297.
17	Chen F F, Huang K, Zhou Y, et al. Multi-molar absorption of CO₂ by the activation of carboxylate groups in amino acid ionic liquids[J]. Angewandte Chemie (International Ed. in English), 2016, 55(25): 7166-7170.
18	王薪薪, 唐少峰, 吕兴梅, 等. 氨基酸季铵离子液体水溶液的密度和黏度[J]. 中国科学:化学, 2014, 44(6): 1050-1057.
	Wang X X, Tang S F, Lyu X M, et al. The density and viscosity of aqueous solutions of quaternary ammonium-amino acid ionic liquids[J]. Scientia Sinica Chimica, 2014, 44(6): 1050-1057.
19	Kim D H, Baek I H, Hong S U, et al. Study on immobilized liquid membrane using ionic liquid and PVDF hollow fiber as a support for CO₂/N₂ separation[J]. Journal of Membrane Science, 2011, 372(1/2): 346-354.
20	张锁江, 刘晓敏, 姚晓倩, 等. 离子液体的前沿、进展及应用[J]. 中国科学(B辑:化学), 2009, 39(10): 1134-1144.
	Zhang S J, Liu X M, Yao X Q, et al. Frontiers, progresses and applications of ionic liquids[J]. Science in China (Series B: Chemistry), 2009, 39(10): 1134-1144.
21	Selvam T, Machoke A, Schwieger W. Supported ionic liquids on non-porous and porous inorganic materials—a topical review[J]. Applied Catalysis A: General, 2012, 445: 92-101.
22	Tan M, Lu J T, Zhang Y, et al. Ionic liquid confined in mesoporous polymer membrane with improved stability for CO₂/N₂ separation[J]. Nanomaterials, 2017, 7(10): 299-309.
23	张佩文. 多孔材料负载离子液体在吸收SO₂、NO₂、CO₂中的应用[D]. 石家庄:河北科技大学, 2019.
	Zhang P W. Application of porous material loaded ionic liquids in absorption of SO₂, NO₂, CO₂ [D]. Shijiazhuang: Hebei University of Science and Technology, 2019.
24	郭艳东, 佟佳欢, 刘晓敏, 等. 负载型离子液体的研究进展及发展趋势[J]. 中国科学:化学, 2016, 46(12): 1305-1316.
	Guo Y D, Tong J H, Liu X M, et al. Recent advances and development of supported ionic liquids[J]. Scientia Sinica Chimica, 2016, 46(12): 1305-1316.
25	Zhang Y Q, Zhang S J, Lu X M, et al. Dual amino-functionalised phosphonium ionic liquids for CO₂ capture[J]. Chemistry (Weinheim an Der Bergstrasse, Germany), 2009, 15(12): 3003-3011.
26	Ziobrowski Z, Rotkegel A. Feasibility study of CO₂/N₂ separation intensification on supported ionic liquid membranes by commonly used impregnation methods[J]. Greenhouse Gases: Science and Technology, 2021, 11(2): 297-312.
27	陈传东, 翟尚儒, 翟滨, 等. 功能离子液体/氧化硅基多孔复合材料[J]. 化学进展, 2010, 22(10): 1921-1928.
	Chen C D, Zhai S R, Zhai B, et al. Functional ionic liquid/porous silica composites[J]. Progress in Chemistry, 2010, 22(10): 1921-1928.
28	Lee K M, Lee Y T, Lin I J B. Supramolecular liquid crystals of amide functionalized imidazolium salts[J]. Journal of Materials Chemistry, 2003, 13(5): 1079-1084.
29	Tarkhanova I G, Anisimov A V, Buryak A K, et al. Immobilized ionic liquids based on molybdenum- and tungsten-containing heteropoly acids: structure and catalytic properties in thiophene oxidation[J]. Petroleum Chemistry, 2017, 57(10): 859-867.
30	Mirzaei M, Badiei A R, Mokhtarani B, et al. Experimental study on CO₂ sorption capacity of the neat and porous silica supported ionic liquids and the effect of water content of flue gas[J]. Journal of Molecular Liquids, 2017, 232: 462-470.
31	董晓晨, 朱佳媚, 孙雅钗, 等. 硅胶负载离子液体的CO₂吸附性能影响因素研究[J]. 材料导报, 2015, 29(14): 77-81.
	Dong X C, Zhu J M, Sun Y C, et al. Study on factors influencing CO₂ adsorption on ionic liquid-immobilized silica gel[J]. Materials Review, 2015, 29(14): 77-81.
32	Pohako-Esko K, Bahlmann M, Schulz P S, et al. Chitosan containing supported ionic liquid phase materials for CO₂ absorption[J]. Industrial & Engineering Chemistry Research, 2016, 55(25): 7052-7059.
33	陈义峰, 王昌松, 丁键, 等. 负载[APMIm][Br]离子液体吸收CO₂的性能[J]. 化工学报, 2014, 65(5): 1716-1720.
	Chen Y F, Wang C S, Ding J, et al. CO₂ absorption properties of supported [APMIm][Br][J]. CIESC Journal, 2014, 65(5): 1716-1720.
34	杨刚胜, 曾淦宁, 赵强, 等. 负载型氨基酸离子液体的制备及其对二氧化碳的吸附性能[J]. 燃料化学学报, 2016, 44(1): 106-112.
	Yang G S, Zeng G N, Zhao Q, et al. Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide[J]. Journal of Fuel Chemistry and Technology, 2016, 44(1): 106-112.
35	Xue C, Feng L, Zhu H, et al. Pyridine-containing ionic liquids lowly loaded in large mesoporous silica and their rapid CO₂ gas adsorption at low partial pressure[J]. Journal of CO₂ Utilization, 2019, 34: 282-292.
36	Mehnert C P, Cook R A, Dispenziere N C, et al. Supported ionic liquid catalysis—a new concept for homogeneous hydroformylation catalysis[J]. Journal of the American Chemical Society, 2002, 124(44): 12932-12933.
37	Xu W L, Zhang J Y, Cheng N N, et al. Facilely synthesized mesoporous polymer for dispersion of amino acid ionic liquid and effective capture of carbon dioxide from anthropogenic source[J]. Journal of the Taiwan Institute of Chemical Engineers, 2021, 125: 115-121.
38	Huang Z, Karami D, Mahinpey N. Study on the efficiency of multiple amino groups in ionic liquids on their sorbents performance for low-temperature CO₂ capture[J]. Chemical Engineering Research and Design, 2021, 167: 198-206.
39	徐玉韬, 徐海涛. 多孔树脂负载离子液体作为固体吸附剂用于CO₂的捕获[J]. 合成材料老化与应用, 2016, 45(2): 25-31, 59.
	Xu Y T, Xu H T. Porous resin supported ionic liquid as solid sorbents for reversible CO₂ capture[J]. Syntheic Materials Aging and Application, 2016, 45(2): 25-31, 59.
40	Nisar M, Bernard F L, Duarte E, et al. New polysulfone microcapsules containing metal oxides and ([BMIM][NTf₂]) ionic liquid for CO₂ capture[J]. Journal of Environmental Chemical Engineering, 2021, 9(1): 104781.
41	Gabrienko A A, Ewing A V, Chibiryaev A M, et al. New insights into the mechanism of interaction between CO₂ and polymers from thermodynamic parameters obtained by in situ ATR-FTIR spectroscopy[J]. Physical Chemistry Chemical Physics, 2016, 18(9): 6465-6475.
42	Reed D G, Dowson G R M, Styring P. Cellulose-supported ionic liquids for low-cost pressure swing CO₂ capture[J]. Frontiers in Energy Research, 2017, 5: 13-24.
43	叶青. 改性多孔材料常温下吸附分离密闭空间二氧化碳[D]. 杭州:浙江大学, 2012.
	Ye Q. CO₂ adsorption from confined space under ambient temperature by modified porous materials[D]. Hangzhou: Zhejiang University, 2012.
44	Wang X H, Cheng H R, Ye G Z, et al. Key factors and primary modification methods of activated carbon and their application in adsorption of carbon-based gases: a review[J]. Chemosphere, 2022, 287: 131995.
45	Shahrom M S R, Nordin A R, Wilfred C D. The improvement of activated carbon as CO₂ adsorbent with supported amine functionalized ionic liquids[J]. Journal of Environmental Chemical Engineering, 2019, 7(5): 103319.
46	Torralba-Calleja E, Skinner J, Gutiérrez-Tauste D. CO₂ capture in ionic liquids: a review of solubilities and experimental methods[J]. Journal of Chemistry, 2013, 2013: 473584.
47	Erto A, Silvestre-Albero A, Silvestre-Albero J, et al. Carbon-supported ionic liquids as innovative adsorbents for CO₂ separation from synthetic flue-gas[J]. Journal of Colloid and Interface Science, 2015, 448: 41-50.
48	Pevida C, Drage T C, Snape C E. Silica-templated melamine-formaldehyde resin derived adsorbents for CO₂ capture[J]. Carbon, 2008, 46(11): 1464-1474.
49	Bui T X, Kang S Y, Lee S H, et al. Organically functionalized mesoporous SBA-15 as sorbents for removal of selected pharmaceuticals from water[J]. Journal of Hazardous Materials, 2011, 193: 156-163.
50	Yin J Z, Zhen M Y, Cai P, et al. Supercritical CO₂ preparation of SBA-15 supported ionic liquid and its adsorption for CO₂ [J]. Materials Research Express, 2018, 5(6): 065060.
51	Huang Z L, Mohamedali M, Karami D, et al. Evaluation of supported multi-functionalized amino acid ionic liquid-based sorbents for low temperature CO₂ capture[J]. Fuel, 2022, 310: 122284.
52	Li Q Y, Ji S F, Hao Z M. Metal-organic framework materials and their applications in catalysis[J]. Progress in Chemistry, 2012, 24(8): 1506-1518.
53	Han G, Yu N, Liu D, et al. Stepped enhancement of CO₂ adsorption and separation in IL‐ZIF‐IL composites with shell‐interlayer‐core structure[J]. AIChE Journal, 2020, 67(2): 17112-17119.
54	Pan R, Guo Y N, Tang Y N, et al. Dicationic liquid containing alkenyl modified CuBTC improves the performance of the composites: increasing the CO₂ adsorption effect[J]. Chemical Engineering Journal, 2021, 430(6): 132127.
55	Zhou Y, Chang M, Zang X, et al. The polymeric ionic liquids/mesoporous alumina composites: synthesis, characterization and CO₂ capture performance test[J]. Polymer Testing, 2020, 81: 106109.
56	Romanos G E, Schulz P S, Bahlmann M, et al. CO₂ capture by novel supported ionic liquid phase systems consisting of silica nanoparticles encapsulating amine-functionalized ionic liquids[J]. The Journal of Physical Chemistry C, 2014, 118(42): 24437-24451.
57	Santiago R, Lemus J, Moya C, et al. Encapsulated ionic liquids to enable the practical application of amino acid-based ionic liquids in CO₂ capture[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(11): 14178-14187.
58	Gaur S S, Edgehouse K J, Klemm A, et al. Capsules with polyurea shells and ionic liquid cores for CO₂ capture[J]. Journal of Polymer Science, 2021, 59(23): 2980-2989.
59	Lee Y Y, Edgehouse K, Klemm A, et al. Capsules of reactive ionic liquids for selective capture of carbon dioxide at low concentrations[J]. ACS Applied Materials & Interfaces, 2020, 12(16): 19184-19193.
60	Jin M J, Taher A, Kang H J, et al. Palladium acetate immobilized in a hierarchical MFI zeolite-supported ionic liquid: a highly active and recyclable catalyst for Suzuki reaction in water[J]. Green Chemistry, 2009, 11(3): 309.
61	Thi T N, Van H D, Ha C H, et al. Preparation and properties of colloidal silica-filled natural rubber grafted with poly(methyl methacrylate)[J]. Polymer Bulletin, 2022, 79: 6011-6027.
62	Duczinski R, Polesso B B, Bernard F L, et al. Enhancement of CO₂/N₂ selectivity and CO₂ uptake by tuning concentration and chemical structure of imidazolium-based ILs immobilized in mesoporous silica[J]. Journal of Environmental Chemical Engineering, 2020, 8(3): 103740.
63	Zhu J M, He B T, Huang J H, et al. Effect of immobilization methods and the pore structure on CO₂ separation performance in silica-supported ionic liquids[J]. Microporous and Mesoporous Materials, 2018, 260: 190-200.
64	Qiu H, Lv L, Pan B C, et al. Critical review in adsorption kinetic models[J]. Journal of Zhejiang University-Science A, 2009, 10(5): 716-724.
65	Sun Y, Zhu J, Huang J, et al. Polymeric ionic liquid modified silica for CO₂ adsorption and diffusivity[J]. Polymer Composites, 2017, 38(4): 759-766.
66	Hiremath V, Jadhav A H, Lee H, et al. Highly reversible CO₂ capture using amino acid functionalized ionic liquids immobilized on mesoporous silica[J]. Chemical Engineering Journal, 2016, 287: 602-617.
67	Nemani S K, Annavarapu R K, Mohammadian B, et al. Surface modification of polymers: methods and applications[J]. Advanced Materials Interfaces, 2018, 5(24): 1801247.
68	Samadi A, Kemmerlin R K, Husson S M. Polymerized ionic liquid sorbents for CO₂ separation[J]. Energy & Fuels, 2010, 24(10): 5797-5804.
69	Wang T, Hou C, Ge K, et al. Spontaneous cooling absorption of CO₂ by a polymeric ionic liquid for direct air capture[J]. The Journal of Physical Chemistry Letters, 2017, 8(17): 3986-3990.
70	Guo Y F, Zhao C W, Li C H. CO₂ adsorption kinetics of K₂CO₃/activated carbon for low-concentration CO₂ removal from confined spaces[J]. Chemical Engineering & Technology, 2015, 38(5): 891-899.
71	Liu Y, Hu Y H, Zhou J S, et al. Polystyrene-supported novel imidazolium ionic liquids: highly efficient catalyst for the fixation of carbon dioxide under atmospheric pressure[J]. Fuel, 2021, 305: 121495.
72	董晓晨. 活性炭负载离子液体的制备及CO₂吸附性能研究[D]. 徐州:中国矿业大学, 2015.
	Dong X C. Synthesis of activated carbon immobilized ionic liquid and CO₂ adsorption properties[D]. Xuzhou: China University of Mining and Technology, 2015.
73	He X D, Zhu J M, Wang H M, et al. Surface functionalization of activated carbon with phosphonium ionic liquid for CO₂ adsorption[J]. Coatings, 2019, 9(9): 590-601.
74	Aquino A S, Bernard F L, Borges J V, et al. Rationalizing the role of the anion in CO₂ capture and conversion using imidazolium-based ionic liquid modified mesoporous silica[J]. RSC Advances, 2015, 5(79): 64220-64227.
75	Vangeli O C, Romanos G E, Beltsios K G, et al. Grafting of imidazolium based ionic liquid on the pore surface of nanoporous materials: study of physicochemical and thermodynamic properties[J]. The Journal of Physical Chemistry. B, 2010, 114(19): 6480-6491.
76	Wilson M, Barrientos-Palomo S N, Stevens P C, et al. Substrate-independent epitaxial growth of the metal-organic framework MOF-508a[J]. ACS Applied Materials & Interfaces, 2018, 10(4): 4057-4065.
77	Bahadori M, Marandi A, Tangestaninejad S, et al. Ionic liquid-decorated MIL-101(Cr) via covalent and coordination bonds for efficient solvent-free CO₂ conversion and CO₂ capture at low pressure[J]. The Journal of Physical Chemistry C, 2020, 124(16): 8716-8725.
78	Sun L W, Yin M L, Tang S K. Bi-functionalized ionic liquid-grafted mesoporous alumina: synthesis, characterization and CO₂/N₂ selectivity[J]. Journal of Environmental Chemical Engineering, 2021, 9(5): 105829.
79	Yuan J, Fan M L, Zhang F F, et al. Amine-functionalized poly(ionic liquid) brushes for carbon dioxide adsorption[J]. Chemical Engineering Journal, 2017, 316: 903-910.
80	Huang L, Jin Y, Sun L, et al. Graphene oxide functionalized by poly(ionic liquid)s for carbon dioxide capture[J]. Journal of Applied Polymer Science, 2017, 134(11): 44592.
81	Cao J J, Shan W J, Wang Q, et al. Ordered porous poly(ionic liquid) crystallines: spacing confined ionic surface enhancing selective CO₂ capture and fixation[J]. ACS Applied Materials & Interfaces, 2019, 11(6): 6031-6041.

[1]	张义飞, 刘舫辰, 张双星, 杜文静. 超临界二氧化碳用印刷电路板式换热器性能分析[J]. 化工学报, 2023, 74(S1): 183-190.
[2]	王琪, 张斌, 张晓昕, 武虎建, 战海涛, 王涛. 氯铝酸-三乙胺离子液体/P₂O₅催化合成伊索克酸和2-乙基蒽醌[J]. 化工学报, 2023, 74(S1): 245-249.
[3]	晁京伟, 许嘉兴, 李廷贤. 基于无管束蒸发换热强化策略的吸附热池的供热性能研究[J]. 化工学报, 2023, 74(S1): 302-310.
[4]	宋瑞涛, 王派, 王云鹏, 李敏霞, 党超镔, 陈振国, 童欢, 周佳琦. 二氧化碳直接蒸发冰场排管内流动沸腾换热数值模拟分析[J]. 化工学报, 2023, 74(S1): 96-103.
[5]	米泽豪, 花儿. 基于DFT和COSMO-RS理论研究多元胺型离子液体吸收SO₂气体[J]. 化工学报, 2023, 74(9): 3681-3696.
[6]	陆俊凤, 孙怀宇, 王艳磊, 何宏艳. 离子液体界面极化及其调控氢键性质的分子机理[J]. 化工学报, 2023, 74(9): 3665-3680.
[7]	郑佳丽, 李志会, 赵新强, 王延吉. 离子液体催化合成2-氰基呋喃反应动力学研究[J]. 化工学报, 2023, 74(9): 3708-3715.
[8]	宋明昊, 赵霏, 刘淑晴, 李国选, 杨声, 雷志刚. 离子液体脱除模拟油中挥发酚的多尺度模拟与研究[J]. 化工学报, 2023, 74(9): 3654-3664.
[9]	杨学金, 杨金涛, 宁平, 王访, 宋晓双, 贾丽娟, 冯嘉予. 剧毒气体PH₃的干法净化技术研究进展[J]. 化工学报, 2023, 74(9): 3742-3755.
[10]	杨绍旗, 赵淑蘅, 陈伦刚, 王晨光, 胡建军, 周清, 马隆龙. Raney镍-质子型离子液体体系催化木质素平台分子加氢脱氧制备烷烃[J]. 化工学报, 2023, 74(9): 3697-3707.
[11]	车睿敏, 郑文秋, 王小宇, 李鑫, 许凤. 基于离子液体的纤维素均相加工研究进展[J]. 化工学报, 2023, 74(9): 3615-3627.
[12]	陈美思, 陈威达, 李鑫垚, 李尚予, 吴有庭, 张锋, 张志炳. 硅基离子液体微颗粒强化气体捕集与转化的研究进展[J]. 化工学报, 2023, 74(9): 3628-3639.
[13]	程业品, 胡达清, 徐奕莎, 刘华彦, 卢晗锋, 崔国凯. 离子液体基低共熔溶剂在转化CO₂中的应用[J]. 化工学报, 2023, 74(9): 3640-3653.
[14]	王俐智, 杭钱程, 郑叶玲, 丁延, 陈家继, 叶青, 李进龙. 离子液体萃取剂萃取精馏分离丙酸甲酯+甲醇共沸物[J]. 化工学报, 2023, 74(9): 3731-3741.
[15]	陈杰, 林永胜, 肖恺, 杨臣, 邱挺. 胆碱基碱性离子液体催化合成仲丁醇性能研究[J]. 化工学报, 2023, 74(9): 3716-3730.

负载型离子液体吸附分离CO₂的研究现状及展望

Status and prospect on CO₂adsorption and separation by supported ionic liquids

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 14

参考文献 81

相关文章 15

编辑推荐

Metrics

本文评价