化工学报 ›› 2009, Vol. 60 ›› Issue (12): 2952-2956.

• 热力学 • 上一篇    下一篇

氯盐离子液体水溶液的物理化学性质

李吉广;杨兰英;褚宏达;刘艳升;刘植昌;胡玉峰   

  1. 中国石油大学(北京)重质油国家重点实验室,北京102249
  • 出版日期:2009-12-05 发布日期:2009-12-05

Physicochemical properties of aqueous chloride ionic liquid solutions

LI Jiguang;YANG Lanying;CHU Hongda;LIU Yansheng;LIU Zhichang;HU Yufeng   

  • Online:2009-12-05 Published:2009-12-05

摘要:

离子液体是一类新型表面活性剂,研究离子液体+水体系的物性具有重要的意义。为此,本文测定了不同浓度和温度下[Bemim][Cl](氯化-1-甲基-3-苄基咪唑),[Cnmim][Cl](氯化-1-甲基-3-烷基咪唑, n=4,14,16),[BeiQu][Cl](氯化-N-苄基异喹啉),[CmiQu][Cl](氯化-N-烷基异喹啉, m=4,8)等氯盐离子液体水溶液的密度、动力黏度、表面张力等物化性质。氯盐离子液体水溶液密度的变化趋势为咪唑类>异喹啉类。离子液体水溶液的黏度随着温度的升高而减小,随着浓度的升高而升高。在等温条件下,阳离子取代基相同时,离子液体水溶液的表面张力的变化趋势为咪唑类<异喹啉类。

关键词: 离子液体, 密度, 黏度, 表面张力

Abstract:

Ionic liquid is a new kind of surfactant,and it is very important to investigate the physicochemical properties of ionic liquid(IL)aqueous solutions.In this work,surface tensions,densities,and viscosities of [Bemim][Cl](1-methyl-3-benzylimidazolium chloride),[Cnmim][Cl](1-methyl-3-alkylimidazolium chloride, n=4,14,16),[BeiQu][Cl](N-benzylimidazolium chloride),[CmiQu][Cl](N-alkylisoquinolinium chloride, m =4,8)aqueous solutions were measured at different temperatures as a function of the concentration of aqueous solutions.The density of imidazolium-based solution is larger than that of isoquinolinium-based.The viscosity gets lower as the temperature increasing,and gets higher with the concentration increasing.At the same condition,with the same substitute of head group of cation,the surface tension of imidazolim-based solution is larger than that of isoquinolinium-based solution.

Key words: 离子液体, 密度, 黏度, 表面张力